Inorganic Surface Ligands for Colloidal Nanomaterials

AbstractSince the discovery of metal chalcogenide complexes (MCCs) as capping ligands for colloidal nanocrystals (NCs) in 2009, the chemistry of inorganic ligands for NCs has provided a new paradigm for surface design of nanomaterials. Various inorganic anions including MCCs, metal-free chalcogenides, oxoanions/oxometallates, and halides/pseudohalides/halometallates have been employed to replace the original long-chain organic ligands on NCs. This ligand exchange can also be achieved through a two-step route using ligands stripping agents like HBF

Download Full-text

Metal-free Inorganic Ligands for Colloidal Nanocrystals: S2–, HS–, Se2–, HSe–, Te2–, HTe–, TeS32–, OH–, and NH2–as Surface Ligands

Journal of the American Chemical Society ◽

10.1021/ja2029415 ◽

2011 ◽

Vol 133 (27) ◽

pp. 10612-10620 ◽

Cited By ~ 485

Author(s):

Angshuman Nag ◽

Maksym V. Kovalenko ◽

Jong-Soo Lee ◽

Wenyong Liu ◽

Boris Spokoyny ◽

...

Keyword(s):

Colloidal Nanocrystals ◽

Surface Ligands ◽

Metal Free ◽

Inorganic Ligands

Download Full-text

Proton Initiated Ligand Exchange Reactions for Colloidal Nanocrystals Functionalized by Inorganic Ligands with Extremely Weak Coordination Ability

Chemistry of Materials ◽

10.1021/acs.chemmater.9b04707 ◽

2019 ◽

Vol 32 (1) ◽

pp. 630-637 ◽

Cited By ~ 1

Author(s):

Wenran Wang ◽

Zhenxiao Pan ◽

Huashang Rao ◽

Guizhi Zhang ◽

Han Song ◽

...

Keyword(s):

Ligand Exchange ◽

Colloidal Nanocrystals ◽

Exchange Reactions ◽

Coordination Ability ◽

Inorganic Ligands ◽

Weak Coordination

Download Full-text

ChemInform Abstract: Colloidal Nanocrystals with Molecular Metal Chalcogenide Surface Ligands.

ChemInform ◽

10.1002/chin.200934208 ◽

2009 ◽

Vol 40 (34) ◽

Author(s):

Maksym V. Kovalenko ◽

Marcus Scheele ◽

Dmitri V. Talapin

Keyword(s):

Colloidal Nanocrystals ◽

Metal Chalcogenide ◽

Surface Ligands

Download Full-text

Disodium diselenide in colloidal nanocrystals: acting as an anion exchange precursor, a metal selenide precursor, and a chalcogenide ligand

Chemical Communications ◽

10.1039/c4cc07438f ◽

2015 ◽

Vol 51 (5) ◽

pp. 899-902 ◽

Cited By ~ 4

Author(s):

Donghyeuk Choi ◽

Seungyeol Lee ◽

Junho Lee ◽

Kyung-Sang Cho ◽

Sang-Wook Kim

Keyword(s):

Alkali Metal ◽

Anion Exchange ◽

Colloidal Nanocrystals ◽

Application Area ◽

Metal Chalcogenide

A new application area using a very simple alkali metal chalcogenide, disodium diselenide (Na2Se2), has been developed.

Download Full-text

Stability constants of metal-ion complexes Section I: Inorganic Ligands, compiled by Lars Gunnar Sill�n; Section II: Organic Ligands, compiled by Arthur E. Martell. (Second edition.) Pp. xviii + 754. Special Publication No. 17. The Chemical Society, London. 1964. E8 net

Endeavour ◽

10.1016/0160-9327(66)90049-4 ◽

1966 ◽

Vol 25 (94) ◽

pp. 52-53 ◽

Cited By ~ 1

Author(s):

R NYHOLM

Keyword(s):

Stability Constants ◽

Metal Ion ◽

Chemical Society ◽

Organic Ligands ◽

Metal Ion Complexes ◽

Special Publication ◽

Inorganic Ligands

Download Full-text

Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding

Journal of the American Chemical Society ◽

10.1021/ja4086758 ◽

2013 ◽

Vol 135 (49) ◽

pp. 18536-18548 ◽

Cited By ~ 478

Author(s):

Nicholas C. Anderson ◽

Mark P. Hendricks ◽

Joshua J. Choi ◽

Jonathan S. Owen

Keyword(s):

Ligand Exchange ◽

Spectroscopic Observation ◽

Metal Carboxylate ◽

Metal Chalcogenide

Download Full-text

SnS44– Metal Chalcogenide Ligand, S2– Metal Free Ligand, and Organic Surface Ligand Toward Efficient CdSe Quantum Dot- Sensitized Solar Cells

The Journal of Physical Chemistry C ◽

10.1021/jp5005242 ◽

2014 ◽

Vol 118 (30) ◽

pp. 17019-17027 ◽

Cited By ~ 15

Author(s):

Sukyung Choi ◽

Ho Jin ◽

Sungjee Kim

Keyword(s):

Solar Cells ◽

Quantum Dot ◽

Free Ligand ◽

Metal Chalcogenide ◽

Metal Free ◽

Cdse Quantum Dot ◽

Surface Ligand ◽

Sensitized Solar Cells

Download Full-text

Colloidal Nanocrystals with Molecular Metal Chalcogenide Surface Ligands

Science ◽

10.1126/science.1170524 ◽

2009 ◽

Vol 324 (5933) ◽

pp. 1417-1420 ◽

Cited By ~ 755

Author(s):

M. V. Kovalenko ◽

M. Scheele ◽

D. V. Talapin

Keyword(s):

Colloidal Nanocrystals ◽

Metal Chalcogenide ◽

Surface Ligands

Download Full-text

Stability constants of metal-ion complexes. Von L. G. Sillén (Inorganic Ligands) und A. E. Martell (Organic Ligands). 754 Seiten. Herausgegeben von The Chemical Society, London 1964. Preis $ 23,—

Archiv der Pharmazie ◽

10.1002/ardp.19652980613 ◽

1965 ◽

Vol 298 (6) ◽

pp. 400-400 ◽

Cited By ~ 1

Author(s):

H. Auterhoff

Keyword(s):

Stability Constants ◽

Metal Ion ◽

Chemical Society ◽

Organic Ligands ◽

Metal Ion Complexes ◽

Inorganic Ligands

Download Full-text

Direct synthesis of sulfide capped CdS and CdS/ZnS colloidal nanocrystals for efficient hydrogen evolution under visible light irradiation

Journal of Materials Chemistry A ◽

10.1039/c8ta05637d ◽

2018 ◽

Vol 6 (34) ◽

pp. 16328-16332 ◽

Cited By ~ 16

Author(s):

Xiang-Bing Fan ◽

Shan Yu ◽

Hao-Lin Wu ◽

Zhi-Jun Li ◽

Yu-Ji Gao ◽

...

Keyword(s):

Visible Light ◽

Hydrogen Evolution ◽

Visible Light Irradiation ◽

Direct Synthesis ◽

Organic Ligands ◽

Light Irradiation ◽

Colloidal Nanocrystals

CdS and CdS/ZnS colloidal nanocrystals (NCs) capped with inorganic sulfide (S2−) ligands were directly synthesized with no aid of organic ligands in water.

Download Full-text