The crystal structure of AlAsO4 at high pressure

Author(s):  
H. Sowa

AbstractSingle-crystal structure determinations of the low-temperature quartz modification of AlAsOThe refinements were carried out in space groupsThe high pressure behaviour of AlAsOFrom the shortening of intertetrahedral O – O distances and the changes of the shape of the Dirichlet domains of the oxygen anions, it can be concluded that the oxygen packing changes with increasing pressure in the direction of an arrangement corresponding to a cubic body-centered lattice. As in the case of SiO

1978 ◽  
Vol 49 (8) ◽  
pp. 4411-4416 ◽  
Author(s):  
H. d’Amour ◽  
D. Schiferl ◽  
W. Denner ◽  
Heinz Schulz ◽  
W. B. Holzapfel

2009 ◽  
Vol 79 (6) ◽  
Author(s):  
Erick A. Juarez-Arellano ◽  
Alexandra Friedrich ◽  
Dan J. Wilson ◽  
Leonore Wiehl ◽  
Wolfgang Morgenroth ◽  
...  

2004 ◽  
Vol 57 (5) ◽  
pp. 503 ◽  
Author(s):  
Peter C. Junk ◽  
Colin L. Raston ◽  
Brian W. Skelton ◽  
Allan H. White

Salts of the trans-[py2AlCl4]– anion have been structurally characterized by ‘low’-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HCl · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HCl · 7py {=(pyH)3[(py)2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6–n)](n–3)± with ‘octahedral’ six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.


Author(s):  
H. Sowa

AbstractSingle-crystal structure refinements of the low-temperature quartz modification of GaPOThe refinements were carried out in space groupThe high pressure behavior of GaPOAs in the case of other quartz-type structures, the high-pressure behavior of GaPO


1995 ◽  
Vol 10 (4) ◽  
pp. 293-295 ◽  
Author(s):  
F. Brunet ◽  
C. Chopin ◽  
A. Elfakir ◽  
M. Quarton

A new diffraction pattern of the high-temperature and high-pressure polymorph Mg3(PO4)2-III (PDF 43-500) is given and indexed on the basis of a single-crystal structure refinement. It allows diffractogram indexing of the isostructural high-temperature and high-pressure form of Co3(PO4)2 (PDF 43-499).


1989 ◽  
Vol 42 (1) ◽  
pp. 201 ◽  
Author(s):  
CL Raston ◽  
CR Whitaker ◽  
AH White

Although only sparingly soluble in acetonitrile, lithium(1) bromide and iodide crystallize as acetonitrile adducts, structurally characterized as LiX/MeCN 1 : 2 and 1 : 4 respectively by single-crystal structure determinations. The bromide is a �,�′-dibromo-bridged dimer , ( MeCN )2LiBr2Li( NCMe )2)] (monoclinic, P21/n, a 7.624(2), b 12.61 2(2), c 8.047(3) � , β 98.94(3)°p; Z 2 dimers; R 0.038 for No 1081 'observed' reflections); Li-Br, N 2.534(7), 2.492(8); 2.031(9), 2.047(8) � respectively, with Li…Li, 3.17(1); Br…Br, 3.8989(9) � respectively. The iodide is ionic, [Li( NCMe )4]+1- (orthorhombic, P21221, a 20.66(1), b 12.208(6), c 8.4296) �, Z 6; R 0.062 for No 866).


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