Initial Sticking Coefficient of H2 on the Pd–Cu(111) Surface Alloy at very Low Coverages

2013 ◽  
Vol 227 (9-11) ◽  
Author(s):  
Daniel Farías ◽  
Marina Minniti ◽  
Amjad Al Taleb ◽  
Rodolfo Miranda
2013 ◽  
Vol 0 (0) ◽  
pp. 1-10
Author(s):  
Daniel Farías ◽  
Marina Minniti ◽  
Amjad Al Taleb ◽  
Rodolfo Miranda

1996 ◽  
Vol 363 (1-3) ◽  
pp. 68-72 ◽  
Author(s):  
F.Buatier de Mongeot ◽  
M. Rocca ◽  
U. Valbusa

1990 ◽  
Vol 54-55 ◽  
pp. 131-141 ◽  
Author(s):  
M. Rocca ◽  
P. Traversaro ◽  
U. Valbusa

1994 ◽  
Vol 101 (1) ◽  
pp. 713-725 ◽  
Author(s):  
L. Vattuone ◽  
M. Rocca ◽  
C. Boragno ◽  
U. Valbusa

2005 ◽  
Vol 12 (05n06) ◽  
pp. 787-792
Author(s):  
S. D. FOULIAS ◽  
A. PERDIKIS ◽  
D. VLACHOS

The adsorption of oxygen and potassium on the two-phase system: carbide-modified stepped- W (100) surface (CMT) in contact with the solid solution of carbon in bulk tungsten, was investigated by AES and WF measurements. The CMT surface shows metallic behavior judging from its interaction with K . The expected dissociative adsorption of oxygen appears to occur with 1 - θ kinetics, possibly via a molecularly chemisorbed state. The "dispersed phase — two-phase" model is clearly applicable when oxygen adsorbs on the K -pre-covered carbide. The initial sticking coefficient of oxygen increases drastically from the dispersed to the condensed phase, at least four-fold with respect to s0 on the clean carbide. It is proposed that this two-phase carbon system can be advantageous compared with the bulk carbide since it can easily regenerate the surface if the latter is depleted from carbon.


2004 ◽  
Vol 11 (01) ◽  
pp. 21-25 ◽  
Author(s):  
M.-A. ZAÏBI ◽  
J.-P. LACHARME

The clean Si (111)(7×7) surface has been exposed to ethylene ( C 2 H 4) doses, up to 7000 L (1 L =10-6 Torr ×1 s ) at most, under ultrahigh vacuum. The structural and electronic property changes of the surface have been studied by low energy electron diffraction (LEED), Auger electron spectrometry (AES) and photoemission yield spectroscopy (PYS). The interaction presents two types of kinetic adsorption, where the first is produced below 3000 L of C 2 H 4. In the first step, the ethylene molecule is adsorbed molecularly and the initial sticking coefficient S 0 is very low (S0≈2×10-3). At the saturation (≈ 5000–6000 L), the valence band is fitted by a power law (E — 4.42)2.5 eV .1,2 The surface is then a stronger scattering for photoemitted electrons. We attribute this result, produced at the second step of adsorption, to the C 2 H 4-π orbital and hydrogen liberated by this molecule, which break the Si – Si surface bonds.


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