Atomic structure of amorphous Al90FexCe10−x

1990 ◽  
Vol 5 (12) ◽  
pp. 2807-2812 ◽  
Author(s):  
H. Y. Hsieh ◽  
B. H. Toby ◽  
T. Egami ◽  
Y. He ◽  
S. J. Poon ◽  
...  

The atomic structure of liquid-quenched amorphous Al90FexCe10−x(x= 5,7) was studied by pulsed neutron and x-ray scattering. The atomic pair-density function determined by pulsed neutron diffraction indicates that a significant portion of Al–Fe distances is anomalously short, while some part of the Al–Al distances is anomalously long. Both neutron and x-ray scattering showed the presence of a prepeak in the structure factor. These results suggest that a strong interaction between A1 and Fe modifies the structure of this glass, leading to chemical and topological short-range ordering.

2010 ◽  
Vol 29 (5-6) ◽  
pp. 381-392
Author(s):  
Osami Haruyama, ◽  
Takahiro Makimura, ◽  
Tomoki Miyakawa, ◽  
Kazumasa Sugiyama,

1997 ◽  
Vol 199 (1) ◽  
pp. 103-113 ◽  
Author(s):  
T. Egami ◽  
S. Teslic ◽  
W. Dmowski ◽  
D. Viehland ◽  
S. Vakhrushev

2020 ◽  
Vol 8 (31) ◽  
pp. 10907-10916
Author(s):  
Matthew A. Davenport ◽  
Jared M. Allred

Local structure in V1−xMoxO2 (x ∼ 0.5) solved using combined total and single X-ray scattering.


2000 ◽  
Vol 644 ◽  
Author(s):  
Eiichiro Matsubara ◽  
Takahiro Nakamura ◽  
Masaki Sakurai ◽  
Muneyuki Imafuku ◽  
Shigeo Sato ◽  
...  

AbstractLocal atomic structures around Zr and Pt in a quasicrystalline Zr80Pt20alloy, and amorphous and quasicrystalline Zr70Ni10Pt20alloys have been determined by the anomalous x-ray scattering (AXS) method. A distinct prepeak observed in an intensity profile of the amorphous Zr70Ni10Pt20alloy indicates existence of strong chemical short-range order (CSRO) clusters in the amorphous phase. Total coordination numbers around Zr and Pt in a nearest neighbor region in both alloys have been evaluated. The values around Pt are almost equal to 12 in the amorphous and quasicrystalline states suggest formation of icosahedral clusters around Pt. Some of crystalline structures formed from the quasicrystalline phases by annealing consist of icosahedral clusters of Zr and Ni atoms, or polyhedral clusters of Zr and Pt atoms similar with icosahedral clusters. The present result appears to support that the phase transformation from the amorphous to the crystal through the quasicrystal is explained by the icosahedral CSRO clusters in the amorphous and quasicrystalline states.


2012 ◽  
Vol 173 ◽  
pp. 164-171 ◽  
Author(s):  
Nourhane Ben Zineb ◽  
Abir Chebaane ◽  
Ferid Hammami ◽  
Mohamed Bahri ◽  
Salah Nasr

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