Organic solar cells: An overview

2004 ◽  
Vol 19 (7) ◽  
pp. 1924-1945 ◽  
Author(s):  
Harald Hoppe ◽  
Niyazi Serdar Sariciftci

Organic solar cell research has developed during the past 30 years, but especially in the last decade it has attracted scientific and economic interest triggered by a rapid increase in power conversion efficiencies. This was achieved by the introduction of new materials, improved materials engineering, and more sophisticated device structures. Today, solar power conversion efficiencies in excess of 3% have been accomplished with several device concepts. Though efficiencies of these thin-film organicdevices have not yet reached those of their inorganic counterparts (η ≈ 10–20%); the perspective of cheap production (employing, e.g., roll-to-roll processes) drives the development of organic photovoltaic devices further in a dynamic way. The two competitive production techniques used today are either wet solution processing or dry thermal evaporation of the organic constituents. The field of organic solar cells profited well from the development of light-emitting diodes based on similar technologies, which have entered the market recently. We review here the current status of the field of organic solar cells and discuss different production technologies as well as study the important parameters to improve their performance.

Author(s):  
Shreyam Chatterjee ◽  
Seihou JINNAI ◽  
Yutaka Ie

Progressive advancement of remarkably high power conversion efficiencies (PCEs) of organic solar cells (OSCs) largely depends on the development of norfullerene acceptors (NFAs), revealing stupendous ability of OSCs to shift...


Nanoscale ◽  
2021 ◽  
Author(s):  
Congcong Zhao ◽  
Jiuxing Wang ◽  
Xuanyi Zhao ◽  
Zhonglin Du ◽  
Renqiang Yang ◽  
...  

The past decade has seen a tremendous development of organic solar cells (OSCs). To date, the high-performance OSCs have boosted the power conversion efficiencies (PCEs) over 17%, showing bright prospects...


2021 ◽  
Author(s):  
Haifen Liu ◽  
Zixuan Zhu ◽  
Huafeng Li ◽  
Weili Fan ◽  
Kaihua Ning ◽  
...  

Non-fullerene acceptors have received a great deal of attention over the past several years, and numerous modifications on the molecular structures significantly boosted the power conversion efficiencies (PCEs). To be...


2021 ◽  
Author(s):  
Zhaofan Yang ◽  
Shijie Liang ◽  
Baiqiao Liu ◽  
Jing Wang ◽  
Fan Yang ◽  
...  

Single-component organic solar cells (SCOSCs) have been recognized as the promising photovoltaic technology due to the excellent stability, but their power conversion efficiencies (PCEs) are far lagging their bulk-heterojunction counterparts....


2019 ◽  
Vol 43 (26) ◽  
pp. 10442-10448 ◽  
Author(s):  
Sergey V. Dayneko ◽  
Arthur D. Hendsbee ◽  
Jonathan R. Cann ◽  
Clément Cabanetos ◽  
Gregory C. Welch

The addition of donor or acceptor type molecular semiconductors to PBDB-T:PC60BM based organic photovoltaics leads to increases in open circuit-voltages and overall power conversion efficiencies.


2019 ◽  
Vol 01 (01) ◽  
pp. 030-037 ◽  
Author(s):  
Jianyun Zhang ◽  
Wenrui Liu ◽  
Shengjie Xu ◽  
Xiaozhang Zhu

Recently, by elaborately designing nonfullerene acceptors and selecting suitable polymer donors great progresses have been made towards binary organic solar cells (OSCs) with power conversion efficiencies (PCEs) over 15%. Ternary organic photovoltaics by introducing a third component into the host binary system is recognized to be highly effective to elevate the performance through extending the light absorption, manipulating the recombination behavior of the carriers, and improving the morphology of the active layer. In this work, we synthesized a new electron-acceptor ZITI-4F matching it with the wide-bandgap polymer donor PBDB-T The PBDB-T:ZITI-4F-based OSC showed a high PCE of 12.33%. After introducing 40% of PC71BM as the third component, the ternary device achieved an improved PCE of 13.40% with simultaneously improved photovoltaic parameters. The higher performance of the ternary device can be attributed to the improved and more balanced charge mobility, reduced bimolecular recombination, and more favorable morphology. These results indicate that the cooperation of a fullerene-based acceptor and a nonfullerene acceptor to fabricate ternary OSCs is an effective approach to optimizing morphology and therefore to increase the performance of OSCs.


2017 ◽  
Vol 5 (6) ◽  
pp. 1275-1302 ◽  
Author(s):  
Wangqiao Chen ◽  
Qichun Zhang

The power conversion efficiencies (PCEs) of non-fullerene small molecule acceptors based on different donors have been compared and summarized.


2016 ◽  
Vol 6 (21) ◽  
pp. 1600660 ◽  
Author(s):  
Tenghooi Goh ◽  
Jing-Shun Huang ◽  
Kevin G. Yager ◽  
Matthew Y. Sfeir ◽  
Chang-Yong Nam ◽  
...  

2020 ◽  
Vol 8 (12) ◽  
pp. 5843-5847 ◽  
Author(s):  
Tainan Duan ◽  
Jie Gao ◽  
Tongle Xu ◽  
Zhipeng Kan ◽  
Wenjing Chen ◽  
...  

A set of centrally halogenated oligothiophenes were developed for organic solar cells. The devices with a chlorinated donor (2Cl7T) achieved power conversion efficiencies (PCEs) of up to ca. 11.5% (vs. ca. 2.5% for non-halogenated donor DRCN7T).


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