Recent advances in the theory of hydrogen storage in complex metal hydrides

MRS Bulletin ◽  
2013 ◽  
Vol 38 (6) ◽  
pp. 462-472 ◽  
Author(s):  
Kyle Jay Michel ◽  
Vidvuds Ozoliņš

Abstract

2019 ◽  
Vol 34 (6) ◽  
pp. 877-904 ◽  
Author(s):  
Matylda N. Guzik ◽  
Rana Mohtadi ◽  
Sabrina Sartori

Abstract


2009 ◽  
Vol 74 (2) ◽  
pp. 183-196 ◽  
Author(s):  
Borislav Bogdanovic ◽  
Michael Felderhoff ◽  
Guido Streukens

Complex metal hydrides such as sodium aluminohydride (NaAlH4) and sodium borohydride (NaBH4) are solid-state hydrogen-storage materials with high hydrogen capacities. They can be used in combination with fuel cells as a hydrogen source thus enabling longer operation times compared with classical metal hydrides. The most important point for a wide application of these materials is the reversibility under moderate technical conditions. At present, only NaAlH4 has favorable thermodynamic properties and can be employed as a thermally reversible means of hydrogen storage. By contrast, NaBH4 is a typical non-reversible complex metal hydride; it reacts with water to produce hydrogen.


MRS Bulletin ◽  
2013 ◽  
Vol 38 (6) ◽  
pp. 488-494 ◽  
Author(s):  
Petra E. de Jongh ◽  
Mark Allendorf ◽  
John J. Vajo ◽  
Claudia Zlotea

Abstract


MRS Bulletin ◽  
2013 ◽  
Vol 38 (6) ◽  
pp. 452-458 ◽  
Author(s):  
Ewa C.E. Rönnebro ◽  
Eric H. Majzoub

Abstract


2014 ◽  
Vol 2 (12) ◽  
pp. 4361-4365 ◽  
Author(s):  
Tengfei Zhang ◽  
Shigehito Isobe ◽  
Yongming Wang ◽  
Hiroshi Oka ◽  
Naoyuki Hashimoto ◽  
...  

It is reported for the first time, that the desorption properties in complex metal hydrides (MgH2, LiAlH4, and LiNH2) are enhanced by a lithium-ion-battery material, LiTi2O4. Three different systems for hydrogen storage are catalysed by one material.


2007 ◽  
Vol 90 (15) ◽  
pp. 151917 ◽  
Author(s):  
E. Muller ◽  
E. Sutter ◽  
P. Zahl ◽  
C. V. Ciobanu ◽  
P. Sutter

Inorganics ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 17 ◽  
Author(s):  
Efi Hadjixenophontos ◽  
Erika Michela Dematteis ◽  
Nicola Berti ◽  
Anna Roza Wołczyk ◽  
Priscilla Huen ◽  
...  

Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel, sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen storage applications based on metal hydrides can provide solutions for such technologies. However, there are still many technical challenges for both hydrogen storage material and ASSBs related to designing low-cost materials with low-environmental impact. The current materials considered for all-solid-state batteries should have high conductivities for Na+, Mg2+ and Ca2+, while Al3+-based compounds are often marginalised due to the lack of suitable electrode and electrolyte materials. In hydrogen storage materials, the sluggish kinetic behaviour of solid-state hydride materials is one of the key constraints that limit their practical uses. Therefore, it is necessary to overcome the kinetic issues of hydride materials before discussing and considering them on the system level. This review summarizes the achievements of the Marie Skłodowska-Curie Actions (MSCA) innovative training network (ITN) ECOSTORE, the aim of which was the investigation of different aspects of (complex) metal hydride materials. Advances in battery and hydrogen storage materials for the efficient and compact storage of renewable energy production are discussed.


2011 ◽  
Vol 197-198 ◽  
pp. 1096-1099
Author(s):  
Wen Xue Zhang ◽  
Xin Hu ◽  
Xiao Bin Lin ◽  
Cheng He

The most promising hydrogen storage materials are perhaps complex metal hydrides. Thus, a plausible first step in the rehydrogenation mechanism is proposed by simulating the reversible hydrogen storage in Zr-doped NaAlH4. It provides insight into the catalytic role of Zr atoms on an Al surface in the chemisorptions of molecular hydrogen. It is found that the diffusion of hydride species on Al-metallic phase and formation of Al hydride species is probably the key to syntheses the next products in the rehydrogenation reaction.


Materials ◽  
2015 ◽  
Vol 8 (9) ◽  
pp. 5891-5921 ◽  
Author(s):  
Morten Ley ◽  
Mariem Meggouh ◽  
Romain Moury ◽  
Kateryna Peinecke ◽  
Michael Felderhoff

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