Metal Hydrides for Hydrogen Storage

2007 ◽  
Vol 1041 ◽  
Author(s):  
Jason Graetz ◽  
James J Reilly ◽  
James Wegrzyn

AbstractThe emergence of a Hydrogen Economy will require the development of new media capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides, where hydrogen is chemically bonded to the metal atoms in the bulk, offer some hope of overcoming the challenges associated with hydrogen storage. Many of the more promising hydrogen materials are tailored to meet the unique demands of a low temperature automotive fuel cell and are therefore either entirely new (e.g. in structural or chemical composition) or in some new form (e.g. morphology, crystallite size, catalysts). This proceeding presents an overview of some of the challenges associated with metal hydride hydrogen storage and a few new approaches being investigated to address these challenges.

2014 ◽  
Vol 268 ◽  
pp. 950-959 ◽  
Author(s):  
Kriston P. Brooks ◽  
Troy A. Semelsberger ◽  
Kevin L. Simmons ◽  
Bart van Hassel

2012 ◽  
Vol 2012 ◽  
pp. 1-18 ◽  
Author(s):  
Jason Graetz

The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. On the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.


2005 ◽  
Vol 142 (1-2) ◽  
pp. 92-102 ◽  
Author(s):  
Z. Jiang ◽  
R.A. Dougal ◽  
S. Liu ◽  
S.A. Gadre ◽  
A.D. Ebner ◽  
...  

2020 ◽  
Vol 45 (14) ◽  
pp. 7958-7967 ◽  
Author(s):  
Mykhaylo Lototskyy ◽  
Ivan Tolj ◽  
Yevgeniy Klochko ◽  
Moegamat Wafeeq Davids ◽  
Dana Swanepoel ◽  
...  

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