scholarly journals Enhanced energy storage performance and fatigue resistance of Mn‐doped 0.7Na0.5Bi0.5TiO3– 0.3Sr0.7Bi0.2TiO3 lead‐free ferroelectric ceramics

Author(s):  
Jinbo Wang ◽  
Huiqing Fan
2020 ◽  
pp. 1-10
Author(s):  
Jinbo Wang ◽  
Huiqing Fan

The validity of Mn element on enhanced energy storage performance and fatigue resistance of Mn-doped 0.7Na0.5Bi0.5TiO3–0.3Sr0.7Bi0.2TiO3 lead-free ferroelectric ceramics (BNT–BST–xMn) is certified by doping. The effects of Mn modification on the dielectric behavior, ferroelectric, energy storage properties, and AC impedance are comprehensively investigated. It is found that the average grain size of the ceramics modified by Mn additions is reduced slightly. Moreover, the relaxor properties are evidently enhanced with the increased Mn content. The AC impedance spectra can even better clarify the dielectric response and relaxor behavior. The results suggest that both of the dielectric response and relaxor behavior are determined by defects especially concentration of the oxygen vacancy. The superior energy storage properties are realized at x = 0.05 with an energy storage density (Wrec) of 1.33 J/cm3 as well as energy storage efficiency (η) of 86.2% at 100 kV/cm, accompanied with a superior thermal stability. BNT–BST–5Mn ceramics can maintain a stable energy storage performance within 106 fatigue cycles, indicating an excellent fatigue resistance.


2016 ◽  
Vol 4 (36) ◽  
pp. 8380-8384 ◽  
Author(s):  
Lei Zhao ◽  
Qing Liu ◽  
Shujun Zhang ◽  
Jing-Feng Li

Enhanced anti-ferroelectric properties and high recoverable energy densities from 2.5–2.9 J cm−3 were achieved in 0.1 wt% Mn-doped AgNbO3 ceramics over 20–180 °C.


2019 ◽  
Vol 45 (16) ◽  
pp. 20266-20275 ◽  
Author(s):  
Li-Feng Zhu ◽  
Xuan-Wei Lei ◽  
Lei Zhao ◽  
M. Irfan Hussain ◽  
Guang-Zhi Zhao ◽  
...  

2021 ◽  
Vol 9 (16) ◽  
pp. 10088-10094
Author(s):  
Chao Zhang ◽  
Wenrong Xiao ◽  
Fangfang Zeng ◽  
Dong Su ◽  
Kang Du ◽  
...  

A high dielectric energy storage performance is achieved in a 0.85Bi0.5Na0.5TiO3–0.15NaNbO3 lead-free ferroelectric ceramic via composition and microstructure engineering.


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