Effect of open and cyclic (>N)2C=S moiety in phenylthiourea and 2-mercapto-benzimidazole on reactivity of •OH and SO4•- in aqueous sulphuric acid media

2014 ◽  
Vol 1 (2) ◽  
pp. 41-52 ◽  
Author(s):  
G. Dey ◽  
Keyword(s):  
1983 ◽  
Vol 18 (3) ◽  
pp. 209-216 ◽  
Author(s):  
St. Rashkov ◽  
M. Monev ◽  
G. Raichevski

1960 ◽  
Vol 38 (9) ◽  
pp. 1518-1525 ◽  
Author(s):  
J. T. Edward ◽  
H. S. Chang ◽  
K. Yates ◽  
Ross Stewart

The basicities of benzamide and of 11 meta- and para-substituted benzamides in sulphuric acid media have been determined by a spectrophotometric method. The [Formula: see text] values of the protonated benzamides were found to be proportional to the Hammett σ constants for the substituents, unlike the [Formula: see text] values of the protonated benzaldehydes, acetophenones, and benzoic acids, which are approximately proportional to σ+ constants. The lack of conjugation between the protonated amide group and the ring, which is indicated by these results, is most easily interpreted in terms of N-protonation although O-protonation cannot be completely excluded. Various other aspects of the problem of N- versus O-protonation are also discussed.


1994 ◽  
pp. 125-138 ◽  
Author(s):  
J. E. Dutrizac ◽  
T. T. Chen

Author(s):  
Rupendranath Banerjee ◽  
Anamika Bhattacharya ◽  
Prabir K. Das ◽  
Amiya K. Chakraburtty

1989 ◽  
Vol 22 (1-2) ◽  
pp. 67-85 ◽  
Author(s):  
R.M. Morrison

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