scholarly journals Electron paramagnetic resonance of manganese-doped strontium titanate

Cerâmica ◽  
2020 ◽  
Vol 66 (378) ◽  
pp. 126-129
Author(s):  
R. S. de Biasi ◽  
M. L. N. Grillo
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Exchange Interaction ◽  
Strontium Titanate ◽  
Relative Intensity ◽  
Theoretical Equation ◽  
Manganese Concentration ◽  
Manganese Ions ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic ◽  
Mn Concentrations

Abstract Electron paramagnetic resonance (EPR) spectra of manganese-doped strontium titanate were investigated for several Mn concentrations. The spectra of Mn2+ and Mn4+ ions were observed and attributed, respectively, to Mn ions occupying Sr2+ and Ti4+ sites. The relative intensity of the spectra suggested that the manganese ions occupy preferentially Ti4+ sites. The results showed that the EPR peak-to-peak linewidth of the Mn4+ spectrum increases with manganese concentration according to the theoretical equation DHpp=0.45+210.f.(1-f)80 (mT). This suggested that the exchange interaction between tetravalent manganese ions in strontium titanate has an approximate range of 0.96 nm, comparable to that of Gd3+ in the same compound.

scholarly journals Monitoring of the Mechanism of Mn Ions Incorporation into Quantum Dots by Optical and EPR Spectroscopy

Photonics ◽  
2019 ◽  
Vol 6 (4) ◽  
pp. 107
Author(s):  
Yuriy G. Galyametdinov ◽  
Dmitriy O. Sagdeev ◽  
Andrey A. Sukhanov ◽  
Violeta K. Voronkova ◽  
Radik R. Shamilov
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Magnetic Properties ◽  
Luminescent Properties ◽  
Manganese Concentration ◽  
Manganese Ions ◽  
Paramagnetic Resonance ◽  
Synthesis Of Nanoparticles ◽  
Zinc Sulfide Nanoparticles ◽  
Optical And Magnetic Properties ◽  
Electron Paramagnetic

Synthesis of nanoparticles doped with various ions can significantly expand their functionality. The conditions of synthesis exert significant influence on the distribution nature of doped ions and therefore the physicochemical properties of nanoparticles. In this paper, a correlation between the conditions of synthesis of manganese-containing cadmium sulfide or zinc sulfide nanoparticles and their optical and magnetic properties is analyzed. Electron paramagnetic resonance was used to study the distribution of manganese ions in nanoparticles and the intensity of interaction between them depending on the conditions of synthesis of nanoparticles, the concentration of manganese, and the type of initial semiconductor. The increase of manganese concentration is shown to result in the formation of smaller CdS-based nanoparticles. Luminescent properties of nanoparticles were studied. The 580 nm peak, which is typical for manganese ions, becomes more distinguished with the increase of their concentration and the time of synthesis.

Paramagnetic Defects in Benitoite

1991 ◽  
Vol 46 (7) ◽  
pp. 579-582 ◽  
Author(s):  
A. B. Vassilikou-Dova ◽  
K. Eftaxias
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Hyperfine Interaction ◽  
Relative Intensity ◽  
Room Temperature ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic ◽  
Magnetic Defects

Abstract In clear, blue, transparent bipyramidal crystals of the rare mineral benitoite, BaTiSi3O9, para­ magnetic defects have been investigated by electron paramagnetic resonance at room temperature and 9.43 GHz. They are attributed to Sn3+ and Fe3+ . A pair of satellites recorded for a wide angular rage around B0 || c (~40°) and a relative intensity of ~ 13% to the central signal is most likely due to hyperfine interaction with 117Sn and 119Sn isotopes. Attempts to bleach the colour of the crystal were unsuccessful.

S–d exchange interaction in GaN:Mn studied by electron paramagnetic resonance

2003 ◽  
Vol 83 (26) ◽  
pp. 5428-5430 ◽  
Author(s):  
Agnieszka Wolos ◽  
Maria Palczewska ◽  
Zbyslaw Wilamowski ◽  
Maria Kaminska ◽  
Andrzej Twardowski ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Exchange Interaction ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic

ELECTRON PARAMAGNETIC RESONANCE OF MANGANESE IN CESIUM AND AMMONIUM CHLORIDES

1967 ◽  
Vol 45 (10) ◽  
pp. 3381-3386 ◽  
Author(s):  
A. Forman ◽  
J. A. Van Wyk
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Fine Structure ◽  
Line Width ◽  
Structure Parameter ◽  
Manganese Ions ◽  
Spin Hamiltonian ◽  
Epr Spectrum ◽  
Paramagnetic Resonance ◽  
Hamiltonian Parameters ◽  
Electron Paramagnetic

The spin-Hamiltonian parameters describing the EPR spectrum of Mn2+ in CsCl crystals grown from solutilon have been determined. The line-width data are in agreement with the manganese ions being incorporated interstitially rather than substitutionally for Cs+ ions. From the work on Mn2+ in NH4Cl we infer that the fine structure parameter, D2, is negative.

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