Social Learning in Empowering Leadership: A Moderated Mediation Analysis

This study suggests a comprehensive social learning model of empowering leadership by focusing on the antecedents and processes of empowering leadership. Data were obtained from subordinate–supervisor dyads from the South Korean Army. The results support the social learning of empowering leadership. Specifically, the empowering leadership of high-level leaders facilitates that of low-level leaders, and this relationship is mediated by leader-leader exchange (LLX). Additionally, the results confirm the existence of a moderated mediation relationship among the constructs of interest; that is, the exchange ideology of low-level leaders moderates the relationship between LLX and their empowering leadership, such that the relationship is stronger when the exchange ideology is weak rather than strong. Thus, a weak exchange ideology strengthens the indirect effects of the empowering leadership of high-level leaders on that of low-level leaders through LLX. Theoretical and practical implications are also discussed.

Words beyond the Partial Deed: Prosocial Framing of a Partial-Trust Act Promotes Reciprocation between Strangers

Displaying partial trust in exchanges between strangers is a common practice, but it does not effectively promote reciprocation. This is an intriguing phenomenon that warrants investigations regarding social mechanisms that can promote reciprocation without changing the level of trust. We seek to examine, given a partial-trust act, whether framing the motive underlying the act as prosocial (mutually beneficial) can promote reciprocation in an exchange between strangers. Across three experiments in the United States, we found that trustor prosocial (vs. no-motive) framing can promote trustee reciprocation through trustee felt obligation and that this effect is particularly strong among trustees with a strong rather than weak exchange orientation. Concurrently, this prosocial framing effect can operate serially through trustee perceived invitation for exchange and felt obligation. Our findings help address the conundrum of promoting reciprocation without introducing deleterious uncertainty about social motives given a partial-trust act that is prevalent in exchanges at zero acquaintance.

[CrIII8NiII6]n+ Heterometallic Coordination Cubes

Three new heterometallic [CrIII8NiII6] coordination cubes of formulae [CrIII8NiII6L24(H2O)12](NO3)12 (1), [CrIII8NiII6L24(MeCN)7(H2O)5](ClO4)12 (2), and [CrIII8NiII6L24Cl12] (3) (where HL = 1-(4-pyridyl)butane-1,3-dione), were synthesised using the paramagnetic metalloligand [CrIIIL3] and the corresponding NiII salt. The magnetic skeleton of each capsule describes a face-centred cube in which the eight CrIII and six NiII ions occupy the eight vertices and six faces of the structure, respectively. Direct current magnetic susceptibility measurements on (1) reveal weak ferromagnetic interactions between the CrIII and NiII ions, with JCr-Ni = + 0.045 cm−1. EPR spectra are consistent with weak exchange, being dominated by the zero-field splitting of the CrIII ions. Excluding wheel-like structures, examples of large heterometallic clusters containing both CrIII and NiII ions are rather rare, and we demonstrate that the use of metalloligands with predictable bonding modes allows for a modular approach to building families of related polymetallic complexes. Compounds (1)–(3) join the previously published, structurally related family of [MIII8MII6] cubes, where MIII = Cr, Fe and MII = Cu, Co, Mn, Pd.

[CrIII8NiII6]n+ Heterometallic Coordination Cubes

Three new heterometallic [CrIII8NiII6] coordination cubes of formulae [CrIII8NiII6L24(H2O)12](NO3)12 (1), [CrIII8NiII6L24(MeCN)7(H2O)5](ClO4)12 (2) and [CrIII8NiII6L24Cl12] (3) (where HL = 1-(4-pyridyl)butane-1,3-dione), were synthesised using the paramagnetic metalloligand [CrIIIL3] and the corresponding NiII salt. The magnetic skeleton of each capsule describes a face-centred cube in which the eight CrIII and six NiII ions occupy the eight vertices and six faces of the structure, respectively. Direct current magnetic susceptibility measurements on (1) reveal weak ferromagnetic interactions between the CrIII and NiII ions, with JCr-Ni = +0.045 cm-1 . EPR spectra are consistent with weak exchange, being dominated by the zero-field splitting of the CrIII ions. Excluding wheel-like structures, examples of large heterometallic clusters containing both CrIII and NiII ions are rather rare, and we demonstrate that the use of metalloligands with predictable bonding modes allows for a modular approach to building families of related polymetallic complexes. Compounds (1)-(3) join the previously published, structurally related family of [MIII8MII6] cubes, where MIII = Cr, Fe and MII = Cu, Co, Mn, Pd. <br>

[CrIII8NiII6]n+ Heterometallic Coordination Cubes

Three new heterometallic [CrIII8NiII6] coordination cubes of formulae [CrIII8NiII6L24(H2O)12](NO3)12 (1), [CrIII8NiII6L24(MeCN)7(H2O)5](ClO4)12 (2) and [CrIII8NiII6L24Cl12] (3) (where HL = 1-(4-pyridyl)butane-1,3-dione), were synthesised using the paramagnetic metalloligand [CrIIIL3] and the corresponding NiII salt. The magnetic skeleton of each capsule describes a face-centred cube in which the eight CrIII and six NiII ions occupy the eight vertices and six faces of the structure, respectively. Direct current magnetic susceptibility measurements on (1) reveal weak ferromagnetic interactions between the CrIII and NiII ions, with JCr-Ni = +0.045 cm-1 . EPR spectra are consistent with weak exchange, being dominated by the zero-field splitting of the CrIII ions. Excluding wheel-like structures, examples of large heterometallic clusters containing both CrIII and NiII ions are rather rare, and we demonstrate that the use of metalloligands with predictable bonding modes allows for a modular approach to building families of related polymetallic complexes. Compounds (1)-(3) join the previously published, structurally related family of [MIII8MII6] cubes, where MIII = Cr, Fe and MII = Cu, Co, Mn, Pd. <br>

ZnII and CuII-Based Coordination Polymers and Metal Organic Frameworks by the of Use of 2-Pyridyl Oximes and 1,3,5-Benzenetricarboxylic Acid

The simultaneous use of 2-pyridyl oximes (pyridine-2 amidoxime, H2pyaox; 2-methyl pyridyl ketoxime, Hmpko) and 1,3,5-benzenetricarboxylic acid (H3btc) provided access to five new compounds, namely [Zn(H2btc)2(H2pyaox)2]•2H2O (1•2H2O), [Zn(Hbtc)(H2pyaox)2]n (2), [Cu(Hbtc)(H2pyaox)]n (3), [Cu(Hbtc)(HmpKo)]n (4) and [Cu2(Hbtc)2(Hmpko)2(H2O)2]•4H2O (5•4H2O). Among them, 3 is the first example of a metal-organic framework (MOF) containing H2pyaox. Its framework can be described as a 3-c uninodal net of hcb topology with the layers being parallel to the (1,0,1) plane. Furthermore, 3 is the third reported MOF based on a 2-pyridyl oxime in general. 2 and 4 are new members of a small family of coordination polymers containing an oximic ligand. 1–5 form 3D networks through strong intermolecular interactions. Dc magnetic susceptibility studies were carried out in a crystalline sample of 3 and revealed the presence of weak exchange interactions between the metal centres; the experimental data were fitted to a theoretical model with the fitting parameters being J = −0.16(1) cm−1 and g = 2.085(1). The isotropic g value was also confirmed by electronic paramagnetic resonance (EPR) spectroscopy. Reactivity studies were performed for 3 in the presence of metal ions; the reaction progress was studied and discussed for Fe(NO3)3 by the use of several characterization techniques, including single crystal X-ray crystallography and IR spectroscopy.

Проявление фрустраций основного состояния двумерной разбавленной модели Изинга в магнитокалорическом эффекте

The magnetocaloric effect is considered in the 2D dilute Ising model for various ratios of the parameters of inter-site repulsion of nonmagnetic impurities and exchange interaction. Numerical simulations using the classical Monte Carlo method on a square lattice shows that in the case of weak exchange at sufficiently high concentrations of nonmagnetic impurities, long-range ferromagnetic ordering is destroyed with the formation of isolated spin clusters in the ground state of the system. This leads to the appearance of a paramagnetic response of the system at zero temperature and a nonzero entropy of the ground state. In the paper, we discuss the possibility of detecting the frustration of the ground state using data on changes in magnetic entropy.

Weak exchange coupling effects leading to fast magnetic relaxations in a trinuclear dysprosium single-molecule magnet

In this work, we investigated the magnetic anisotropy and the influence of weak exchange interactions on the magnetic relaxations of a triangular type dysprosium single-molecule magnet.

Black sea marine litter pollution related to naval operations

The Black Sea, due to its weak exchange of waters and poor vertical circulation, has an increased sensibility to pollution. Even though this maritime basin is subject to numerous regulations at the national, regional, and international levels, the pollution issue is still actual and stringent. The present paper analyses the findings of three studies focused on marine litter issues and provide, in the concluding part, few directions which can improve the pollution prevention and containment effort. As the studies related to Black Sea litter pollution are scarce and fragmented, the authors took the opportunity and analyzed three different studies conducted in different periods and concluded that a significant part of marine debris is related to naval operations.

Studies of reproductive biology of seed plants in the Nikita Botanical Gardens

The paper presents the results of study the reproductive biology of a number of higher plants and shows the features of the formation of their generative structures, pollination, fertilization and seed formation. It has been established that the studied species have a high reproductive potential, they are characterized by the conjugacy in the development of male and female gametophyte and gametogenesis, the relationship and relevance of the development of flower elements and pollinating insects, etc. It is indicated that the limiting factors of high productive reproduction and reproduction of the studied plants are anomalies of the processes of formation of generative structures that occur during critical periods under the influence of extreme environmental factors, weak exchange of genetic information due to discontinuity of the area and small number of cenopopulations, as well as human impact. It is shown that the current state of natural cenopopulations of the studied rare species of the Crimean flora necessitates the development and strict observance of scientifically based measures for their protection.