scholarly journals Organotin pollution from pleasure craft at Paraty, a tourist area of Southeastern Brazil: amelioration or interference?

2013 ◽  
Vol 61 (3) ◽  
pp. 177-186 ◽  
Author(s):  
Camila de Leon Lousada Borges ◽  
Marcos Antonio dos Santos Fernandez ◽  
Ítalo Braga Castro ◽  
Gilberto Fillmann
Keyword(s):  
Organic Carbon ◽  
Chemical Analysis ◽  
Dissolved Organic Carbon ◽  
Endocrine Disruptors ◽  
Marine Ecosystems ◽  
Southeastern Brazil ◽  
Reference Sites ◽  
Mangrove Swamp ◽  
Small Vessels ◽  
Stramonita Haemastoma

Some organotin compounds, such as TBT, are endocrine disruptors and harm marine ecosystems. Even after the global ban on organotins, increasing imposex levels have been detected in Stramonita haemastoma analyzed in 2004 and 2011 in some locations at Paraty, a tourist area in southeastern Brazil. The results of this study indicate that particulate and dissolved organic carbon and xenoestrogens might be interfering in this syndrome's development, leading to underestimation of imposex evaluation. Chemical analysis of three mangrove swamp sediments in the area showed the presence of TBT (16.0 - 205.7 ng Sn g-1), DBT (10.1 - 16.4 ng Sn g-1) and MBT (10.1 - 10.2 ng Sn g-1) even at the reference sites. The concentrations of butyltins and the increased incidence of imposexat some stations indicate recent inputs of TBT in the study area due to its illegal use on small vessels.

scholarly journals Contamination of Arctic Lakes with Persistent Toxic PAH Substances in the NW Part of Wedel Jarlsberg Land (Bellsund, Svalbard)

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 411
Author(s):  
Sara Lehmann-Konera ◽  
Marek Ruman ◽  
Łukasz Franczak ◽  
Żaneta Polkowska
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Phenolic Compounds ◽  
Organic Compound ◽  
Organic Carbon ◽  
Chemical Analysis ◽  
Dissolved Organic Carbon ◽  
Aromatic Hydrocarbons ◽  
Arctic Lakes ◽  
Polar Regions ◽  
Polycyclic Aromatic

The expansion of glacier-free areas in polar regions favours the appearance of lakes in the non-glaciated parts of glacier basins. This paper presents the differentiation of organic compound concentrations in fifty-four Arctic lakes collected in four locations (Logne Valley, in the vicinity of the Scott, Renard and Antonia glaciers). We cover meteorological measurements, chemical analysis of sixteen dioxin-like compounds (Polycyclic Aromatic Hydrocarbons (PAHs)), formaldehyde (HCHO), sum parameters of phenolic compounds (∑phenols) and dissolved organic carbon (DOC). The most contaminated with PAH compounds were lakes exposed to the influence of the Greenland Sea (Logne Valley lakes) and to the prevailing winds (Scott and Renard lakes). Interpretation of the PAH compounds results allowed for identification of pyrogenic sources as the main sources of PAH compounds in the year 2012. The highest levels of HCHO and ∑phenols were observed for the Scott lakes, while the highest DOC levels were noted in Antonia lakes.

CHARACTERISATION OF DISSOLVED ORGANIC CARBON (DOC) LEACHED FROM LEAVES IN WATER

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Total Organic Carbon ◽  
Gas Chromatography Mass Spectrometry ◽  
Pyrolysis Gas ◽  
Pyrolysis Gas Chromatography ◽  
Chromatography Mass Spectrometry ◽  
Pinus Radiate

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>

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