Fluorinated ethers. Communication 2. Preparation of fluorinated ethers by the reaction of fluorinated alcohols with diazomethane, addition of polyfluoroalkyl iodides to alkenes, intermolecular dehydration, addition of perfluoroalkyl hypohalogenites to alkenes and pyrolysis of derivatives of perfluoro-2-alkoxypropionic acids

2021 ◽  
pp. 7-8
Author(s):  
Vadim Kornilov
1996 ◽  
Vol 22 (1) ◽  
pp. 184-189 ◽  
Author(s):  
Noriaki Nakazawa ◽  
Takeshi Sako ◽  
Takashi Nakane ◽  
Akira Sekiya ◽  
Masahito Sato ◽  
...  

2012 ◽  
Vol 77 (5) ◽  
pp. 667-683
Author(s):  
Radmila Pavlovic ◽  
Antonio Biondi ◽  
Maria Chiesa ◽  
Natasa Trutic ◽  
Mirjana Abramovic ◽  
...  

In view to develop a gas-chromatographic (GC) determination of the 3-nitrotyrosine (NY)/tyrosine (Y) ratio as a marker of nitro-oxidative stress, different reagents were tested with the objective of obtaining a single volatile fluorinated product for each amino acid by a one-step derivatization procedure. The heptafluorobutyric anhydride (HFBA) /heptafluorobutanol (HFBOH) mixture proved unsuccessful for NY and Y simultaneous analysis. The reaction with different chloroformates [isobutyl chlorofomate (iBuCF) and ethyl chloroformate (EtCF)] in the presence of different perfluorinated alcohols such as trifluoroethanol (TFEOH) and HFBOH was investigated. Combination EtCF/fluorinated alcohols yielded derivatives of NY and Y as single peaks suitable to the GC determination of the NY/Y ratio. The different behaviour of two amino acids in the used reaction mixtures and the parameters influencing the results were discussed.


1982 ◽  
Vol 85 (1) ◽  
pp. 257-263 ◽  
Author(s):  
A. Graja ◽  
M. Przybylski ◽  
B. Butka ◽  
R. Swietlik

2002 ◽  
Vol 23 (2) ◽  
pp. 125-207 ◽  
Author(s):  
Igor D. Sadekov ◽  
Alexander V. Zakharov ◽  
Alexander A. Maksimenko
Keyword(s):  

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