Mesophases Induced in the Binary Systems Consisting of the 4-Dimethylamino-4-Alkoxy and 4-Nitro-4-Alkoxy Derivatives of N-Benzylideneaniline

1986 ◽  
Vol 131 (3) ◽  
pp. 273-283 ◽  
Author(s):  
N. Homura ◽  
Y. Matsunaga ◽  
M. Suzuki
Keyword(s):  
Binary Systems ◽  
Derivatives Of

New possibilities of applications of the Barker quasi-lattice theory. Prediction of gE and hE of binary systems whose one component is formed by n-alkanes

1979 ◽  
Vol 44 (6) ◽  
pp. 1698-1714 ◽  
Author(s):  
Vladimír Dohnal ◽  
Robert Holub ◽  
Jiří Pick
Keyword(s):  
Aromatic Hydrocarbons ◽  
Lattice Theory ◽  
Binary Systems ◽  
Derived Relations ◽  
Orientation Effects ◽  
The Given ◽  
Derivatives Of ◽  
Arbitrary Component ◽  
Excess Quantities ◽  
Good Agreement

For binary systems of the type an arbitrary component + n-alkane we derived relations, on the basis of the Barker theory and on the basis of the group contribution concept, for predicting gE and hE from one system to another when the n-alkane length is changed. To carry out the prediction it is not necessary to evaluate any adjustable parameters. The developed method was tested using a large number of different systems covering alcohols, amines, ketones, esters, chlorinated derivatives of hydrocarbons, aromatic hydrocarbons and n-alkanes from n-pentane to n-hexadecane. The results of predictions are in very good agreement with experimental data in the cases, when the n-alkanes involved are not longer than n-decane. Systematic regular deviations in hE in the cases, when at least one of n-alkanes involved is longer, can be explained by the presence of orientation effects in the pure longer n-alkanes. The correction suggested by us for these effects improves considerably results obtained. The developed method appears to be suitable for the systematic prediction of excess quantities of systems of the given type and represents an effective test of the Barker theory.

scholarly journals How much do coulombic interactions stabilize a mesophase? Ion pair and non-ionic binary isosteric derivatives of monocarbaborates and carboranes

RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 53907-53914 ◽  
Author(s):  
Aleksandra Jankowiak ◽  
Ajan Sivaramamoorthy ◽  
Damian Pociecha ◽  
Piotr Kaszyński
Keyword(s):  
Binary Systems ◽  
Ion Pair ◽  
Coulombic Interactions ◽  
Derivatives Of

A comparison of two isosteric, ionic and non-ionic binary systems, provides a measure of coulombic interactions impact on mesophase stability in the absence of other factors.

Some Results of the Spectroscopic Study of Four Close Binary Systems of Early Spectral Types

1965 ◽  
Vol 5 ◽  
pp. 120-130
Author(s):  
T. S. Galkina
Keyword(s):  
Spectroscopic Study ◽  
Spectral Type ◽  
Spectroscopic Investigation ◽  
Binary Systems ◽  
Quantitative Information ◽  
Close Binary ◽  
Physical Parameters ◽  
Absorption And Emission ◽  
Close Binary Systems ◽  
Quantitative Estimates

It is necessary to have quantitative estimates of the intensity of lines (both absorption and emission) to obtain the physical parameters of the atmosphere of components.Some years ago at the Crimean observatory we began the spectroscopic investigation of close binary systems of the early spectral type with components WR, Of, O, B to try and obtain more quantitative information from the study of the spectra of the components.

Quasi-Periodic Oscillations in Dwarf Novae

1979 ◽  
Vol 46 ◽  
pp. 77-88
Author(s):  
Edward L. Robinson
Keyword(s):  
Binary Systems ◽  
Outer Edge ◽  
Light Curves ◽  
Close Binary ◽  
Bright Spot ◽  
Dwarf Novae ◽  
Periodic Oscillations ◽  
High Frequencies ◽  
Short Period ◽  
Typical Time

Three distinct kinds of rapid variations have been detected in the light curves of dwarf novae: rapid flickering, short period coherent oscillations, and quasi-periodic oscillations. The rapid flickering is seen in the light curves of most, if not all, dwarf novae, and is especially apparent during minimum light between eruptions. The flickering has a typical time scale of a few minutes or less and a typical amplitude of about .1 mag. The flickering is completely random and unpredictable; the power spectrum of flickering shows only a slow decrease from low to high frequencies. The observations of U Gem by Warner and Nather (1971) showed conclusively that most of the flickering is produced by variations in the luminosity of the bright spot near the outer edge of the accretion disk around the white dwarf in these close binary systems.

Bence-albee after 25 years: A new superior α-factor correction procedure for the quantitative analysis of oxides and silicates

1992 ◽  
Vol 50 (2) ◽  
pp. 1744-1745
Author(s):  
John T. Armstrong
Keyword(s):  
Quantitative Analysis ◽  
Electron Microprobe ◽  
Binary Systems ◽  
Correction Procedure ◽  
Geological Samples ◽  
The Past ◽  
Large Matrix ◽  
Computational Speed ◽  
Microprobe Data ◽  
Geological Sciences

One of the most cited papers in the geological sciences has been that of Albee and Bence on the use of empirical " α -factors" to correct quantitative electron microprobe data. During the past 25 years this method has remained the most commonly used correction for geological samples, despite the facts that few investigators have actually determined empirical α-factors, but instead employ tables of calculated α-factors using one of the conventional "ZAF" correction programs; a number of investigators have shown that the assumption that an α-factor is constant in binary systems where there are large matrix corrections is incorrect (e.g, 2-3); and the procedure’s desirability in terms of program size and computational speed is much less important today because of developments in computing capabilities. The question thus exists whether it is time to honorably retire the Bence-Albee procedure and turn to more modern, robust correction methods. This paper proposes that, although it is perhaps time to retire the original Bence-Albee procedure, it should be replaced by a similar method based on compositiondependent polynomial α-factor expressions.

Fractionation of polymethylene chains: An electron crystallographic investigation

1986 ◽  
Vol 44 ◽  
pp. 794-795
Author(s):  
Douglas L. Dorset
Keyword(s):  
Cross Section ◽  
Binary Systems ◽  
Linear Chain ◽  
Pure Component ◽  
Organic Substrates ◽  
Crystallographic Investigation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Molecular Sizes ◽  
The Stability

A variety of linear chain materials exist as polydisperse systems which are difficultly purified. The stability of continuous binary solid solutions assume that the Gibbs free energy of the solution is lower than that of either crystal component, a condition which includes such factors as relative molecular sizes and shapes and perhaps the symmetry of the pure component crystal structures.Although extensive studies of n-alkane miscibility have been carried out via powder X-ray diffraction of bulk samples we have begun to examine binary systems as single crystals, taking advantage of the well-known enhanced scattering cross section of matter for electrons and also the favorable projection of a paraffin crystal structure posited by epitaxial crystallization of such samples on organic substrates such as benzoic acid.

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