scholarly journals A safe way of performing dangerous experiments. III. The safety box. 2. Demonstrating the reactions of alkali metals with concentrated oxoacids

2021 ◽  
Vol 40 (1) ◽  
pp. 123
Author(s):  
Miha Bukleski ◽  
Vladimir Petruševski ◽  
Slavica Aleksova

A way to conciliate one of the most dangerous reactions and at the same time, a way of a systematic approach towards studying the reaction of the alkali metals and acids, has been offered. Explanation of the observed phenomena considering the extent of how vigorous the reaction is and the circumstances contributing to the rate of reaction due to the precipitate formation or water presence, are discussed.  In this paper, the reaction between some concentrated aqueous solutions of oxoacids (HNO3, H3PO4, H2SO4, HClO4) and alkali metals (Li, Na, K) are considered. Video clips of the experiments were prepared as an aid for those instructors that lack experience and/or the necessary materials. This publication is a continuation of the previously published article about the reaction of alkali metals with hydrohalic acids and is part of the series of publications under the general title “A Safe Way of Performing Dangerous Experiments”.

1985 ◽  
Vol 122 (5) ◽  
pp. 475-479 ◽  
Author(s):  
G.W. Neilson ◽  
D. Schiöberg ◽  
W.A.P. Luck

1969 ◽  
Vol 113 (4) ◽  
pp. 611-615 ◽  
Author(s):  
J. Leichter ◽  
M. A. Joslyn

Results are presented on the rate of thiamin cleavage by sulphite in aqueous solutions as affected by temperature (20–70°), pH(2·5–7·0), and variation of the concentration of either thiamin (1–20μm) or sulphite (10–5000μm as sulphur dioxide). Plots of the logarithm of percentage of residual thiamin against time were found to be linear and cleavage thus was first-order with respect to thiamin. At pH5 the rate was also found to be proportional to the sulphite concentration. In the pH region 2·5–7·0 at 25° the rate constant was 50m−1hr.−1 at pH5·5–6·0, and decreased at higher or lower pH values. The rate of reaction increased between 20° and 70°, indicating a heat of activation of 13·6kcal./mole.


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