scholarly journals The New Anode Environmentally Friendly for Water Electrolysis Based on 430 Stainless Steel Coated with Recycled Cobalt from Spent Lithium–Ion Batteries

Author(s):  
Eric M. Garcia ◽  
Hosane A. Taroco

In this paper, a new anode environmentally friendly for hydrogen production was developed based on 430 stainless steel with an electrodeposited cobalt layer. The novelty of this work is the cobalt source once the electrodeposition bath was obtained from recycling of spent Li-ion batteries cathode with composition LiCoO2. The electrodeposited cobalt behaves as supercapacitor in KOH 1M. In the linear voltammetry in KOH 1M, when the overpotential reaches 370 mV, the anodic density current for 430 SS/Co is 19 mA cm−2. Thus, the anode developed in this paper achieves the double of density current with half of production cost if compared with 316SS. Moreover the anode construction described in this paper is an excellent option for Li- ion battery recycling.

Recycling ◽  
2018 ◽  
Vol 3 (3) ◽  
pp. 42 ◽  
Author(s):  
Eric Garcia ◽  
Hosane Taroco

In this paper, a new environmentally-friendly anode for hydrogen production was developed based on 430 stainless steel with an electrodeposited cobalt layer. The novelty of this work is the cobalt source once the electrodeposition bath was obtained from acid dissolution of a spent Li-ion battery cathode. The oxygen evolution reaction on electrodeposited cobalt in 1 M KOH is compatible with the E. Kobussen mechanism. The water discharge is related with reaction determinant step in low overpotential. The cobalt electrodeposition (3 Ccm−2) promotes a significant improvement of 430 stainless steel anodic properties for oxygen evolution reaction. When the overpotential reaches 370 mV, the density current for 430 stainless steel with electrodeposit cobalt is 19 mA·cm−2 against 0.80 mA·cm−2 for 430 stainless steel without cobalt. Thus, the anode construction described in this paper is an excellent option for Li-ion battery recycling.


Ionics ◽  
2016 ◽  
Vol 22 (5) ◽  
pp. 735-741 ◽  
Author(s):  
Eric M. Garcia ◽  
Hosane A. Taroco ◽  
Rozana Z. Domingues ◽  
Tulio Matencio ◽  
Sicele L. A. Gonçalves

Author(s):  
A. Mancha

Today the United States is heavily reliant on the lithium-ion battery as most portable devices and electronics run on it. Current innovations are also looking on how to maximize it on the grid and transportation. This paper will look at three sovereign states and their current initiatives on Li-ion battery recycling: US, European Union, and China. The term initiative is used loosely as the information is not permanent in most policies or plans. Li-ion battery recycling initiatives are crucial to look at because used and wasted Li-ion batteries can disrupt public health and Li-ion batteries are expected to be a factor for effective material supply for future battery production especially in transportation, like the Tesla Roadster.


Author(s):  
Mohamed Aklalouch ◽  
Hajer Bouaddi ◽  
Ghita Garhi ◽  
Abdelfattah Mahmoud ◽  
Mohammed Mansori ◽  
...  

ChemSusChem ◽  
2016 ◽  
Vol 9 (14) ◽  
pp. 1804-1813 ◽  
Author(s):  
Mosè Casalegno ◽  
Franca Castiglione ◽  
Marco Passarello ◽  
Andrea Mele ◽  
Stefano Passerini ◽  
...  

2021 ◽  
Vol 1044 ◽  
pp. 3-14
Author(s):  
Ahmad Jihad ◽  
Affiano Akbar Nur Pratama ◽  
Salsabila Ainun Nisa ◽  
Shofirul Sholikhatun Nisa ◽  
Cornelius Satria Yudha ◽  
...  

Li-ion batteries are one of the most popular energy storage devices widely applied to various kinds of equipment, such as mobile phones, medical and military equipment, etc. Therefore, due to its numerous advantages, especially on the NMC type, there is a predictable yearly increase in Li-ion batteries' demand. However, even though it is rechargeable, Li-ion batteries also have a usage time limit, thereby increasing the amount of waste disposed of in the environment. Therefore, this study aims to determine the optimum conditions and the potential and challenges from the waste Li-ion battery recycling process, which consists of pretreatment, metal extraction, and product preparation. Data were obtained by studying the literature related to Li-ion battery waste's recycling process, which was then compiled into a review. The results showed that the most optimum recycling process of Li-ion batteries consists of metal extraction by a leaching process that utilizes H2SO4 and H2O2 as leaching and reducing agents, respectively. Furthermore, it was proceeding with the manufacturing of a new Li-ion battery.


2019 ◽  
pp. 223-237
Author(s):  
Daniel Horn ◽  
Jörg Zimmermann ◽  
Andrea Gassmann ◽  
Rudolf Stauber ◽  
Oliver Gutfleisch

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