NanoGram Detection of Drilling Fluids Additives for Uncertainty Reduction in Surface Logging

Manual sampling rock cuttings off the shale shaker for lithology and petrophysical characterization is frequently performed during mud logging. Knowing the depth origin where the cuttings were generated is very important for correlating the cuttings to the petrophysical characterization of the formation. It is a challenge to accurately determine the depth origin of the cuttings, especially in horizontal sections and in coiled tubing drilling, where conventional logging while drilling is not accessible. Additionally, even in less challenging drilling conditions, many factors can contribute to an inaccurate assessment of the depth origin of the cuttings. Inaccuracies can be caused by variation of the annulus dimension used to determine the lag time (and thus the depth of the cuttings), by the shifting or scrambling of cuttings during their return trip back to the surface, and by the mislabelling of the cuttings during sampling. In this work, we report the synthesis and application of polystyrenic nanoparticles (NanoTags) in labeling cuttings for depth origin assessment. We have successfully tagged cuttings using two NanoTags during a drilling field test in a carbonate gas well and demonstrated nanogram detection capability of the tags via pyrolysis-GCMS using an internally developed workflow. The cuttings depth determined using our tags correlates well with the depth calculated by conventional mud logging techniques.