scholarly journals EFFECT OF HOT CORROSION AND OXIDATION ON COBALT - BASE SUPERALLOYS COATED BY ALUMINUM WITH PRESENCE OF THERMAL BARRIER ZRO2 AND MIXTURE OF (NACL) AND (NA2SO4) STEAMSALTSAT HIGH TEMPERATURES

2021 ◽  
Vol 9 (07) ◽  
pp. 954-969
Author(s):  
Khudhur A. Saleh ◽  
◽  
Mahmood A. Hamood ◽  
Nawfal Y. Jahmeel ◽  
◽  
...  
Keyword(s):  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Degradation Behavior ◽  
Barrier Coatings ◽  
Bond Coating ◽  
First Order ◽  
Cobalt Base ◽  
Corrosion And Oxidation ◽  
Base Superalloy ◽  
Thermally Grown

The aim of the study was to investigate the Mechanisms properties of thermal barrier coatings (TBCs) to enhance of performance evaluation characteristics and develop TBCs.Cobalt –base superalloy has been used as a substrate and zirconium stabilized Aluminum as ceramic topcoat , in addition the study include degradation behavior of system during thermal cycling (3hr per cycle in furnace) the failure of the aluminized was due to thermally grown oxide (TGO) interface. The fractures propagatethrough the interface and produce a deformation of the bond coating . the effect of cycle will result a spallation failure of the TBCsand this is also corresponding to a slightdegradation .The steam of salt (Nacl)and(Na2So4) mixture will affecton the coating lifetimes .The high temperature have a strong effect thermally grown oxide (TGO) which consistent with a first order growth of scale failer variation.

Comprehensive Numerical Simulation on Thermally Grown Oxide and Internal Stress Evolutions in Thermal Barrier Coatings

2019 ◽  
Vol 827 ◽  
pp. 343-348
Author(s):  
Ryuta Nakajima ◽  
Hiroaki Katori ◽  
Masayuki Arai ◽  
Kiyohiro Ito
Keyword(s):  
Constitutive Equation ◽  
Internal Stress ◽  
Gas Turbine ◽  
Thermal Barrier Coatings ◽  
Ceramic Coating ◽  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Bond Coating ◽  
Thermally Grown

TBCs (Thermal Barrier Coatings) is deposited on gas turbine blades to protect the substrate from a combustion gas flow. One of the serious problems occurred in gas turbine is TBC delamination which is caused by startup, steady and stop operation in service. TBC delamination results from subjecting to both cyclic thermal stress and evolution of internal stress due to thermally grown oxide (TGO). In this study, the finite element code which can simulate thermal and internal stress fields generated in TBC was developed. The developed code involves the follows: inelastic constitutive equation for ceramic coating, bilinear-type constitutive equation for bond coating and Chaboche-type inelastic constitutive equation for the substrate, and mass transfer equation in consideration of oxygen diffusion and chemical reaction with aluminum. Thermal cycling simulation was conducted using the developed code. It was confirmed that maximum stress and its location in the ceramic coating/bond coating interface were matched with the associated experimental results.

Determination of the Structure and Chemistry of Thermally Grown Oxides in Thermal Barrier Coatings

1999 ◽  
Vol 5 (S2) ◽  
pp. 854-855
Author(s):  
M.R. Brickey ◽  
J.L. Lee
Keyword(s):  
Thermal Barrier Coatings ◽  
Nickel Aluminide ◽  
Physical Vapor Deposition ◽  
Thermal Exposure ◽  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Engine Operation ◽  
Barrier Coatings ◽  
Combustion Gas ◽  
Thermally Grown

Thermal barrier coatings (TBCs) insulate gas turbine hot section components from the hot (∽1200 - 1450°C) combustion gas exhaust stream. An airline company can save millions of dollars per year by using TBCs to protect vital engine components and to improve fuel efficiency. TBCs typically consist of an 8 wt.% yttria-partially-stabilized zirconia (YPSZ) ceramic topcoat deposited on a platinum-nickel-aluminide (Pt-Ni-Al) bondcoat covering a nickel-based superalloy substrate. Thermal exposure during YPSZ electron beam-physical vapor deposition (EB-PVD) and engine operation promotes the formation of a thermally grown oxide (TGO) between the Pt-Ni-Al and the YPSZ layers. Stresses can develop at the Pt-Ni-Al/TGO and TGO/YPSZ interfaces due to TGO growth and thermal expansion coefficient mismatch. These stresses eventually cause spallation of the YPSZ, leaving the metallic substrate vulnerable to high temperature degradation since exhaust temperatures are often higher than the melting temperature of most nickel-based superalloys (∽1200 - 1450°C).

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