scholarly journals Synthesis and Characterization of Poly(Ԑ-caprolactone-b-Styrene) Block Copolymer by Ring-Opening Polymerization and Reversible Addition-Fragmentation Chain Transfer Polymerization

2020 ◽  
pp. 1759-1766
Author(s):  
Bedrettin SAVAŞ ◽  
Temel ÖZTÜRK
Keyword(s):  
Block Copolymer ◽  
Ring Opening ◽  
Chain Transfer ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Synthesis and characterization of bead-like poly(N-isopropylacrylamide) copolymers with double decker silsesquioxane in the main chains

2015 ◽  
Vol 6 (2) ◽  
pp. 256-269 ◽  
Author(s):  
Kun Wei ◽  
Lei Wang ◽  
Lei Li ◽  
Sixun Zheng
Keyword(s):  
Chain Transfer ◽  
Main Chain ◽  
Synthesis And Characterization ◽  
Double Decker ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

A bead-like PNIPAAm copolymer with double-decker silsesquioxane (DDSQ) in the main chain was synthesized via a reversible addition–fragmentation chain transfer polymerization (RAFT) approach.

Self-Assembly of Amphiphilic Block Copolymer in Aqueous Solutions Tuned by Host-Guest Inclusion Complexation

2012 ◽  
Vol 487 ◽  
pp. 663-667
Author(s):  
Yu Long Shuai ◽  
Mi Zhou ◽  
Xin Qian
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Ring Opening ◽  
Chain Transfer ◽  
Gene Transfection ◽  
Inclusion Complexation ◽  
Ring Opening Polymerization ◽  
Isopropyl Acrylamide ◽  
Reversible Addition ◽  
Copolymer Poly

The block copolymer poly (ε-caprolactone)-b-poly (N-isopropyl acrylamide) (PCL-b-PNIPAM) is synthesized via the combination of ring-opening polymerization (ROP) and reversible addition-fragmentation chain transfer (RAFT). PCL-b-PNIPAM can self-assemble into the micelles taking PCL as the cores and PNIPAM as the shells. Add α-CD into the micelles, because the inclusion complexation of α-CD to PCL chains and phenols is stronger than that to PCL, to regulate the hydrophilic and hydrophobic features of PCL chain. So PCL-b-PNIPAM block copolymers have potential application in drug delivery and gene transfection.

Sign in / Sign up

Export Citation Format

Share Document