scholarly journals Ultrasonic and Microwave effects on the Benzamide/Sulfuryl Chloride mediated benzoylation of Benzene derivatives under Vilsmeier-Haack conditions

2017 ◽  
Vol 2 (Issue 2. pp. 94-185) ◽  
pp. 94-104
Author(s):  
Marri Venkateswarlu ◽  
Mukka Satish Kumar ◽  
Chinna Rajanna Kamatala ◽  
Purugula Venkanna ◽  
Pondichery Kuppuswamy Saiprakash
Keyword(s):  
Sulfuryl Chloride ◽  
Benzene Derivatives ◽  
Microwave Effects

Coefficients of molecular homeomorphism and crystalline isomorphism in the series of para-disubstituted benzene derivatives

1991 ◽  
Vol 88 ◽  
pp. 509-514 ◽  
Author(s):  
MA Cuevas Diarte ◽  
T Calvet ◽  
M Labrador ◽  
E Estop ◽  
HAJ Oonk ◽  
...  
Keyword(s):  
Benzene Derivatives ◽  
Disubstituted Benzene

Arene Dearomatization via Radical Hydroarylation

2019 ◽  
Author(s):  
Autumn Flynn ◽  
Kelly McDaniel ◽  
Meredith Hughes ◽  
David Vogt ◽  
Nathan Jui
Keyword(s):  
Precious Metal ◽  
Room Temperature ◽  
Aryl Halide ◽  
Solvent System ◽  
Benzene Derivatives ◽  
Green Solvent ◽  
Photocatalytic System

A photocatalytic system for the dearomative hydroarylation of benzene derivatives has been developed. Using a combination of an organic photoredox catalyst and an amine reductant, this process operates through a reductive radical-polar crossover mechanism where aryl halide reduction triggers a regioselective cyclization event, giving rise to a range of complex spirocyclic cyclohexadienes. This light-driven protocol functions at room temperature in a green solvent system (aq. MeCN), without the need for precious metal-based catalysts or reagents, or the generation of stoichiometric metal byproducts.

Ene-type chlorination of functionalised olefins using sulfuryl chloride in the absence of a base

2002 ◽  
Vol 2002 (3) ◽  
pp. 110-111 ◽  
Author(s):  
Nana K. Bhamare ◽  
Gaifa Lai ◽  
Wayne K. Anderson
Keyword(s):  
Sulfuryl Chloride

Toxicity of Para-Chloro Substituted Benzene Derivatives in the Microtox™ Test

1985 ◽  
Vol 20 (2) ◽  
pp. 36-43 ◽  
Author(s):  
Klaus L.E. Kaiser ◽  
Juan M. Ribo ◽  
Brian M. Zaruk
Keyword(s):  
General Formula ◽  
Functional Group ◽  
Structural Parameters ◽  
Systematic Investigation ◽  
Photobacterium Phosphoreum ◽  
Benzene Derivatives ◽  
Quantitative Structure ◽  
Chlorinated Benzenes ◽  
Chloro Derivatives ◽  
Derivatives Of

Abstract This paper gives the results of part of a systematic investigation into contaminant toxicity to Photobacterium phosphoreum in the Microtox™ test. Reported are the toxicity values for 39 para-chloro substituted benzene derivatives of the general formula l-Cl-C6h4-4-X=CH2CH(NH2)COOH, F, SO2NH2, OCH2COOH, CH2COOH, CONHNH2, NHCOCH3, CONH2, CH=CHCOOH, SeOOH, CH2NH2, CH2CH2NH2, NO2, H, CF3, CHO, CH2OH, OH, CH3, CCl3, COCH3, COOH, NH2, SO2C6H5, Cl, CH2COCH3, COCl, CN, OCH3, NCO, NHCH3, I, COC6H5, CH2Cl, SH, CH2SH, NCS, CH2CN and SO2C6H4Cl. Except for the last compound, whose solubility is below the required concentration, the toxicities increase in the presented order with a total range of more than three orders of magnitude. The data are discussed in terms of quantitative structure-toxicity correlations with compound-specific structural parameters. In combination with a previously developed submodel on chlorinated benzenes, phenols, nitrobenzenes and anilines, the observed relationships allow the prediction of the toxicity of some 780 possible chloro derivatives of the general formula C6H5-nClnX, where n=<5 and X is a functional group as listed above.

Simple Preparation of Methyl 4-Chloromethyl- and Methyl 5-Chloromethyl-2-thiophenecarboxylate

1992 ◽  
Vol 57 (7) ◽  
pp. 1483-1486 ◽  
Author(s):  
Václav Kozmík ◽  
Jaroslav Paleček
Keyword(s):  
Selective Reduction ◽  
Sulfuryl Chloride ◽  
Simple Preparation

Selective reduction of a mixture of methyl 4-chloromethyl-2-thiophenecarboxylate (I) and the 5-chloromethyl isomer II, prepared by chloromethylation of methyl 2-thiophenecarboxylate (III), gave pure 4-chloromethyl derivative I and 5-methyl-2-thiophenecarboxylate (V) which on treatment with sulfuryl chloride was converted into the 5-chloromethyl isomer II.

NMR-spektroskopische Untersuchungen über zwischenmolekulare Wechselwirkungen bei Benzolderivaten und Pyrrol / NMR-Spectroscopic Investigation of the Intermolecular Reactions of Benzene Derivatives and Pyrrole

1969 ◽  
Vol 24 (11) ◽  
pp. 1365-1370 ◽  
Author(s):  
H.-H. Perkampus ◽  
U. Krüger ◽  
W. Krüger
Keyword(s):  
Dipole Moment ◽  
Temperature Dependence ◽  
Aromatic Compounds ◽  
Spectroscopic Investigation ◽  
Chemical Shifts ◽  
Benzene Derivatives ◽  
Intermolecular Reactions ◽  
Proton Chemical Shifts

The proton chemical shifts of aromatic compounds are strongly concentration dependent. Moreever, for molecules with a dipole moment a temperature dependence of the proton chemical shifts is observed. For hemellitone, p-methylanisole, o-chlortoluene, p-chlortoluene, pyrrole and N-methyl-pyrrole the enthalpies of a dipole-dipole association between -0,7 and -1,8 Kcal could be estimated by NMR measurements combined with the temperature dependence in the whole range of the molefraction (0 → 1).

Effect of Benzene Derivatives as Guest Molecules on Semiconductor Properties of MOF‐199

2021 ◽  
Vol 6 (3) ◽  
pp. 425-429
Author(s):  
Haleemathul Zahadiya ◽  
Ruwan P. Wijesundera ◽  
Champika V. Hettiarachchi ◽  
Ishanie R. Perera
Keyword(s):  
Benzene Derivatives ◽  
Guest Molecules ◽  
Semiconductor Properties

ChemInform Abstract: ANODIC FLUOROALKYLATION OF BENZENE DERIVATIVES

1978 ◽  
Vol 9 (31) ◽  
Author(s):  
V. A. GRINBERG ◽  
V. R. POLISHCHUK ◽  
L. S. GERMAN ◽  
L. S. KANEVSKII ◽  
YU. B. VASIL'EV
Keyword(s):  
Benzene Derivatives

scholarly journals A Reversed-phase HPLC Study of the Complexation of Benzene Derivatives Guest Molecules with 5,17-bis(N-Tolyliminomethyl)-25,27-dipropoxycalix[4]arene in Acetonitrile–Water Solution

1999 ◽  
Vol 23 (1) ◽  
pp. 60-61
Author(s):  
O. I. Kalchenko ◽  
A. V. Solovyov ◽  
J. Lipkowski ◽  
V. I. Kalchenko
Keyword(s):  
Stability Constants ◽  
Water Solution ◽  
Reversed Phase ◽  
Benzene Derivatives ◽  
Reversed Phase Hplc ◽  
Guest Molecules ◽  
Hplc Study

Stability constants of the host–guest complexes of 5,17-bis( N-tolyliminomethyl)-25,27-dipropoxycalix[4]arene with benzene derivatives were determined by reversed-phase HPLC in acetonitrile–water solution.

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