scholarly journals Detailed comparison of the performance between a simple and a modified mono-block-layer-built type solid oxide fuel cell

2021 ◽  
pp. 170-170
Author(s):  
José Ramírez-Minguela ◽  
Jorge Alfaro-Ayalaa ◽  
Agustín Uribe-Ramírez ◽  
Jesús Minchaca-Mojica ◽  
Beatriz Ruiz-Camacho ◽  
...  

A detailed comparison of the performance between a simple Mono-Block-Layer-Build (MOLB) type Solid Oxide Fuel Cell (SOFC) geometry and a MOLB type SOFC with an embedded porous pipe in the air supply channel is carried out. The study considers constant and variable porosities along the porous pipe, fed with an airflow in a counter-flow arrangement. Four cases are analyzed: a) without the porous pipe, b) with a pipe of constant porosity, c) with two different porosities, and d) with four variable porosities. This work is based in a three-dimensional Computational Fluid Dynamics (CFD) model that considers the phenomena of mass transfer, heat transfer, species transport and electrochemical reactions. Detailed comparisons of the voltage, temperature and species concentration are illustrated. The electrode-electrolyte interface contours of species concentration, temperature and electric fields are compared. The results show that there is approximately twice the current density in the geometry that considers the two different porosities compared to the simple geometry. The consumption of hydrogen has the same behavior for the entire tested current density, while the availability of oxygen at the cathode-electrolyte interface is improved in cases with porous pipe compared to the simple MOLB-type geometry. The use of a porous pipe embedded in the air channel showed that it is possible to have a wider operating range of a MOLB-type SOFC, and allowed to obtain a more homogeneous temperature distribution on the electrode-electrolyte interface of the SOFC, consequently, there is the possibility of reducing the thermal stress in the SOFC.

2014 ◽  
Vol 79 ◽  
pp. 461-469 ◽  
Author(s):  
J.J. Ramírez-Minguela ◽  
J.M. Mendoza-Miranda ◽  
V.D. Muñoz-Carpio ◽  
V.H. Rangel-Hernández ◽  
V. Pérez-García ◽  
...  

Author(s):  
George J. Nelson ◽  
Comas Haynes ◽  
William Wepfer

Analytical models have been developed to describe the partial pressure distributions of reactants within solid oxide fuel cell (SOFC) electrodes and introduce the concept of a reactant depletion current density. These existing analytical expressions for two-dimensional reactant partial pressure distributions and the reactant depletion current density are presented in non-dimensional form. Performance metrics for SOFC electrodes are developed including a correction factor that can be applied to button-cell predictions of pressure distribution and two forms of dimensionless reactant depletion current density. Performance predictions based on these metrics are compared to numerical predictions of partial pressure and depletion current density based on a finite element solution of the dusty-gas model (DGM) within SOFC electrodes. It is shown that the pressure correction factor developed provides a reasonable prediction of interconnect geometry effects. Thus, it is presented as a modeling tool that can be applied to translate component level fidelity to cell and stack level models. The depletion current density metrics developed are used to present basic design maps for SOFC unit cell cross-sections. These dimensionless forms of the depletion current density quantify the influence of sheet resistance effects on reactant depletion and can predict the deviation from the limiting current behavior predicted using a button-cell model.


2015 ◽  
Vol 40 (24) ◽  
pp. 7895-7902 ◽  
Author(s):  
Selahattin Celik ◽  
Beycan Ibrahimoglu ◽  
Mahmut D. Mat ◽  
Yuksel Kaplan ◽  
T. Nejat Veziroglu

Author(s):  
Mehdi Borji ◽  
Kazem Atashkari ◽  
Nader Nariman-zadeh ◽  
Mehdi Masoumpour

Solid oxide fuel cell is a promising tool for distributed power generation systems. This type of power system will experience different conditions during its operating life. The present study aims to simulate mathematically a direct internal reforming planar type anode supported solid oxide fuel cell considering mass and energy conservation equations along with a complete electrochemical model. Two main reactions, namely water–gas shift reaction and methane steam reforming reaction, are considered as two dominant reactions occurring in a fuel cell. Such a model may be employed to examine the effect of different operating conditions on main solid oxide fuel cell parameters, such as temperature gradients, power, and efficiency. Furthermore, using such mathematical model, a multi-objective optimization procedure can be applied to determine maximum cell efficiency and output power under constraints such as the allowable temperature difference and limited operating potential. The selected design variables are air ratio, fuel utilization, average current density, steam to carbon ratio, and pre-reforming rate of methane. It has been revealed that any increase in pre-reforming rate of methane and steam to carbon ratio of the entering fuel will lead to efficiency penalty and more uniform temperature distribution along the cell. In addition, the more average current density increases, the less electric efficiency is achieved, and on the other hand, the more temperature difference along the cell is seen. Besides, it is shown that some interesting and important relationships as useful optimal design principles involved in the performance of solid oxide fuel cells can be discovered by Pareto based multi-objective optimization of the mathematically obtained model representing their electric performance. Such important optimal principles would not have been obtained without the use of both mathematical modeling and the Pareto optimization approach.


2013 ◽  
Vol 712-715 ◽  
pp. 1325-1329 ◽  
Author(s):  
Wei Kong ◽  
Shi Chuan Su ◽  
Xiang Gao ◽  
Dong Hui Zhang ◽  
Zi Dong Yu

The influence of anode current collector layer (ACCL) thickness is studied for different ACCL porosity and different pitch width. The results shows conclusively that the output current density depends strongly on the ACCL thickness and a suitable choice of the ACCL thickness is very important for the high performance of a SOFC stack. Furthermore, the optimal ACCL thickness is found to be dependent linearly on the pitch width and the parameters for the linearity are given.


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