Two-dimensional, free, turbulent mixing between a uniform stream and a cavity flow is investigated experimentally in a plug nozzle, a geometry that generates idealized mixing layer conditions. Upstream viscous layer effects are minimized through the use of a sharp-expansion plug nozzle. Experimental velocity profiles exhibit close agreement with both similarity analyses and with error function predictions. Refrigerant-12 was injected into the cavity and concentration profiles were obtained using a gas chromatograph. Spreading factors for momentum and mass were determined. Two methods are presented to determine the average turbulent Schmidt number. The relation Sct = Sc is suggested by the data for Sc < 2.0.