scholarly journals A Modular, Self-Assembling Metallaphotocatalyst for Cross Couplings Using the Full Visible-Light Spectrum

2020 ◽  
Author(s):  
Susanne Reischauer ◽  
Volker Strauss ◽  
Bartholomäus Pieber
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Excited States ◽  
Catalyst System ◽  
Chemical Energy ◽  
Modular Approach ◽  
Nickel Catalysis ◽  
Light Spectrum ◽  
Dye Sensitized ◽  
Self Assembling

The combination of nickel- and photocatalysis has unlocked a variety of cross couplings. These protocols rely on a few photocatalysts that can only convert a small portion of visible light (<500 nm) into chemical energy. Many dyes that absorb a much broader spectrum of light are not applicable due to their short-lived excited states. Here we describe a self-assembling catalyst system that overcomes this limitation. The modular approach combines nickel catalysis with dye-sensitized titanium dioxide and can be used to catalyze various bond formations. <br>

scholarly journals A Modular, Self-Assembling Metallaphotocatalyst for Cross Couplings Using the Full Visible-Light Spectrum

2020 ◽  
Author(s):  
Susanne Reischauer ◽  
Volker Strauss ◽  
Bartholomäus Pieber
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Excited States ◽  
Catalyst System ◽  
Chemical Energy ◽  
Modular Approach ◽  
Nickel Catalysis ◽  
Light Spectrum ◽  
Dye Sensitized ◽  
Self Assembling

The combination of nickel- and photocatalysis has unlocked a variety of cross couplings. These protocols rely on a few photocatalysts that can only convert a small portion of visible light (<500 nm) into chemical energy. Many dyes that absorb a much broader spectrum of light are not applicable due to their short-lived excited states. Here we describe a self-assembling catalyst system that overcomes this limitation. The modular approach combines nickel catalysis with dye-sensitized titanium dioxide and can be used to catalyze various bond formations. <br>

scholarly journals Visible Light Photocatalytic Properties of Modified Titanium Dioxide Nanoparticles via Aluminium Treatment

2016 ◽  
Vol 11 (1) ◽  
pp. 40 ◽  
Author(s):  
Dessy Ariyanti ◽  
Junzhe Dong ◽  
Junye Dong ◽  
Wei Gao
Keyword(s):  
Titanium Dioxide ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Titanium Dioxide Nanoparticles ◽  
Wide Bandgap ◽  
Reaction Engineering ◽  
Photocatalytic Properties ◽  
Light Spectrum ◽  
Visible Light Range ◽  
Visible Light Photocatalytic

<p>Titanium dioxide (TiO2) has gained much attentions for the last few decades due to its remarkable performance in photocatalysis and some other related properties. However, its wide bandgap (~3.2 eV) can only absorb UV energy which is only ~5% of solar light spectrum. The objective of this research was to improve the photocatalytic activity of TiO2 by improving the optical absorption to the visible light range. Here, colored TiO2 nanoparticles range from light to dark grey were prepared via aluminium treatment at the temperatures ranging from 400 to 600 oC. The modified TiO2 is able to absorb up to 50% of visible light (400-700 nm) and shows a relatively good photocatalytic activity in organic dye (Rhodamine B) degradation under visible light irradiation compared with the commercial TiO2. Copyright © 2016 BCREC GROUP. All rights reserved</p><p><em>Received: 10th November 2015; Revised: 7th January 2016; Accepted: 7th January 20 </em></p><p><strong>How to Cite</strong>: Ariyanti, D., Dong, J.Z., Dong, J.Y., Gao, W. (2016). Visible Light Photocatalytic Properties of Modified Titanium Dioxide Nanoparticles via Aluminium Treatment. <em>Bulletin of Chemical Reaction Engineering &amp; Catalysis</em>, 11 (1): 40-47. (doi:10.9767/bcrec.11.1.414.40-47)</p><p><strong>Permalink/DOI</strong>: <a href="http://dx.doi.org/10.9767/bcrec.11.1.414.40-47">http://dx.doi.org/10.9767/bcrec.11.1.414.40-47</a></p>

scholarly journals Modular, Self-Assembling Metallaphotocatalyst for Cross-Couplings Using the Full Visible-Light Spectrum

ACS Catalysis ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 13269-13274
Author(s):  
Susanne Reischauer ◽  
Volker Strauss ◽  
Bartholomäus Pieber
Keyword(s):  
Visible Light ◽  
Light Spectrum ◽  
Self Assembling

ARS–TiO2 photocatalyzed direct functionalization of sp2 C–H bonds toward thiocyanation and cyclization reactions under visible light

2020 ◽  
Vol 10 (5) ◽  
pp. 1401-1407 ◽  
Author(s):  
Mehdi Koohgard ◽  
Zeinab Hosseinpour ◽  
Abdollah Masoudi Sarvestani ◽  
Mona Hosseini-Sarvari
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Room Temperature ◽  
Light Spectrum ◽  
Cyclization Reactions ◽  
Simple Method ◽  
Direct Functionalization

An ARS–TiO2 photocatalyst has been prepared, by a simple method through stirring a mixture of ARS and TiO2 at room temperature in the dark, to extend the photocatalytic response of titanium dioxide toward the visible light spectrum.

scholarly journals Photohydrogenation of Acetophenone Using Coumarin Dye-Sensitized Titanium Dioxide under Visible Light Irradiation

Catalysts ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 1417-1424 ◽  
Author(s):  
Shigeru Kohtani ◽  
Mizuho Mori ◽  
Eito Yoshioka ◽  
Hideto Miyabe
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Dye Sensitized ◽  
Coumarin Dye
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