scholarly journals Silica-supported PdGa Nanoparticles: Metal Synergy for Highly Active and Selective CO2-to-CH3OH Hydrogenation

2021 ◽  
Author(s):  
Scott Docherty ◽  
Nat Phongprueksathat ◽  
Erwin Lam ◽  
Gina Noh ◽  
Olga V. Safonova ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Highly Active ◽  
Supported Palladium ◽  
Surface Organometallic Chemistry ◽  
Hydrogenation Of Co

A precise synthesis of small (<2 nm) supported palladium-gallium alloyed nanoparticles on Ga<sup>III </sup>sites dispersed on silica (PdGa@SiO<sub>2</sub>) is reported. This material, prepared via a Surface Organometallic Chemistry (SOMC) approach, is highly active and selective in hydrogenation of CO<sub>2</sub> to methanol.

scholarly journals Silica-supported PdGa Nanoparticles: Metal Synergy for Highly Active and Selective CO2-to-CH3OH Hydrogenation

2021 ◽  
Author(s):  
Scott Docherty ◽  
Nat Phongprueksathat ◽  
Erwin Lam ◽  
Gina Noh ◽  
Olga V. Safonova ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Highly Active ◽  
Supported Palladium ◽  
Surface Organometallic Chemistry ◽  
Hydrogenation Of Co

A precise synthesis of small (<2 nm) supported palladium-gallium alloyed nanoparticles on Ga<sup>III </sup>sites dispersed on silica (PdGa@SiO<sub>2</sub>) is reported. This material, prepared via a Surface Organometallic Chemistry (SOMC) approach, is highly active and selective in hydrogenation of CO<sub>2</sub> to methanol.

scholarly journals Silica-supported PdGa Nanoparticles: Metal Synergy for Highly Active and Selective CO2-to-CH3OH Hydrogenation

2021 ◽  
Author(s):  
Scott Docherty ◽  
Nat Phongprueksathat ◽  
Erwin Lam ◽  
Gina Noh ◽  
Olga V. Safonova ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Highly Active ◽  
Supported Palladium ◽  
Surface Organometallic Chemistry ◽  
Hydrogenation Of Co

A precise synthesis of small (<2 nm) supported palladium-gallium alloyed nanoparticles on Ga<sup>III </sup>sites dispersed on silica (PdGa@SiO<sub>2</sub>) is reported. This material, prepared via a Surface Organometallic Chemistry (SOMC) approach, is highly active and selective in hydrogenation of CO<sub>2</sub> to methanol.

scholarly journals Enhanced CH3OH selectivity in CO2 hydrogenation using Cu-based catalysts generated via SOMC from GaIII single-sites

2020 ◽  
Vol 11 (29) ◽  
pp. 7593-7598 ◽  
Author(s):  
Erwin Lam ◽  
Gina Noh ◽  
Ka Wing Chan ◽  
Kim Larmier ◽  
Dmitry Lebedev ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Co2 Hydrogenation ◽  
Alloy Nanoparticles ◽  
Surface Organometallic Chemistry ◽  
Hydrogenation Of Co

CuGax alloy nanoparticles supported on SiO2 can be obtained by surface organometallic chemistry. This catalyst is active and selective for the hydrogenation of CO2 to CH3OH, related to the formation of an optimal interface between Cu and GaIIIOx.

scholarly journals Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis

2018 ◽  
Vol 54 (32) ◽  
pp. 3989-3992 ◽  
Author(s):  
Keishi Yamamoto ◽  
Ka Wing Chan ◽  
Victor Mougel ◽  
Haruki Nagae ◽  
Hayato Tsurugi ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Reducing Agent ◽  
Highly Active ◽  
Species Formation ◽  
Surface Organometallic Chemistry

A well-defined silica-supported molybdenum dioxo species, (SiO)2Mo(O)2, prepared via Surface Organometallic Chemistry, is highly active in metathesis upon reaction with organosilicon reducing agent.

Well-Defined Molybdenum Oxo Alkyl Complex Supported on Silica by Surface Organometallic Chemistry: A Highly Active Olefin Metathesis Precatalyst

2017 ◽  
Vol 139 (6) ◽  
pp. 2144-2147 ◽  
Author(s):  
Nicolas Merle ◽  
Frédéric Le Quéméner ◽  
Yassine Bouhoute ◽  
Kai C. Szeto ◽  
Aimery De Mallmann ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Highly Active ◽  
Surface Organometallic Chemistry

Controllable synthesis of Ir(Rh)–Sn/SiO2 bimetallic catalysts via surface organometallic chemistry for the production of ethanol from hydrogenolysis of ethyl acetate

2020 ◽  
Vol 10 (4) ◽  
pp. 1086-1095
Author(s):  
Rui Xu ◽  
Kunbo Lian ◽  
Zhikang Xu ◽  
Yuanyuan Yue ◽  
Pei Yuan ◽  
...  
Keyword(s):  
Ethyl Acetate ◽  
Organometallic Chemistry ◽  
Bimetallic Catalysts ◽  
Controllable Synthesis ◽  
Highly Active ◽  
Surface Organometallic Chemistry

A series of highly active Ir–Sn/SiO2 and Rh–Sn/SiO2 catalysts for ethyl acetate hydrogenolysis to ethanol were prepared from the grafting synthesis based on the surface organometallic chemistry concept.

Electrophilicity in heterogeneous catalysis: Role of surface and sub-surface modification

2021 ◽  
Author(s):  
Anand S Burange ◽  
Awais Ahmad ◽  
Rafael Luque
Keyword(s):  
Surface Modification ◽  
Heterogeneous Catalysis ◽  
Metal Nanoparticles ◽  
Organometallic Chemistry ◽  
Single Atom ◽  
Surface Organometallic Chemistry

Efforts to bridge the gap between homogeneous and heterogeneous catalysis include the use of surface organometallic chemistry, single atom catalysis and monodispersed metal nanoparticles, among others. In case of metal...

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