scholarly journals On the Unsuspected Role of Multivalent Metal Ions on the Charge Storage of a Metal Oxide Electrode in Mild Aqueous Electrolytes

2019 ◽  
Author(s):  
Yee-Seul Kim ◽  
Kenneth D. Harris ◽  
Benoit Limoges ◽  
Véronique Balland
Keyword(s):  
Metal Oxide ◽  
Metal Ions ◽  
Chemical Nature ◽  
Aqueous Electrolyte ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Oxide Electrode ◽  
Multivalent Metal

<p>The main objective of the work is to elucidate and rationalize the role played by an Al<sup>3+</sup>-based aqueous electrolyte on the charge accumulated in model mesoporous TiO<sub>2</sub> electrodes and to decipher the chemical nature of the inserting cation.<br></p>

scholarly journals On the Unsuspected Role of Multivalent Metal Ions on the Charge Storage of a Metal Oxide Electrode in Mild Aqueous Electrolytes

2019 ◽  
Author(s):  
Yee-Seul Kim ◽  
Kenneth D. Harris ◽  
Benoit Limoges ◽  
Véronique Balland
Keyword(s):  
Metal Oxide ◽  
Metal Ions ◽  
Chemical Nature ◽  
Aqueous Electrolyte ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Oxide Electrode ◽  
Multivalent Metal

<p>The main objective of the work is to elucidate and rationalize the role played by an Al<sup>3+</sup>-based aqueous electrolyte on the charge accumulated in model mesoporous TiO<sub>2</sub> electrodes and to decipher the chemical nature of the inserting cation.<br></p>

scholarly journals On the unsuspected role of multivalent metal ions on the charge storage of a metal oxide electrode in mild aqueous electrolytes

2019 ◽  
Vol 10 (38) ◽  
pp. 8752-8763 ◽  
Author(s):  
Yee-Seul Kim ◽  
Kenneth D. Harris ◽  
Benoît Limoges ◽  
Véronique Balland
Keyword(s):  
Metal Oxide ◽  
Metal Ions ◽  
Metal Ion ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Electron Charge ◽  
Oxide Electrode ◽  
Metal Ion Complexes ◽  
Multivalent Metal

The hidden role of hexaaquo metal ion complexes in the proton-coupled electron charge storage at a metal oxide electrode.

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

On the role of the metal oxide/reactive electrode interface during the forming procedure of valence change ReRAM devices

Nanoscale ◽  
2019 ◽  
Vol 11 (39) ◽  
pp. 18201-18208 ◽  
Author(s):  
Andreas Kindsmüller ◽  
Alexander Meledin ◽  
Joachim Mayer ◽  
Rainer Waser ◽  
Dirk J. Wouters
Keyword(s):  
Metal Oxide ◽  
Oxygen Exchange ◽  
Oxide Electrode ◽  
Electrode Interface ◽  
Valence Change ◽  
Forming Behaviour

This work investigates the oxygen exchange at the oxide/electrode interface in ReRAM devices and its influence on the forming behaviour.

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

A renewable biopolymer cathode with multivalent metal ions for enhanced charge storage

2014 ◽  
Vol 2 (6) ◽  
pp. 1974-1979 ◽  
Author(s):  
Shimelis Admassie ◽  
Anders Elfwing ◽  
Edwin W. H. Jager ◽  
Qinye Bao ◽  
Olle Inganäs
Keyword(s):  
Metal Ions ◽  
Charge Storage ◽  
Multivalent Metal

Adaptive Role of Lipids in Algae under Metal Ions Impact (a Review)

2018 ◽  
Vol 54 (6) ◽  
pp. 78-93
Author(s):  
V. V. Grubinko ◽  
O. I. Bodnar ◽  
A. I. Lutsiv ◽  
G. B. Viniarska
Keyword(s):  
Metal Ions ◽  
Adaptive Role

scholarly journals Conversion of Methanol on Rutile TiO2 (110) and Tungsten Oxide Clusters: 2. The Role of Defects and Electron Transfer in Bifunctional Oxidic Photocatalysts

2021 ◽  
Author(s):  
Lars Mohrhusen ◽  
Jessica Kräuter ◽  
Katharina Al-Shamery
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Metal Oxide ◽  
Tungsten Oxide ◽  
Organic Compounds ◽  
Uv Irradiation ◽  
Organic P ◽  
Rutile Tio2 ◽  
Metal Oxide Surfaces

The photochemical conversion of organic compounds on tailored transition metal oxide surfaces by (UV) irradiation has found wide applications ranging from the production of chemicals to the degradation of organic...

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