scholarly journals Experimental research on the mechanism of chemical energy conversion to light energy under thermal induction

Author(s):  
Liu Jiping ◽  
Fang Zhuqing ◽  
Wang Yinjie ◽  
Han Jia

Since the discovery of glare illuminators, considerable efforts have been devoted to achieving a breakthrough of high light intensity on the order of magnitude. In this paper, we prepared strong flash blinding agents for the first time by using aluminum powder, oxidant, and adhesive as the main materials, and tris-(8-hydroxyquinolinato) aluminum (Al2q3), triazoindolizine, or nano zinc oxide, etc. as electronic output brightener after mixing and granulation according to the developed formulation. It was discovered that the luminescence intensity was related to the thermal effect of the substance while the brightener only served as an auxiliary brightening effect to achieve energy non-destructive conversion. With the same formula, the luminescence intensities of glaze agents with ADN and potassium perchlorate as oxidants were slightly higher than that of ammonium perchlorate oxidant; the brightening effect of nano-zinc oxide was slightly higher than those of tris-(8-hydroxyquinolinato) aluminum (Al2q3) and triazoindolizine. The luminescence intensity of the substance with a high thermal effect value was high, but the luminescence time was slightly short. Under identical conditions, the luminescence effect of nano-aluminum powder was obviously better than that of micro-aluminum powder with the highest luminescence intensity of 3.9 × 1010 ~ 1.9 × 1011 cd and the luminescence time of 39 - 48 ms. The effects of shell material and structure and the effect of heat-induced mode on the luminescence intensity were also investigated. The luminescence intensity of the glare agent with a high shell strength was high, but the luminescence time was slightly short. Moreover, the energy level of the brightener is excited under the induction of high temperatures, which leads to a blue shift to promote the chemical reaction of the material in a favorable direction. Finally, the optical radiation of the thermally induced high-temperature combustion system was analyzed from the aspects of thermal effect, combustion temperature, and chemiluminescence effect. A way to improve the optical radiation intensity of a high-temperature combustion system was proposed.

2017 ◽  
Vol 9 (1) ◽  
pp. 168781401668503 ◽  
Author(s):  
Chaozhi Cai ◽  
Qiang Ma ◽  
Di Wu ◽  
Leyao Fan ◽  
Bingsheng Wu

This article describes the configuration and working principle of the high-temperature combustion system; according to the control requirements which have a wide range and high precision for fuel flow-rate of the high-temperature combustion system, a set of fuel supply system is designed based on the frequency conversion hydraulic technology and electro-hydraulic proportional technique. An automatic control system with the function of field and remote control is carried out to achieve the precise supply of the fuel. The transfer function which describes the dynamic characteristic of the fuel supply system is given and the dynamic matrix control algorithm is employed to realize the high-quality control of fuel flow-rate. The experimental results show that the response time of flow-rate is about 12 s, almost no overshoot, and control accuracy within 1%. Therefore, the designed fuel supply system can meet the requirements of the high-temperature combustion system, and the designed control system has good control performance.


2015 ◽  
Vol 1107 ◽  
pp. 326-332
Author(s):  
Abdul Rahim Yacob ◽  
Kamaluddeen Suleiman Kabo

The use of metal oxides in heterogeneous base catalysis has gained a large interest due to their application in many chemical and industrial processes and is environmental friendly. Basic metal oxides are commonly used and their structures, morphology and performance can be modified by method of preparation and thermal activation. In this study, surface modified amphoteric zinc oxide was prepared via hydration-dehydration method and characterised by TGA and FTIR. The basic strength at various temperatures is characterised by FTIR and back titration analyses. The results shows that surface modified zinc oxide has the highest basic strength of 1.453mmolg-1at 400°C making it a relatively good and suitable compound for use in heterogeneous basic catalysis. This result is also supported by FTIR spectra which show possible relationship between the Lewis O2-and increasing basic strength.


1995 ◽  
Vol 26 (3-4) ◽  
pp. 247-254 ◽  
Author(s):  
Takeshi Okutani ◽  
Yoshinori Nakata ◽  
Masaaki Suzuki ◽  
Hideaki Nagai

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