A Transport Model of Asphalt Binder Oxidation in Pavements

2009 ◽  
Vol 10 (SI) ◽  
pp. 95-113 ◽  
Author(s):  
Nikornpon Prapaitrakul ◽  
Rongbin Han ◽  
Xin Jin ◽  
Charles J Glover
2009 ◽  
Vol 10 (sup1) ◽  
pp. 95-113 ◽  
Author(s):  
Nikornpon Prapaitrakul ◽  
Rongbin Han ◽  
Xin Jin ◽  
Charles J. Glover

Author(s):  
Sara Pournoman ◽  
Elie Y. Hajj ◽  
Nathan Morian ◽  
Amy Epps Martin

The overall objective of this study was to evaluate the influence of selected recycling agents (RAs) and recycled materials on the development of cracking potential with respect to oxidative aging. Given the complex nature of varying base asphalt binders, recycled materials, whether recycled asphalt pavement (RAP), reclaimed asphalt shingles (RAS), or both, and the complexity of their combined interactions with recycling agents, standard evaluation protocols for binder grading and evaluation may be insufficient. The binder blend aging predictions or oxidation modeling evaluation was introduced as a means to evaluate the combined influence of both binder oxidation kinetics and resulting rheological changes on the measured cracking potential of the various binder blends—that is, Glover–Rowe (G-R) parameter—driven by temperature estimation modeling over simulated in-service durations at example geographic locations. This evaluation has demonstrated the importance of adequate characterization of the specific materials being used in conjunction with selection of the correct dose of the appropriate recycling agent to ensure sufficient resistance to cracking and embrittlement of proposed material combinations. The combined influence of all the interested components did not always add up to the sum of the individual parts, nor are the measured interactions consistent with increased levels of oxidation. Therefore, the prevailing conclusion of the study as a whole indicated that material-specific evaluations are needed to identify the complex interactions taking place within the material combinations of interest, but also multiple levels of aging at appropriate intervals may be necessary for comprehensive characterization.


1999 ◽  
Author(s):  
Bohdan Cybyk ◽  
Jay Boris ◽  
Theodore Young, Jr. ◽  
Charles Lind ◽  
Alexandra Landsberg

2019 ◽  
Author(s):  
Michael Stukel ◽  
Thomas Kelly

Thorium-234 (234Th) is a powerful tracer of particle dynamics and the biological pump in the surface ocean; however, variability in carbon:thorium ratios of sinking particles adds substantial uncertainty to estimates of organic carbon export. We coupled a mechanistic thorium sorption and desorption model to a one-dimensional particle sinking model that uses realistic particle settling velocity spectra. The model generates estimates of 238U-234Th disequilibrium, particulate organic carbon concentration, and the C:234Th ratio of sinking particles, which are then compared to in situ measurements from quasi-Lagrangian studies conducted on six cruises in the California Current Ecosystem. Broad patterns observed in in situ measurements, including decreasing C:234Th ratios with depth and a strong correlation between sinking C:234Th and the ratio of vertically-integrated particulate organic carbon (POC) to vertically-integrated total water column 234Th, were accurately recovered by models assuming either a power law distribution of sinking speeds or a double log normal distribution of sinking speeds. Simulations suggested that the observed decrease in C:234Th with depth may be driven by preferential remineralization of carbon by particle-attached microbes. However, an alternate model structure featuring complete consumption and/or disaggregation of particles by mesozooplankton (e.g. no preferential remineralization of carbon) was also able to simulate decreasing C:234Th with depth (although the decrease was weaker), driven by 234Th adsorption onto slowly sinking particles. Model results also suggest that during bloom decays C:234Th ratios of sinking particles should be higher than expected (based on contemporaneous water column POC), because high settling velocities minimize carbon remineralization during sinking.


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