scholarly journals THE VOLUME OF THE CAGE OF ENDOHEDRAL COMPLEXES OF THE C60 FULLERENE AND HALOGENIDE-IONS

2021 ◽  
pp. 602
Author(s):  
A. A. Tukhbatullina ◽  
A. D. Zakirova ◽  
D. Sh. Sabirov
Keyword(s):  
C60 Fullerene ◽  
Endohedral Complexes

scholarly journals Influence of the Active Layer Structure on the Photovoltaic Performance of Water-Soluble Polythiophene-Based Solar Cells

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1640
Author(s):  
Massimiliano Lanzi ◽  
Debora Quadretti ◽  
Martina Marinelli ◽  
Yasamin Ziai ◽  
Elisabetta Salatelli ◽  
...  
Keyword(s):  
Solar Cells ◽  
Layer Structure ◽  
Photovoltaic Performance ◽  
Phase Segregation ◽  
Water Soluble ◽  
Polymerization Reaction ◽  
Fullerene Derivative ◽  
C60 Fullerene ◽  
Photovoltaic Efficiency ◽  
Single Material

A new side-chain C60-fullerene functionalized thiophene copolymer bearing tributylphosphine-substituted hexylic lateral groups was successfully synthesized by means of a fast and effective post-polymerization reaction on a regioregular ω-alkylbrominated polymeric precursor. The growth of the polymeric intermediate was followed by NMR spectrometry in order to determine the most convenient reaction time. The obtained copolymer was soluble in water and polar solvents and was used as a photoactive layer in single-material organic photovoltaic (OPV) solar cells. The copolymer photovoltaic efficiency was compared with that of an OPV cell containing a water-soluble polythiophenic homopolymer, functionalized with the same tributylphosphine-substituted hexylic side chains, in a blend with a water-soluble C60-fullerene derivative. The use of a water-soluble double-cable copolymer made it possible to enhance the control on the nanomorphology of the active blend, thus reducing phase-segregation phenomena, as well as the macroscale separation between the electron acceptor and donor components. Indeed, the power conversion efficiency of OPV cells based on a single material was higher than that obtained with the classical architecture, involving the presence of two distinct ED and EA materials (PCE: 3.11% vs. 2.29%, respectively). Moreover, the synthetic procedure adopted to obtain single material-based cells is more straightforward and easier than that used for the preparation of the homopolymer-based BHJ solar cell, thus making it possible to completely avoid the long synthetic pathway which is required to prepare water-soluble fullerene derivatives.

Endo- and exohedral chloro-fulleride as η5 ligands: A DFT study on the first-row transition metal complexes

2021 ◽  
Author(s):  
Sebastian Anila ◽  
Cherumuttathu Hariharan Suresh
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dft Study ◽  
C60 Fullerene ◽  
Ring Fusion ◽  
Coordination Modes

C60 fullerene coordinates to transition metals in η2-fashion through its C-C bond at [6,6] ring fusion whereas other coordination modes η3, η4, η5 and η6 are rarely observed. The coordination...

Post-traumatic recovery of muscle soleus in rats is improved via synergistic effect of C60 fullerene and TRPM8 agonist menthol

2021 ◽  
Author(s):  
Dmytro Nozdrenko ◽  
Tatiana Matvienko ◽  
Oksana Vygovska ◽  
Vasil Soroca ◽  
Kateryna Bogutska ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
C60 Fullerene ◽  
Post Traumatic

Structure and Stability of Endohedral Complexes X@(HBNH)12.

ChemInform ◽  
2007 ◽  
Vol 38 (4) ◽  
Author(s):  
Hong Wang ◽  
Jian-Feng Jia ◽  
Hai-Shun Wu
Keyword(s):  
Structure And Stability ◽  
Endohedral Complexes

Dispersed state of C60 fullerene in some polymers

2016 ◽  
Vol 42 (1) ◽  
pp. 102-104 ◽  
Author(s):  
A. A. Bogdanov ◽  
A. O. Pozdnyakov
Keyword(s):  
C60 Fullerene

The Nature of the Noncovalent Interactions between Benzene and C60 Fullerene

2016 ◽  
Vol 120 (28) ◽  
pp. 5766-5772 ◽  
Author(s):  
Ming-Ming Li ◽  
Yi-Bo Wang ◽  
Yu Zhang ◽  
Weizhou Wang
Keyword(s):  
Noncovalent Interactions ◽  
C60 Fullerene
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