CHEMICAL PREPARATION AND CRYSTAL DATA FOR TWO CONDENSED PHOSPHATES NiCs4(PO3)6 AND NiK4(P3O9)2

Methods of chemical preparation and crystallographic data are reported for two new condensed phosphates: a hydrated cyclotriphosphate with a formula MnNa4(P3O9)2 4H2O and its anhydrous form MnNa4(P3O9)2. MnNa4(P3O9)2 4H2O is monoclinic P21/a with the following unit-cell dimensions: a=8.536(2) Å, b=14.309(3) Å, c=8.508(2) Å, β=96.452(2)°, and Z=2. MnNa4(P3O9)2 is monoclinic C2/c with the following unit-cell dimensions: a=13.198(2) Å, b=8.241(1) Å, c=14.228(2) Å, β=95.045(1)°, and Z=4.

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Chemical preparation and crystal data for two condensed phosphates NiCs4(PO3)6 and NiK4(P3O9)2

Powder Diffraction ◽

10.1154/1.1725198 ◽

2004 ◽

Vol 19 (4) ◽

pp. 375-377 ◽

Cited By ~ 1

Author(s):

Kacem Sbai ◽

Said Belaaouad ◽

Abdelkebir Kenz ◽

El Mostafa Tace ◽

Malika Tridane

Keyword(s):

Unit Cell ◽

Crystallographic Data ◽

Crystal Data ◽

Chemical Preparation ◽

Space Group ◽

Cell Dimensions ◽

Condensed Phosphates ◽

Unit Cell Dimensions

Methods of chemical preparation and crystallographic data are reported for two new condensed phosphates: a polyphosphate of nickel and cesium, NiCs4(PO3)6, and a cyclotriphosphate of nickel and potassium, NiK4(P3O9)2. NiCs4(PO3)6 is rhombohedral with the following unit-cell dimensions: a=b=11.602(1) Å, c=9.078(1) Å, space group P−31c, V=1058.24(1) Å3, and Z=2. NiK4(P3O9)2 is triclinic with the following unit-cell dimensions: a=6.143(8) Å, b=6.80(1) Å, c=12.80(3) Å, α=102.8(3)°, β=89.7(2)°, γ=66.03(7)°, space group P−1, V=473.56(3) Å3, and Z=1.

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Chemical preparation and crystal data for two hydrated cyclotriphosphates SrMIP3O9⋅3H2O and their corresponding anhydrous SrMIP3O9 (MI=K+ and Tl+)

Powder Diffraction ◽

10.1154/1.1575761 ◽

2003 ◽

Vol 18 (3) ◽

pp. 233-235 ◽

Cited By ~ 1

Author(s):

Kacem Sbai ◽

Khadija El Kababi ◽

Saïd Belaaouad

Keyword(s):

General Formula ◽

Unit Cell ◽

Monoclinic Space Group ◽

Crystal Data ◽

Chemical Preparation ◽

Space Group ◽

Cell Dimensions ◽

Condensed Phosphates ◽

Unit Cell Dimensions

Methods of chemical preparation and crystal data are reported for four new condensed phosphates: two hydrated cyclotriphosphates with a general formula SrMIP3O9⋅3H2O (MI=K+,Tl+) and their corresponding anhydrous cyclotriphosphates SrMIP3O9 (MI=K+,Tl+). The two hydrated condensed phosphates, SrKP3O9⋅3H2O and SrTlP3O9⋅3H2O, belong to previously investigated structure types. SrKP3O9⋅3H2O and SrTlP3O9⋅3H2O are orthorhombic, Z=4, space group Pnma, with respectively the following unit-cell dimensions: a=9.082(2) Å, b=8.133(2) Å, c=15.009(2) Å, M(20)=49, F(25)=61(0.0052;79) and a=9.115(7) Å, b=8.139(7) Å, c=15.221(2) Å, M(20)=285, F(30)=522(0.000 411;140). SrKP3O9 and SrTlP3O9 are monoclinic, space group P21/m or P21, Z=4, with, respectively, the following unit-cell dimensions: a=14.957(1) Å, b=8.372(1) Å, c=7.909(1) Å, β=102.27(1)°, M(20)=81, F(24)=95(0.000 025;92) and a=14.544(2) Å, b=8.639(1) Å, c=7.727(1) Å, β=102.05(1)°, M(20)=66, F(30)=78(0.003 098;125).

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Chemical preparation and crystal data for four new condensed phosphates

Powder Diffraction ◽

10.1154/1.1424262 ◽

2002 ◽

Vol 17 (1) ◽

pp. 19-22 ◽

Cited By ~ 2

Author(s):

Kacem Sbai ◽

Azzeddine Atibi ◽

Khadija El Kababi ◽

Said Belaaouad

Keyword(s):

Crystallographic Data ◽

Crystal Data ◽

Chemical Preparation ◽

Condensed Phosphates ◽

Long Chain

Methods of chemical preparation and crystallographic data are reported for four new condensed phosphates: one hydrated cyclotriphosphate MnAg4(P3O9)2·6H2O and three long-chain polyphosphates: MnAg2(PO3)4, NiAg4(PO3)6 and NiNa4(PO3)6. Two of these new condensed phosphates, associated with manganese, belong to previously investigated structure types.

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ChemInform Abstract: Chemical Preparations and Crystal Data for Twelve New Condensed Phosphates

ChemInform ◽

10.1002/chin.199321002 ◽

2010 ◽

Vol 24 (21) ◽

pp. no-no

Author(s):

M. T. AVERBUCH-POUCHOT ◽

J.-L. PRISSET ◽

A. DURIF

Keyword(s):

Crystal Data ◽

Condensed Phosphates

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Chemical preparations and crystal data for eight new condensed phosphates

Solid State Sciences ◽

10.1016/s1293-2558(00)01081-5 ◽

2000 ◽

Vol 2 (7) ◽

pp. 701-704 ◽

Cited By ~ 14

Author(s):

M. Tridane ◽

S. Belaaouad ◽

K. Sbai

Keyword(s):

Crystal Data ◽

Condensed Phosphates

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CHEMICAL PREPARATIONS, CRYSTAL DATA FOR MONOPHOSPHATES AND CONDENSED PHOSPHATES ASSOCIATED TO BARIUM AND IR STUDIES OF THEIR ANIONS.

International Journal of Advanced Research ◽

10.21474/ijar01/8432 ◽

2019 ◽

Vol 7 (1) ◽

pp. 1133-1149

Author(s):

Soufiane Zerraf ◽

◽

Mustafa Belhabra ◽

Malika Tridane ◽

Said Belaaouad ◽

...

Keyword(s):

Crystal Data ◽

Ir Studies ◽

Condensed Phosphates

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Chemical preparations, crystal data for monophosphates and condensed phosphates associated to strontium and IR studies of their anions

International Journal of Emerging Trends in Engineering Research ◽

10.30534/ijeter/2020/265892020 ◽

2020 ◽

Vol 8 (9) ◽

pp. 6587-6598

Keyword(s):

Crystal Data ◽

Ir Studies ◽

Condensed Phosphates

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Chemical preparation and crystal data for two new cyclotriphosphates MIIK4(P3O9)2 (MII=Co2+ and Mn2+)

Powder Diffraction ◽

10.1154/1.1566954 ◽

2003 ◽

Vol 18 (3) ◽

pp. 224-226 ◽

Cited By ~ 1

Author(s):

Kacem Sbai ◽

Malika Tridane ◽

Ali Abouimrane ◽

Saïd Belaaouad ◽

Abdelouahed Cherqaoui

Keyword(s):

Unit Cell ◽

Crystal Data ◽

Chemical Preparation ◽

Triclinic Space Group ◽

Space Group ◽

Cell Dimensions ◽

Unit Cell Dimensions

Methods of chemical preparation and crystal data are reported for two new anhydrous cyclotriphosphates MIIK4(P3O9)2 (MII=Co2+ and Mn2+). These anhydrous cyclotriphosphates CoK4(P3O9)2 and MnK4(P3O9)2 were obtained by total dehydration of corresponding hydrated cyclotriphosphates CoK4(P3O9)2.7H2O and MnK4(P3O9)2.2H2O. CoK4(P3O9)2 is triclinic, space group P−1, Z=1 with the following unit-cell dimensions: a=6.29(3) Å, b=8.00(1)Å, c=13.05(8)Å, α=86.03(5)°, β=98.00(1)°, γ=68.11(2)°. MnK4(P3O9)2 crystallizes in the rhombohedral system, space group P−31c, Z=2 with the following unit-cell dimensions: a=b=7.337(3)Å, c=19.920(1)Å.

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