scholarly journals Strategies for Developing Transition Metal Phosphides in Electrochemical Water Splitting

2021 ◽  
Vol 9 ◽  
Author(s):  
Jie Ying ◽  
Huan Wang
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
High Efficiency ◽  
Molar Ratio ◽  
Renewable Energy Resources ◽  
Design Strategies ◽  
Metal Phosphides ◽  
High Efficient ◽  
Electrochemical Water Splitting ◽  
Transition Metal Phosphides

Electrochemical water splitting involving hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is a greatly promising technology to generate sustainable and renewable energy resources, which relies on the exploration regarding the design of electrocatalysts with high efficiency, high stability, and low cost. Transition metal phosphides (TMPs), as nonprecious metallic electrocatalysts, have been extensively investigated and proved to be high-efficient electrocatalysts in both HER and OER. In this minireview, a general overview of recent progress in developing high-performance TMP electrocatalysts for electrochemical water splitting has been presented. Design strategies including composition engineering by element doping, hybridization, and tuning the molar ratio, structure engineering by porous structures, nanoarray structures, and amorphous structures, and surface/interface engineering by tuning surface wetting states, facet control, and novel substrate are summarized. Key scientific problems and prospective research directions are also briefly discussed.

scholarly journals Bifunctional Heterostructured Transition Metal Phosphides for Efficient Electrochemical Water Splitting

2020 ◽  
Vol 30 (34) ◽  
pp. 2003261 ◽  
Author(s):  
Haojie Zhang ◽  
A. Wouter Maijenburg ◽  
Xiaopeng Li ◽  
Stefan L. Schweizer ◽  
Ralf B. Wehrspohn
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Metal Phosphides ◽  
Electrochemical Water Splitting ◽  
Transition Metal Phosphides

Strategies for developing transition metal phosphides as heterogeneous electrocatalysts for water splitting

Nano Today ◽  
2017 ◽  
Vol 15 ◽  
pp. 26-55 ◽  
Author(s):  
Yang Wang ◽  
Biao Kong ◽  
Dongyuan Zhao ◽  
Huanting Wang ◽  
Cordelia Selomulya
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Metal Phosphides ◽  
Transition Metal Phosphides

Synthesis and application of transition metal phosphides as electrocatalyst for water splitting

2017 ◽  
Vol 62 (9) ◽  
pp. 633-644 ◽  
Author(s):  
Jinzhan Su ◽  
Jinglan Zhou ◽  
Lu Wang ◽  
Cong Liu ◽  
Yubin Chen
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Metal Phosphides ◽  
Transition Metal Phosphides

scholarly journals Recent Advances in the Colloidal Synthesis of Ternary Transition Metal Phosphides

2019 ◽  
Vol 74 (8) ◽  
pp. 709-719 ◽  
Author(s):  
Joanna Kolny-Olesiak
Keyword(s):  
Transition Metal ◽  
Colloidal Synthesis ◽  
Magnetic Characteristics ◽  
Crystallographic Structure ◽  
Metal Phosphides ◽  
Semiconducting Properties ◽  
Wide Range ◽  
Wet Chemical ◽  
Electrochemical Water Splitting ◽  
Transition Metal Phosphides

AbstractTransition metal phosphides are interesting candidates for application as catalysts in electrochemical water splitting or heteroatom removal reactions, energy storage, and magnetic refrigeration. Metal phosphides can adopt a wide range of stoichiometries, and have metallic or semiconducting properties. The electronic and magnetic characteristics of metal phosphides can be further controlled by changing the size and the shape of the crystallites and by combining two different metals. In this review, the wet-chemical methods to synthesize such ternary Fe, Co, and Ni phosphides are summarised. First, an overview of the general synthetic strategies and the crystallographic structure of the related materials is given. Then, examples of the synthesis of several ternary phosphides are described, and the motivation for synthesising the specific materials is discussed.

Design strategies toward transition metal selenide-based catalysts for electrochemical water splitting

2021 ◽  
Author(s):  
ChuiTao Zeng ◽  
Lingyun Dai ◽  
YuHong Jin ◽  
JingBing Liu ◽  
QianQian Zhang ◽  
...  
Keyword(s):  
Composite Materials ◽  
Transition Metal ◽  
Water Splitting ◽  
Catalytic Mechanism ◽  
Synergistic Effects ◽  
Design Strategies ◽  
Morphological Control ◽  
Cation Doping ◽  
Anion Substitution ◽  
Electrochemical Water Splitting

This review focuses on the catalytic mechanism and the modification strategies for Se-based catalysts, including morphological control, anion substitution and cation doping, using composite materials modified by constructing hetero-structures, and their synergistic effects

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