scholarly journals Promotional Effect of Pd Addition on the Catalytic Activity of Composite Pt-Pd/AlSBA-15–β Catalyst for Enhanced n-Heptane Hydroisomerization

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 377
Author(s):  
Karolina Jaroszewska ◽  
Monika Fedyna ◽  
Aleksandra Masalska ◽  
Rafał Łużny ◽  
Janusz Trawczyński
Keyword(s):  
Catalytic Activity ◽  
Octane Number ◽  
Research Octane Number ◽  
Promotion Effect ◽  
Detailed Consideration ◽  
Promotional Effect ◽  
Zeolite Type ◽  
Acidic Function ◽  
High Yields ◽  
Effect Of Pd

Hierarchical AlSBA-15–zeolite materials were utilized as a supports for preparing hydroisomerization catalysts. Detailed consideration was given to: (i) the effect of the zeolite type introduced into AlSBA-15–zeolite composites (where zeolite is β, mordenite or ZSM-5) as well as (ii) the promotion effect of Pd addition. The composites showed higher activity in isomerization as compared to Pt/AlSBA-15. The enhanced isomerization efficiency were explained by the appropriate metallic and acidic function as well as suitable transport properties. The modification of the hydrogenating function by Pd incorporation increases the hydroisomerization efficiency of Pt-Pd/AlSBA-15–β catalyst. Over bimetallic Pt-Pd/AlSBA-15–β, the high yields of isomers (68 wt%) with respect to 50 wt% for a control catalyst. The most promising Pt-Pd/AlSBA-15–β catalyst allows to improve research octane number from 0 to the 74 value.

PENGARUH LAJU ALIRAN BAHAN BAKAR CNG PADA PERFORMA MESIN KENDARAAN BERMOTOR

2016 ◽  
Vol 6 (2) ◽  
pp. 65
Author(s):  
Ridwan Arief Subekti
Keyword(s):  
Natural Gas ◽  
Octane Number ◽  
Compressed Natural Gas ◽  
Research Octane Number

Makalah ini membahas tentang pengaruh laju aliran bahan bakar CNG (compressed natural gas) terhadap performa kendaraan roda empat jenis minibus. Pengaturan dan pengujian dilakukan untuk mencari setelan laju aliran CNG yang terbaik agar performa kendaraan optimal. Tahap pertama dari penelitian ini adalah pemasangan peralatan kit konverter tipe injeksi sequensial pada kendaraan. Selanjutnya dilakukan pengujian performa kendaraan menggunakan  dyno  test  atau  sasis  dyno.  Pada  awalnya,  bahan  bakar  yang  digunakan  adalah  Pertamax  RON (research  octane  number)  92  yang  kemudian  diganti  dengan  CNG.  Dari  pengujian  dua  bahan  bakar  tersebut diketahui bahwa terjadi penurunan daya dan torsi kendaraan bila menggunakan CNG. Tahap berikutnya adalah melakukan pengaturan laju aliran CNG dengan cara mengatur durasi penyemprotan injektor. Hasil uji yang ditampilkan dalam bentuk grafik putaran terhadap daya dan putaran terhadap torsi memperlihatkan bahwa performa kendaraan  berbahan  bakar  CNG  dengan  pengaturan  laju  aliran  gas  meningkat  sekitar  3%.  Sedangkan  bila penggunaan CNG dibandingkan dengan Pertamax RON 92, terjadi penurunan daya dan torsi pada kendaraan sebesar 12,4% dan 23,7%.Kata kunci : ratio laju udara, CNG, kit konverter, laju aliran gas, mesin bensin

An effective method based on multi-model fusion for research octane number prediction

2021 ◽  
Author(s):  
Ningchen Fu ◽  
Zicheng Lai ◽  
Yuping Zhang ◽  
Yan Ma
Keyword(s):  
Crude Oil ◽  
Octane Number ◽  
Research Octane Number ◽  
Model Fusion ◽  
Gasoline Engines ◽  
Oil Processing

The octane number is one of the important indicators in crude oil processing, and it is related to the anti-knock performance of gasoline engines. The loss of octane number in...

The Effect of Adding Oxygenated Compounds to Gasoline on Automotive Exhaust Emissions

2002 ◽  
Vol 125 (1) ◽  
pp. 344-350 ◽  
Author(s):  
S. G. Poulopoulos ◽  
C. J. Philippopoulos
Keyword(s):  
Octane Number ◽  
Combustion Engine ◽  
Methyl Tertiary Butyl Ether ◽  
Butyl Ether ◽  
Tertiary Butyl ◽  
Research Octane Number ◽  
Oxygenated Compounds ◽  
Reid Vapor Pressure ◽  
Three Way Catalyst ◽  
Unregulated Emissions

In the present work, the effect of adding ethanol or methyl tertiary butyl ether (MTBE) to gasoline on the regulated and unregulated emissions from an internal combustion engine with a typical three-way catalyst was studied. The addition of ethanol to fuel (10% w/w) increased both the research octane number and the Reid vapor pressure of the fuel, whereas adding 11% w/w MTBE caused an increase only in the research octane number of the fuel. When the fuel contained MTBE, less hydrocarbons, carbon monoxide, and acetaldehyde were emitted in the tailpipe. The increased emissions of acetaldehyde and ethanol were the main disadvantages of using ethanol.

Heterogeneous Copper(I)-Catalyzed Cascade Addition–Oxidative Cyclization of Nitriles with 2-Aminopyridines or Amidines: Efficient and Practical Synthesis of 1,2,4-Triazoles

Synthesis ◽  
2019 ◽  
Vol 51 (09) ◽  
pp. 2014-2022 ◽  
Author(s):  
Jianhui Xia ◽  
Xue Huang ◽  
Mingzhong Cai
Keyword(s):  
Catalytic Activity ◽  
Oxidative Cyclization ◽  
Triazole Derivatives ◽  
Step Procedure ◽  
Practical Synthesis ◽  
High Yields ◽  
Mcm 41

The heterogeneous cascade addition-oxidative cyclization of nitriles with 2-aminopyridines or amidines was achieved in 1,2-dichlorobenzene or DMSO at 120–130 °C by using a 1,10-phenanthroline-functionalized MCM-41-supported copper(I) complex [Phen-MCM-41-CuBr] as the catalyst and air as the oxidant. The approach was used to generate a wide variety of 1,2,4-triazole derivatives in mostly high yields. This heterogeneous copper(I) catalyst could be easily prepared in a two-step procedure from commercially or readily available and inexpensive reagents and it exhibited higher catalytic activity than the CuBr/1,10-Phen system. Phen-MCM-41-CuBr was also easy to recover and was recyclable up to eight times with almost consistent activity.

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