scholarly journals Earth-Abundant 3d Transition Metal Catalysts for Hydroalkoxylation and Hydroamination of Unactivated Alkenes

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 674
Author(s):  
Lou Rocard ◽  
Donghuang Chen ◽  
Adrien Stadler ◽  
Hailong Zhang ◽  
Richard Gil ◽  
...  
Keyword(s):  
Transition Metal ◽  
Relevant Literature ◽  
Bond Formation ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper ◽  
Earth Abundant

This review summarizes the most noteworthy achievements in the field of C–O and C–N bond formation by hydroalkoxylation and hydroamination reactions on unactivated alkenes (including 1,2- and 1,3-dienes) promoted by earth-abundant 3d transition metal catalysts based on manganese, iron, cobalt, nickel, copper and zinc. The relevant literature from 2012 until early 2021 has been covered.

scholarly journals On the Dissolution of Metals in Ionic Liquids 1. Iron, Cobalt, Nickel, Copper, and Zinc

2021 ◽  
Vol 2 (1) ◽  
pp. 63-73
Author(s):  
Jéssica D. S. Vicente ◽  
Domingas C. Miguel ◽  
Afonso M. P. Gonçalves ◽  
Diogo M. Cabrita ◽  
José M. Carretas ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Redox Potential ◽  
Final State ◽  
Iron Cobalt ◽  
Influence Of Temperature ◽  
Dissolution Reaction ◽  
Cobalt Nickel ◽  
Iron Metal ◽  
Copper And Zinc ◽  
Nickel Copper

Ionic liquids are critical reagents for science and technical processes nowadays. Metals are the most used reagents in the industry. It is crucial to have a deeper understanding of how ionic liquids and metals could interact. In this article the interaction of those two families of compounds is accessed. The dissolution (reaction) of metals with ionic liquids is studied, namely the influence of temperature, redox potential, and availability of an oxidant in the process. The final state achieved by the iron metal samples was also addressed by Mössbauer spectroscopy.

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