scholarly journals Electrochemical Detection of Sarcosine and Supercapacitor Based on a New Ni–Metal Organic Framework Electrode Material

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1036
Author(s):  
Shaomin Lin ◽  
Yi Wang ◽  
Chenyang Zhang ◽  
Yunying Wu ◽  
Bodong Zhang ◽  
...  

A new Ni metal organic framework based on 2,2′-Biphenyldicarboxylic, 4,4′- bipyridine as linker is prepared by hydrothermal reaction and directly used as an electrode material for supercapacitor and the detection of sarcosine. [Ni3(BIPY)3(BPDA)2(HCOO)2(H2O)2]n (Ni-1; BIPY = 4,4′-bipyridine; BPDA = 2,2′-Biphenyldicarboxylate) displays the specific capacitance of the Ni-1 are 667 F/gat 1 A/g and retention is 82% of initial capacitance at 1 A/g. The excellent electrochemical property is ascribed to the intrinsic nature of Ni-1. Furthermore, the sarcosine sensing performance of the Ni-1 electrode is evaluated in 0.1 M of NaOH solution and the electrode showed a wider range of linear response 1 × 10−4 M to 1 × 10−3 M. Thus, the results show that the Ni-1 is a potential candidate for not only sensing of sarcosine but also supercapacitor application.

2022 ◽  
Author(s):  
Chong-Huan Wang ◽  
Da-Wei Zhang ◽  
Shude Liu ◽  
Yusuke Yamauchi ◽  
Fei-Bao Zhang ◽  
...  

Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as an electrode material for supercapacitors. Such high electrochemical performance is attributed...


2021 ◽  
pp. 130338
Author(s):  
S Kishore babu ◽  
M. Jayachandran ◽  
T. Maiyalagan ◽  
T. Vijayakumar ◽  
B. Gunasekaran

Author(s):  
Lin Ren ◽  
Xudong Zhao ◽  
Baosheng Liu ◽  
Hongliang Huang

Abstract Rapid removal of radioactive strontium from nuclear wastewater is of great significance for environment safety and human health. This work reported the effective adsorption of strontium ion in a stable dual-group metal-organic framework, Zr6(OH)14(BDC-(COOH)2)4(SO4)0.75 (Zr-BDC-COOH-SO4), which contains strontium-chelating groups (-COOH and SO4) and strongly ionizable group (-COOH). Zr-BDC-COOH-SO4 exhibits very rapid adsorption kinetics (<5 min) and a maximum adsorption capacity of 67.5 mg g−1. The adsorption behaviors can be well evaluated by pseudo-second-order model and Langmuir isotherm model. Further investigations indicate that the adsorption of Sr2+ in Zr-BDC-COOH-SO4 would not be interfered by solution pH and adsorption temperature obviously. Feasible regeneration of the adsorbent was also demonstrated through a simple elution method. Mechanism investigation suggests that free -COOH contributes to the rapid adsorption based on electrostatic interaction while introduction of -SO4 can enhance the adsorption capacity largely. Thus, these results suggest that Zr-BDC-COOH-SO4 might be a potential candidate for Sr2+ removal and introducing dual groups is an effective strategy for designing high-efficiency adsorbents.


2020 ◽  
Vol 282 ◽  
pp. 121093
Author(s):  
Shankhamala Ghosh ◽  
Chandan Kumar Maity ◽  
G.C. Nayak ◽  
Hari Pada Nayek

2017 ◽  
Vol 194 ◽  
pp. 185-188 ◽  
Author(s):  
Feng Yu ◽  
Lei Zhou ◽  
Ting You ◽  
Li Zhu ◽  
Xiang Liu ◽  
...  

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