Safety Comes First: Novel Styrene Butadiene Rubber (SBR) and Ethylene Propylene Diene Monomer (EPDM) Surfaces as a Response to Sport Injuries

An athlete’s performance depends not only on the shoes they wear but also on the surface used in sports facilities. In addition, it can significantly contribute to reducing injuries, which are easy to get during sports competitions. In the present study, we wanted to investigate whether recycled styrene butadiene rubber (SBR) and ethylene propylene diene monomer (EPDM) could be used in the production of sports surfaces. For this purpose, we designed three different sports surfaces: (1) SBR covered with a thin EPDM spray layer on the top, (2) clean EPDM, and (3) bottom SBR layer with the top layer of EPDM. The test program of these surfaces included in its scope: shock absorption, vertical deformation, tensile strength, abrasion resistance, and slip resistance tests. Our research also involved the influence of the substrate under surface, temperature, and surface conditions. Presented results show that both materials, in the right proportions, can be used in the production of sports surfaces.

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A novel chemical technique for compatibility of ethylene-propylene-diene monomer rubber and styrene-butadiene rubber in their blends

Journal of Elastomers & Plastics ◽

10.1177/0095244316653262 ◽

2016 ◽

Vol 49 (4) ◽

pp. 298-314 ◽

Cited By ~ 2

Author(s):

Sara Estagy ◽

Saeed Ostad Movahed ◽

Soheil Yazdanbakhsh ◽

Majid Karim Nezhad

Keyword(s):

Mechanical Properties ◽

Heat Flow ◽

Classical Problem ◽

Styrene Butadiene Rubber ◽

Butadiene Rubber ◽

Ethylene Propylene Diene Monomer ◽

Scanning Calorimetry ◽

Covalent Bonds ◽

Ethylene Propylene ◽

Styrene Butadiene

The market for commercial polymer blends has grown steadily. A good blend should have strong interphases between different parts of the constituted polymers. Lack of strong interphases is a classical problem of the blend industry. Ethylene-propylene-diene monomer rubber (EPDM)/styrene-butadiene rubber (SBR) blends have a very good aging resistance and good compression sets. However, these rubbers are partially miscible. To improve the miscibility of EPDM and SBR in their blends, a Lewis acid, AlCl3, was used to form EPDM–g–SBR copolymer through Friedel–Crafts reactions. The existence of covalent bonds between EPDM and SBR macromolecules was studied by the cure traces of the blends, that is, ΔTorque, Fourier transform infrared spectrums, differential scanning calorimetry (DSC) heat flow curves, thermogravimetric analysis curves, and scanning electron (SEM) micrographs. Subsequently, several blends with EPDM/SBR ratio of 40/60 and with various AlCl3 amounts were prepared and after curing, their mechanical properties were measured and compared. The results showed covalent bonds formed between SBR–EPDM and SBR–SBR macromolecules. An exothermic change in heat flow in the DSC curve was observed around 111.28°C, which can be attributed to the formation of carbocations in Friedel–Crafts reactions. Adding 2 phr AlCl3 had an efficient effect on EPDM–SBR and or SBR–SBR linkages. The mechanical properties of the cured blends, that is, tensile strength were lower when compared with corresponding values for prepared compound with SBR. Excellent compatibility between the two polymers and strong interphases were observed in SEM micrograph of the cured blend with 1 phr AlCl3.

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