scholarly journals Effect of Gravity and Various Operating Conditions on Proton Exchange Membrane Water Electrolysis Cell Performance

Membranes ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 822
Author(s):  
Yena Choi ◽  
Woojung Lee ◽  
Youngseung Na
Keyword(s):  
Flow Rate ◽  
Proton Exchange Membrane ◽  
Operating Temperature ◽  
Water Electrolysis ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Phase Flow ◽  
Cell Orientation ◽  
Two Phase ◽  
Exchange Membrane

Water electrolysis is an eco-friendly method for the utilization of renewable energy sources which provide intermittent power supply. Proton exchange membrane water electrolysis (PEMWE) has a high efficiency in this regard. However, the two-phase flow of water and oxygen at the anode side causes performance degradation, and various operating conditions affect the performance of PEMWE. In this study, the effects of four control parameters (operating temperature, flow rate, cell orientation, and pattern of the channel) on the performance of PEMWE were investigated. The effects of the operating conditions on its performance were examined using a 25 cm2 single-cell. Evaluation tests were conducted using in situ methods such as polarization curves and electrochemical impedance spectroscopy. The results demonstrated that a high operating temperature and low flow rate reduce the activation and ohmic losses, and thereby enhance the performance of PEMWE. Additionally, the cell orientation affects the performance of PEMWE owing to the variation in the two-phase flow regime. It was observed that the slope of specific sections in the polarization curve rapidly increases at a specific cell voltage.

Ex-Situ Characterization of Two-Phase Flow Regimes in Proton-Exchange Membrane Fuel Cells Under Non-Isothermal Conditions

2010 ◽  
Author(s):  
Arganthae¨l Berson ◽  
Jon G. Pharoah
Keyword(s):  
Proton Exchange Membrane ◽  
Two Phase Flow ◽  
Metal Foam ◽  
Flow Regimes ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Ex Situ ◽  
Phase Flow ◽  
Two Phase ◽  
Exchange Membrane

Efficient water management is crucial for the good performances of proton-exchange membrane fuel cells (PEMFCs). The geometric and physical characteristics of the components of a PEMFC as well as operating conditions have an impact on the transport of water through the porous transport layer (PTL) and the two-phase flow regimes in the microchannels. One parameter of importance is the local temperature, which affects properties such as surface tension and is coupled with phase change. Indeed, a temperature difference of about 5K is expected across the PTL, with spatial variations due to the geometry of the flow field plate. We present preliminary results obtained with a first experimental setup for the ex-situ characterization of two-phase flow regimes in the flow channels. Water is pushed through the PTL, which is sandwiched between a porous metal foam and the flow field plate. The air flow rate, temperature and humidity can be controlled. The cell can be heated up by applying an electrical current through the metal foam. A transparent window is located on top of the flow channel. The two-phase flow within the micro-channels is visualized using a high-speed camera and laser-induced fluorescence. Preliminary results obtained under isothermal conditions at room temperature show that different two-phase flow regimes occur in the channels depending on the operating conditions, in good qualitative agreement with data from the literature. Eventually, a new visualization cell is presented that is expected to correct the flaws of the previous design and will allow a better thermal control. It will be possible to adjust the temperature gradient and the mean temperature in order to observe their impact on two-phase flow regimes for different types of PTL and flow rates. The results will provide a better understanding of water transport in PEMFC and benchmark data for the validation of numerical models.

An Analytical Solution to Predict the Inception of Two-Phase Flow in a Proton Exchange Membrane Fuel Cell

2010 ◽  
Vol 7 (6) ◽  
Author(s):  
A. S. Bansode ◽  
T. Sundararajan ◽  
Sarit K. Das
Keyword(s):  
Fuel Cell ◽  
Analytical Model ◽  
Current Density ◽  
Proton Exchange Membrane ◽  
Two Phase Flow ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Phase Flow ◽  
Two Phase ◽  
Exchange Membrane

The presence of liquid water at the cathode of proton exchange membrane fuel cell hinders the reactant supply to the electrode and is known as electrode flooding. The flooding at the cathode due to the presence of two-phase flow of water is one of the major performance limiting conditions. A pseudo-two-dimensional analytical model is developed to predict the inception of two-phase flow along the length of the cathode channel. The diffusion of the water is considered to take place only across the gas diffusion layer (GDL). The current density corresponding to the inception of two-phase flow, called the threshold current density, is found to be a function of the channel length and height, GDL thickness, velocity, and relative humidity of the air at the inlet and cell temperature. Thus, for given design and operating conditions, the analytical model is capable of predicting the inception of two-phase flow, and therefore a flooding condition can be avoided in the first place.

scholarly journals Heat and Mass Transfer and Two Phase Flow in Hydrogen Proton Exchange Membrane Fuel Cells and Direct Methanol Fuel Cells

2003 ◽  
Author(s):  
Hang Guo ◽  
Chong Fang Ma ◽  
Mao Hai Wang ◽  
Jian Yu ◽  
Xuan Liu ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Fuel Cells ◽  
Proton Exchange Membrane ◽  
Direct Methanol Fuel Cells ◽  
Proton Exchange ◽  
Phase Flow ◽  
Two Phase ◽  
Direct Methanol ◽  
Methanol Fuel Cells ◽  
Exchange Membrane

Fuel cells are related to a number of scientific and engineering disciplines, which include electrochemistry, catalysis, membrane science and engineering, heat and mass transfer, thermodynamics and so on. Several thermophysical phenomena such as heat transfer, multicomponent transport and two phase flow play significant roles in hydrogen proton exchange membrane fuel cells and direct methanol fuel cells based on solid polymer electrolyte membrane. Some coupled thermophysical issues are bottleneck in process of scale-up of direct methanol fuel cells and hydrogen proton exchange membrane fuel cells. In present paper, experimental results of visualization of condensed water in fuel cell cathode microchannels are presented. The equivalent diameter of the rectangular channel is 0.8mm. Water droplets from the order of 0.08mm to 0.8mm were observed from several different locations in the channels. Several important problems, such as generation and change characteristics of water droplet and gas bubble, two phase flow under chemical reaction conditions, mass transfer enhancement of oxygen in the cathode porous media layer, heat transfer enhancement and high efficiency cooling system of proton exchange membrane fuel cells stack, etc., are discussed.

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