Science goals and new mission concepts for future exploration of Titan’s atmosphere, geology and habitability: titan POlar scout/orbitEr and in situ lake lander and DrONe explorer (POSEIDON)

In response to ESA’s “Voyage 2050” announcement of opportunity, we propose an ambitious L-class mission to explore one of the most exciting bodies in the Solar System, Saturn’s largest moon Titan. Titan, a “world with two oceans”, is an organic-rich body with interior-surface-atmosphere interactions that are comparable in complexity to the Earth. Titan is also one of the few places in the Solar System with habitability potential. Titan’s remarkable nature was only partly revealed by the Cassini-Huygens mission and still holds mysteries requiring a complete exploration using a variety of vehicles and instruments. The proposed mission concept POSEIDON (Titan POlar Scout/orbitEr and In situ lake lander DrONe explorer) would perform joint orbital and in situ investigations of Titan. It is designed to build on and exceed the scope and scientific/technological accomplishments of Cassini-Huygens, exploring Titan in ways that were not previously possible, in particular through full close-up and in situ coverage over long periods of time. In the proposed mission architecture, POSEIDON consists of two major elements: a spacecraft with a large set of instruments that would orbit Titan, preferably in a low-eccentricity polar orbit, and a suite of in situ investigation components, i.e. a lake lander, a “heavy” drone (possibly amphibious) and/or a fleet of mini-drones, dedicated to the exploration of the polar regions. The ideal arrival time at Titan would be slightly before the next northern Spring equinox (2039), as equinoxes are the most active periods to monitor still largely unknown atmospheric and surface seasonal changes. The exploration of Titan’s northern latitudes with an orbiter and in situ element(s) would be highly complementary in terms of timing (with possible mission timing overlap), locations, and science goals with the upcoming NASA New Frontiers Dragonfly mission that will provide in situ exploration of Titan’s equatorial regions, in the mid-2030s.

In Situ Investigation of Under-Deposit Microbial Corrosion and its Inhibition Using a Multi-Electrode Array System

Carbon steel pipelines used in the oil and gas industry can be susceptible to the combined presence of deposits and microorganisms, which can result in a complex phenomenon, recently termed under-deposit microbial corrosion (UDMC). UDMC and its inhibition in CO2 ambiance were investigated in real-time using a multi-electrode array (MEA) system and surface profilometry analysis. Maps from corrosion rates, galvanic currents, and corrosion potentials recorded at each microelectrode allowed the visualization of local corrosion events on the steel surface. A marine bacterium Enterobacter roggenkampii, an iron-oxidizing, nitrate-reducing microorganism, generated iron deposits on the surface that resulted in pitting corrosion under anaerobic conditions. Areas under deposits displayed anodic behavior, more negative potentials, higher corrosion rates, and pitting compared to areas outside deposits. In the presence of the organic film-forming corrosion inhibitor, 2-Mercaptopyrimidine, the marine bacterium induced local breakdown of the protective inhibitor film and subsequent pitting corrosion of carbon steel. The ability of the MEA system to locally measure self-corrosion processes, galvanic effects and, corrosion potentials across the surface demonstrated its suitability to detect, evaluate and monitor the UDMC process as well as the efficiency of corrosion inhibitors to prevent this corrosion phenomenon. This research highlights the importance of incorporating the microbial component to corrosion inhibitors evaluation to ensure chemical effectiveness in the likely scenario of deposit formation and microbial contamination in oil and gas production equipment.

Non-Destructive In Situ Investigation of the Study of a Medieval Copper Alloy Door in Canosa di Puglia (Southern Italy)

This paper reports the analyses carried out on the medieval copper alloy door (1111–1118 AD) of the mausoleum of Boemondo d’Altavilla in Canosa di Puglia (Southern Italy). The studied door is the smallest medieval bronze door extant in Italy and, unlike the other Byzantine doors, was most probably made in Canosa di Puglia and not in Constantinople. Analyses were performed to assess the chemical composition of the alloy patinas using a portable energy dispersive X-ray fluorescence (ED-XRF) instrument designed at the University of Salento. The experimental results suggested that the two door leaves have the same chemical composition, even if they appear different in both style and size. Furthermore, the alloy used for the door is different from the other previously-analyzed Byzantine bronze doors. The obtained results can be used in the future to compare the chemical composition of other Byzantine doors in order to better understand the manufacture of these precious artifacts.

Electrochemical microelectrode degradation monitoring: in situ investigation of platinum corrosion at neutral pH

Objective. The stability of platinum and other noble metal electrodes is critical for neural implants, electrochemical sensors, and energy sources. Beyond the acidic or alkaline environment found in most electrochemical studies, the investigation of electrode corrosion in neutral pH and chloride containing electrolytes is essential, particularly regarding the long-term stability of neural interfaces, such as brain stimulation electrodes or cochlear implants. In addition, the increased use of microfabricated devices demands the investigation of thin-film electrode stability. Approach. We developed a procedure of electrochemical methods for continuous tracking of electrode degradation in situ over the complete life cycle of platinum thin-film microelectrodes in a unique combination with simultaneous chemical sensing. We used chronoamperometry and cyclic voltammetry to measure electrode surface and analyte redox processes, together with accelerated electrochemical degradation. Main results. We compared degradation between thin-film microelectrodes and bulk electrodes, neutral to acidic pH, different pulsing schemes, and the presence of the redox active species oxygen and hydrogen peroxide. Results were confirmed by mechanical profilometry and microscopy to determine material changes on a nanometer scale. We found that electrode degradation is mainly driven by repeated formation and removal of the platinum surface oxide, also within the electrochemical stability window of water. There was no considerable difference between thin-film micro- and macroscopic bulk electrodes or in the presence of reactive species, whereas acidic pH or extending the potential window led to increased degradation. Significance. Our results provide valuable fundamental information on platinum microelectrode degradation under conditions found in biomedical applications. For the first time, we deployed a unified method to report quantitative data on electrode degradation up to a defined endpoint. Our method is a widely applicable framework for comparative long-term studies of sensor and neural interface stability.

The Art of Everyday Objects: A Non-Invasive In Situ Investigation of Materials and Techniques of Italian Pop Art Paintings on Aluminium

Two paintings, made on aluminium support by Silvio Pasotti (among the major exponents of 1960s Italian pop art) were investigated in a totally non-invasive manner to identify the materials used by the artist. Raman spectroscopy, Fourier-transform infrared spectroscopy (FTIR), visible reflectance spectroscopy, and spectrofluorimetry with visible excitation were exploited as molecular analysis techniques, which are particularly suitable to recognise also synthetic organic materials, such as pigments and binders. The effectiveness of this multi-analytical approach was demonstrated, leading to the identification of several synthetic organic pigments, both conventional and “special effect” ones, introduced during the first half of the 20th century, as well as some well-established inorganic ones. Combining FTIR results both in the medium and near IR ranges, considerations regarding the binders employed by the artist could also be made, suggesting the use of both nitrocellulose and acrylic paints. Imaging techniques, such as IR reflectography, false colour IR, UV induced fluorescence, and portable microscopy, were also used to achieve a better knowledge of the painting practice.

Evaluation and Analysis of Dust Storm Activity in Tianwen-1 Landing Area Based on the Moderate Resolution Imaging Camera Observations and Mars Daily Global Maps

The first Mars exploration mission from China (Tianwen-1) was launched on 23 July 2020 with the goal of “orbiting, landing, and roving”. The occurrence of dust storm activities is an important criterion of assessing atmospheric risk for the Tianwen-1 landing process. Dust storm activities from Mars Year (MY) 24 to MY32 in southern Utopia Planitia were identified. Most dust storms only appeared in one Mars Daily Global Map (MDGM), with a lifetime of less than or equal to solar longitude (Ls) = 0.5°. Only if the lifetime of a dust storm is greater than or equal to Ls = 1° can it reach the primary landing ellipse. From Ls = 0–50°, dust storms are mostly in the diffusion stage with a maximum speed of movement of 2479 km/Ls. Then, the speed gradually decreases to the minimum value of 368 km/Ls when the dust storm is in the dissipation stage. If a dust storm moves at an average speed of 750 km/Ls, the safe landing zone is a circle within a radius of 750 km centered on the primary landing ellipse. From March to May 2021, eight dust storms were identified in the Moderate Resolution Imaging Camera (MoRIC) mosaics. Because there was no dust storm activity in MoRIC mosaic on 13 May 2021, we concluded that there would be no dust storm in the primary landing ellipse on 15 May (MY36, Ls = 45.1°). Therefore, the landing time of the Tianwen-1 probe was finally determined as 15 May, which successfully landed in the south of the Utopia Planitia, and the in-situ investigation was carried out by the Zhurong Mars rover.

A Durability Prediction Method for Historical Square Rebar Reinforced Concrete Buildings

Square rebars were developed and used for decades in the early development of reinforced concrete (RC) structures; however, the objectives of modern concrete structure durability analyses and standards are centered on round rebars in past decades, which are not suited for RC buildings utilizing square rebars. Considering the absence of proper evaluation techniques to evaluate the square rebar RC structures’ durability accurately, a novel durability prediction method has been proposed for this type of historical building. The method is based on major parts as in-situ investigation, finite element model simulation, component importance analysis, and structural durability prediction. The durability prediction calculation method was established on the experimental results of the realistic historical concrete tests and corrosion-induced cover cracking experiments for square rebar components. It was found that the carbonization-resistant ability of historical concretes was relatively weaker than that of current concretes and the calculation method for critical corrosion depth of square rebar was different from that of round rebar. Furthermore, two typical application cases are presented to introduce the procedure of the method in detail. Consequently, the research outcomes can be directly used on the durability prediction and protection works for historical RC buildings.