Statistical Mechanics of Unconfined Systems: Challenges and Lessons
Motivated by applications of statistical mechanics in which the system of interest is spatially unconfined, we present an exact solution to the maximum entropy problem for assigning a stationary probability distribution on the phase space of an unconfined ideal gas in an anti-de Sitter background. Notwithstanding the gas’ freedom to move in an infinite volume, we establish necessary conditions for the stationary probability distribution solving a general maximum entropy problem to be normalizable and obtain the resulting probability for a particular choice of constraints. As a part of our analysis, we develop a novel method for identifying dynamical constraints based on local measurements. With no appeal to a priori information about globally defined conserved quantities, it is therefore applicable to a much wider range of problems.