Fertilizers. Determination of chelating agents in fertilizers by chromatography

2017 ◽  
Keyword(s):  
1980 ◽  
Vol 45 (12) ◽  
pp. 3313-3319 ◽  
Author(s):  
Josef Komárek ◽  
Dalibor Kolčava ◽  
Lumír Sommer

The effect of chelating agents on the determination of cobalt in various flames, in a graphite cuvette and tantalum boat was studied considering the expected reaction mechanism of the atomization of cobalt and the reagent donor atom. A marked increase in the sensitivity of the determination of cobalt was observed in the presence of 1-(2-pyridylazo)-2-naphthol, pyrrolidinedithiocarboxylate, diethyldithiocarbamate, 8-mercaptoquinoline, 8-hydroxyquinoline and thenoyltrifluoroacetone for atomization from a tantalum boat. The optimum conditions for the determination of cobalt in the presence of 1-(2-pyridylazo)-1-naphthol are given.


1961 ◽  
Vol 33 (1) ◽  
pp. 150-151 ◽  
Author(s):  
Sarah. Mook ◽  
Ernest. Schonfeld ◽  
Dipen. Ghosh

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