scholarly journals PROSPECTS FOR THE USE OF TRICHLOROETHYL AMIDES WITH THIOAMIDE FUNCTIONS IN THE TECHNOLOGY OF BRILLIANT NICKEL PLATING

Author(s):  
Dmitriy Shurupov ◽  
Yuliya Andreeva ◽  
Yuliya Balyueva ◽  
Nina Sosnovskaya ◽  
Igor' Rozencveyg

The influence of organic additives in the nickel-plating sulfate electrolyte on the pos sibility of obtaining shiny coatings is investigated. The presence in the structure of the additive of trichloramide fragments and substituents containing a thiocarbonyl group-a residue of thiourea or rubeanoic acid, allows to obtain shiny nickel coatings without the introduction of additional reagents.

Author(s):  
Marina Shaferova ◽  
Nina Sosnovskaya ◽  
Valentina Kobelevskaya ◽  
Nikolay Korchevin

The introduction of available pyrazole-containing isothiuronium salts as additives to a standard nickel-plating sulfate electrolyte for the electrochemical production of shiny nickel coatings is considered


2020 ◽  
Vol 836 ◽  
pp. 151-157
Author(s):  
S.D. Polischuk ◽  
Yu.A. Stekolnikov ◽  
D.G. Churilov ◽  
N.V. Byshov ◽  
S.N. Borychev ◽  
...  

The physical-mechanical properties of chromium coatings from low-concentrated electrolytes with additions of organic substances were studied when comparing with similar ones from standard sulphate electrolyte. It has been established that the properties of chromium coatings from low concentrated electrolytes are superior to those of standard sulphate electrolyte. An additional advantage of low-concentrated electrolytes is less carry-over of chromium anhydrate through ventilation and wash water, which reduces the cost of cleaning them when they are discharged. However, under operating conditions, more frequent adjustment of the composition of such electrolytes is required. The electrolyte is distinguished by a good scattering over the surface of parts and covering power when restored to size on a thickness of 250-300 μm of hydraulic cylinders of agricultural and mining equipment, having a length of up to 4 m and a diameter of up to 0.5 m, an increased current output of up to 24-36 % and up to 3-4 times higher corrosion resistance, micro hardness of up to 1,300 kg / mm2, determined by the conditions of deposition relative to the standard sulfate electrolyte of chromium plating. Chromium coatings from a low-concentration electrolyte with organic additives passed the recommended tests for adhesion, tearing, wear and micro hardness according to GOST methods. Their use at the enterprises of technical service for repair of agricultural parts promises economic advantages in the field of practical application (higher deposition rate and less application time), as well as lower costs for environmental protection.


Author(s):  
Egor Verhoturov ◽  
Nina Shatohina ◽  
Nina Sosnovskaya

Isothiuronium salts from 5-chloromethylisoxazoles were synthesized for the first time. The resulting salts are used as gloss-forming additives to the Watts electrolyte in the process of applying nickel coatings.


2004 ◽  
Vol 228 (1-4) ◽  
pp. 326-333 ◽  
Author(s):  
F. Lallemand ◽  
L. Ricq ◽  
M. Wery ◽  
P. Berçot ◽  
J. Pagetti

2022 ◽  
Vol 1 (15) ◽  
pp. 89-92
Author(s):  
Nina Sosnovskaya ◽  
Nikolay Korchevin ◽  
Boris Skulin

The article deals with the study of the properties of 5-oxa-2,8-dithianonane as a brightening additive. The research was carried out by obtaining a shiny nickel coating at different concentrations of organic additives and different modes of electrolysis


Author(s):  
Anastasiya Preina ◽  
Valeriya Dmitrieva ◽  
Valentina Grabel'nyh ◽  
Nina Sosnovskaya

Based on chlorex, bis (2-chloroethyl) disubstituted isothiuronium salts containing additional oxygen or nitrogen atoms have been synthesized for amine and thiourea. The resulting salts were studied as gloss-forming additives in the Watts electrolyte for the electrochemical production of shiny nickel coatings. The electrolysis modes that ensure the production of high-quality coatings are found.


2017 ◽  
Vol 90 (4) ◽  
pp. 566-573 ◽  
Author(s):  
I. V. Antikhovich ◽  
D. S. Kharitonov ◽  
A. A. Chernik ◽  
I. B. Dobryden’

RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 30695-30698 ◽  
Author(s):  
Xingkai Zhang ◽  
Junyan Zhang

Aluminum was used as a reducing agent for preparing nickel coatings with excellent corrosion resistance from electroless plating baths containing no reducing agents.


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