scholarly journals Influence of single charge salting-out agents on solvent extraction of iron (III) from chloride solutions with oxygen-containing extractants

2021 ◽  
Vol 12 (2-2021) ◽  
pp. 234-246
Author(s):  
A. Y. Sokolov ◽  
◽  
A. G. Kasikov ◽  

The work is devoted to the solvent extraction of iron(III) from chloride solutions of single-charge salting-out agents with 2-octanone, 1-octanol, and their mixture at a 1:1 ratio. A comparison of the effect of the salting-out ability of single-charge cations on the extraction of iron (III) was made. It was found that at the cation concentration is less than 6 mol∙dm-3, the salting-out ability increases in the row NH4+ < K+ < Na+ < Li+ < H+.

2004 ◽  
Vol 74 (1-2) ◽  
pp. 173-177 ◽  
Author(s):  
B.Ramachandra Reddy ◽  
J.Rajesh Kumar ◽  
A.Varada Reddy

2019 ◽  
Vol 97 (8) ◽  
pp. 615-620
Author(s):  
Mustafa Jaipallah Abualreish ◽  
Adel Noubigh

This paper investigates the solubility–temperature dependence data for L-glutamic acid (Glu) in water and in some chloride salt (NaCl and KCl) aqueous solutions. Solubility data were determined from 293.15 to 318.15 K under atmospheric pressure by using a thermostatted reactor and the gravimetric method. After the investigation of the impact of inorganic salts on the solvency of Glu, it was found that the salting-out effect decreases in the following order: sodium chloride > potassium chloride. Results demonstrated that the solubility, in unadulterated water and in aqueous chloride solutions, increased with a rising temperature. The experimental data were well correlated by the semi-empirical equation. Using the measured solubilities, the standard molar thermodynamic properties of transfer of Glu (ΔtrG°, ΔtrH°, and ΔtrS°) from pure water to aqueous solutions of the chloride salts were estimated.


2002 ◽  
Vol 20 (3) ◽  
pp. 389-405 ◽  
Author(s):  
M. K. Jha ◽  
Vinay Kumar ◽  
R. J. Singh

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