Block copolymers from ionic liquids for the preparation of thin carbonaceous shells
2017 ◽
Vol 13
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pp. 1693-1701
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This paper describes the controlled radical polymerization of an ionic-liquid monomer by RAFT polymerization. This allows the control over the molecular weight of ionic liquid blocks in the range of 8000 and 22000 and of the block-copolymer synthesis. In this work we focus on block copolymers with an anchor block. They can be used to control the formation of TiO2 nanoparticles, which are functionalized thereafter with a block of ionic-liquid polymer. Pyrolysis of these polymer functionalized inorganic nanoparticles leads to TiO2 nanoparticles coated with a thin carbonaceous shell. Such materials may, e.g., be interesting as battery materials.
2015 ◽
Vol 2
(15)
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pp. 1500187
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2016 ◽
Vol 30
(3)
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pp. 2514-2523
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Keyword(s):
2017 ◽
Vol 164
(8)
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pp. H5031-H5035
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Keyword(s):
2011 ◽
Vol 28
(1)
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pp. 77-83
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Keyword(s):
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