scholarly journals Synthesis and Characterization of Metal Carbonyls M(CO)_6 (M=Cr,Mo,W) with Indole -3-carboxyaldehydemethanesulfonylhydrazone

2018 ◽  
Vol 1 (2) ◽  
pp. 31-34
Author(s):  
Sema SERT
Keyword(s):  
Synthesis And Characterization ◽  
Metal Carbonyls

Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

2003 ◽  
Vol 6 (7) ◽  
pp. 926-929 ◽  
Author(s):  
Ozan Sanlı Şentürk ◽  
Ümmühan Özdemir ◽  
Sema Sert ◽  
Nurcan Karacan ◽  
Fadime Uǧur (Sarikahya)
Keyword(s):  
Synthesis And Characterization ◽  
Metal Carbonyls

Synthesis and Characterization of Metal Carbonyls [M(CO)6(M =Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

2003 ◽  
Vol 58 (11) ◽  
pp. 1124-1127 ◽  
Author(s):  
Ozan Sanli Senturk ◽  
Sema Serta ◽  
Ümmuhan Özdemirc
Keyword(s):  
Photochemical Reaction ◽  
Spectroscopic Studies ◽  
Tridentate Ligand ◽  
Synthesis And Characterization ◽  
Donor Atom ◽  
Metal Carbonyls ◽  
Monodentate Ligand ◽  
H Nmr ◽  
Ft Ir

Abstract Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3(nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1-napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).

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