Study on Nickel Ferrite Formation by Using a Simple Method to Simulate Heat Transfer Surface

Author(s):  
Jei Won Yeon ◽  
Kwang Soon Choi ◽  
Yongju Jung ◽  
Selvaraj Rengaraj ◽  
Yeong Keong Ha ◽  
...  
2007 ◽  
Vol 124-126 ◽  
pp. 1565-1568 ◽  
Author(s):  
Jei Won Yeon ◽  
Kwang Soon Choi ◽  
Yongju Jung ◽  
Selvaraj Rengaraj ◽  
Yeong Keong Ha ◽  
...  

The condition of a heat transfer surface with boiling is composed of three environmental components; high temperature, high pressure and water vapor. In general an autoclave or a high temperature loop system is used for maintaining the required condition. The thermodynamic relationship of chemical reactions states that the free energy difference (ΔG) is clearly dependent on the reaction temperature and independent of the reaction pressure if the reaction has no volume change: (∂ΔG/∂P)T = ΔV ~ 0. Based on the above relationship, the high-pressure term was removed from the environmental components of the heat transfer surface. A vacuum quartz capsule with a moisturized metal oxide powder was used to study the formation of nickel ferrite. The feasibility of this simplified method to simulate a heat transfer surface was confirmed by an analysis of the FT-IR spectra and XRD pattern during the transformation of a nickel and iron mixed oxide into nickel ferrite.


2020 ◽  
Vol 2020 (0) ◽  
pp. 0074
Author(s):  
Noriyuki Unno ◽  
Kazuhisa Yuki ◽  
Ryo Inoue ◽  
Yasuo Kogo ◽  
Jun Taniguchi ◽  
...  

Author(s):  
Will Schreiber ◽  
John Kuo

Abstract The current paper describes a computer model designed to analyze the moisture transport in the unmelted, porous soil neighboring a convecting melt. The time-dependent fluid and heat flow in the soil melt is simulated implicitly using the SIMPLE method generalized to predict viscous fluid motion and heat transfer on boundary-fitted, non-orthogonal coordinates which adapt with time. TOUGH2, a general-purpose computer code for multiphase fluid and heat flow developed by K. Pruess at Lawrence Berkekey Laboratory, has been modified for use on time-adaptive, boundary-fitted coordinates to predict heat transfer, moisture and air transport, and pressure distribution in the porous, unmelted soil. The soil melt model is coupled with the modified TOUGH2 model via an interface (moving boundary) whose shape is determined implicitly with the progression of time. The computer model’s utility is demonstrated in the present study with a special two-dimensional study. A soil initially at 20°C and partially-saturated with either a 0.2 or 0.5 relative liquid saturation is contained in a box two meters wide by ten meters high with impermeable bottom and sides. The upper surface of the soil is exposed to a 20°C atmosphere to which vapor and air can escape. Computation begins when the soil, which melts at 1700°C, is heated from one side (maintained at constant temperatures ranging from 1700°C to 4000°C). Heat from the hot wall causes the melt to circulate in such a way that the melt interface grows more rapidly at the top of the box than at the bottom. As the upper portion of the melt approaches the impermeable wall it creates a bottle neck for moisture release from the soil’s lower regions. The pressure history of the trapped moisture is examined as a means for predicting the potential for moisture penetration into the melt. The melt’s interface movement and moisture transport in the unmelted, porous soil are also examined.


1999 ◽  
Vol 72 (1) ◽  
pp. 7-10
Author(s):  
D. S. Pashkevich ◽  
V. N. Krasnokutskii ◽  
V. B. Petrov ◽  
V. L. Korolev

Sign in / Sign up

Export Citation Format

Share Document