Ethanol Steam Reforming over La2O2CO3 Supported Ni-Ru Bimetallic Catalysts

2012 ◽  
Vol 457-458 ◽  
pp. 314-319
Author(s):  
Qiu Jie Shi ◽  
Bin Li ◽  
Wei Qing Chen ◽  
Cheng Wei Liu ◽  
Bi Wu Huang
2012 ◽  
Vol 457-458 ◽  
pp. 314-319 ◽  
Author(s):  
Qiu Jie Shi ◽  
Bin Li ◽  
Wei Qing Chen ◽  
Cheng Wei Liu ◽  
Bi Wu Huang

A series of Ni-Ru bimetallic catalysts over La2O2CO3 are prepared by an impregnation method. The catalytic properties are evaluated in ethanol steam reforming reaction from 350 to 700 °C under atmospheric pressure. Ni-Ru/La2O2CO3 containing 6 wt% Ni and 3 wt% Ru is found to be more efficient, and Ni-La composite oxide could be formed in the catalyst. Ru is more active in the ethanol dehydration reaction to form ethylene than Ni. The presence of Ru could improve the selectivity for hydrogen of Ni catalyst. TG results reveal that Ni-Ru/La2O2CO3 has excellent resistance to carbon deposition.


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