The Synthesis and Characterization of N-Propyl Pyridine Tetrafluoroborate

The halogenated hydrocarbon and pyridine are used in the synthesis of room temperature ionic liquid intermediates bromided N-propyl pyridine PPB, and the nuclear magnetic resonance instrument and the intermediate infrared spectrometer are used in chemical structure characterization, so it is determined that the synthesis is the room temperature ionic intermediates PPB. We use differential scanning calorimetric method for the determination of PPB melting point and enthalpy change. We use the double decomposition reaction of PPB and NaBF4in acetone for the synthesis of PP-BF4ionic liquids. We use infrared spectrometer for the structure characterization, it is proved that we have gotten PP-BF4room temperature ionic liquids. Solvent polarity and acid alkali both will have an influence on ultraviolet spectrum diagram displacement of room temperature ionic liquid, so in the research of ultraviolet spectrum diagram of ionic liquids and other solvent mixed solution, it is necessary to indicate which solvent is used.

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The Synthesis and Characterization of N-Butyl Pyridine Tetrafluoroborate

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.295-298.236 ◽

2013 ◽

Vol 295-298 ◽

pp. 236-239 ◽

Cited By ~ 1

Author(s):

Peng Tian ◽

Bo Meng ◽

Hong Bo Zhang ◽

Tian Ling Qin ◽

Yang Yang Song ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Solvent Polarity ◽

Room Temperature Ionic Liquid ◽

Ultraviolet Spectrum ◽

Structure Characterization ◽

Differential Scanning Calorimetric ◽

Mixed Solution ◽

Infrared Spectrometer

The halogenated hydrocarbon and pyridine are used in the synthesis of room temperature ionic liquid intermediates chlorinated N-butyl pyridine BPC, and the nuclear magnetic resonance instrument and the intermediate infrared spectrometer are used in chemical structure characterization, so it is determined that the synthesis is the room temperature ionic intermediates BPC. We use differential scanning calorimetric method for the determination of BPC melting point and enthalpy change. We use the double decomposition reaction of BPC and NaBF4 in acetone for the synthesis of BP-BF4ionic liquids. We use infrared spectrometer for the structure characterization, it is proved that we have gotten BP-BF4room temperature ionic liquids. Solvent polarity and acid alkali both will have an influence on ultraviolet spectrum diagram displacement of room temperature ionic liquid, so in the research of ultraviolet spectrum diagram of ionic liquids and other solvent mixed solution, it is necessary to indicate which solvent is used.

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The Preparation of N-Heptyl Pyridine Tetrafluoroborate

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.685.102 ◽

2014 ◽

Vol 685 ◽

pp. 102-105

Author(s):

Ting Ting Xu ◽

Cheng Cheng Zhang ◽

Peng Tian ◽

Ji Dong Duan ◽

Qing Wen Shen

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Solvent Polarity ◽

Room Temperature Ionic Liquid ◽

Ultraviolet Spectrum ◽

Structure Characterization ◽

Differential Scanning Calorimetric ◽

Mixed Solution ◽

Infrared Spectrometer

The halogenated hydrocarbon and pyridine are used in the synthesis of room temperature ionic liquid intermediates bromided N-heptyl pyridine HEPB, and the nuclear magnetic resonance instrument and the intermediate infrared spectrometer are used in chemical structure characterization, so it is determined that the synthesis is the room temperature ionic intermediates HEPB. We use differential scanning calorimetric method for the determination of HEPB melting point and enthalpy change. We use the double decomposition reaction of HEPB and NaBF4in acetone for the synthesis of HEP-BF4ionic liquids. We use infrared spectrometer for the structure characterization, it is proved that we have gotten HEP-BF4room temperature ionic liquids. Solvent polarity and acid alkali both will have an influence on ultraviolet spectrum diagram displacement of room temperature ionic liquid, so in the research of ultraviolet spectrum diagram of ionic liquids and other solvent mixed solution, it is necessary to indicate which solvent is used.

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Preparation and Characterization of N-Octyl Pyridine Tetrafluoroborate

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.707.16 ◽

2014 ◽

Vol 707 ◽

pp. 16-19 ◽

Cited By ~ 4

Author(s):

Peng Tian ◽

Yan Hong Kang ◽

Li Yan Liu ◽

Jie Lu

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Solvent Polarity ◽

Room Temperature Ionic Liquid ◽

Ultraviolet Spectrum ◽

Structure Characterization ◽

Mixed Solution ◽

Halogenated Hydrocarbon ◽

Infrared Spectrometer

Ionic liquids combine a set of proper ties like non-flammability, non-volatility, high ionic density and intrinsically high ionic conductivity; they also behave as good solvents for various chemical and electrochemical processes. These attributes make them appealing as alternative materials to replace conventional solvents, wherefore the interest in ionic liquid based materials for diverse electrochemical devices has boosted in the last few decades. The halogenated hydrocarbon and pyridine are used in the preparation of room temperature ionic liquid intermediates bromided N-octyl pyridine OPB, and the intermediate infrared spectrometer are used in chemical structure characterization, so it is determined that the product is the room temperature ionic intermediates OPB. Infrared spectrometer for the structure characterization is used, it is proved that OP-BF4 room temperature ionic liquid has been gotten. Both solvent polarity and acid alkali have an influence on ultraviolet spectrum diagram displacement of room temperature ionic liquid. If the ultraviolet spectrum diagram of ionic liquids and other solvent mixed solution is studied, it is necessary to indicate which solvent is used.

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Preparation and Characterization of N-Butyl Pyridine Nitrate

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.295-298.220 ◽

2013 ◽

Vol 295-298 ◽

pp. 220-223 ◽

Cited By ~ 1

Author(s):

Peng Tian ◽

Zhi Gang Zhao ◽

Yang Yang Song ◽

Bo Meng ◽

Tian Ling Qin ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Solvent Polarity ◽

Decomposition Reaction ◽

Room Temperature Ionic Liquid ◽

Ultraviolet Spectrum ◽

Mixed Solution ◽

Halogenated Hydrocarbon ◽

Double Decomposition

The halogenated hydrocarbon and pyridine are used in the synthesis of room temperature ionic liquid intermediates chlorinated N-butyl pyridine BPC. We use the double decomposition reaction of BPC and NaNO3in acetone for the synthesis of BP-NO3 ionic liquids. We use infrared spectrometer for the structSubscript texture characterization, it is proved that we have gotten BP-NO3room temperature ionic liquids. Solvent polarity and acidSubscript textalkali both will have a room temperature ionic liquid ultraviolet spectrum diagram happen displacement, so in the ionic liquid and other solvent mixed solution of ultraviolet spectrum diagram, want to indicate the use of solvent. Therefore, solvent polarity and acid alkali both will have an influence on ultraviolet spectrum diagram displacement of room temperature ionic liquid.

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When do defectless alkanethiol SAMs in ionic liquids become penetrable? A molecular dynamics study

Physical Chemistry Chemical Physics ◽

10.1039/c5cp04566e ◽

2015 ◽

Vol 17 (47) ◽

pp. 31947-31955 ◽

Cited By ~ 10

Author(s):

Sergey A. Kislenko ◽

Victoria A. Nikitina ◽

Renat R. Nazmutdinov

Keyword(s):

Molecular Dynamics ◽

Ionic Liquid ◽

Ionic Liquids ◽

Molecular Dynamics Simulations ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Self Assembled Monolayers ◽

Assembled Monolayers ◽

Self Assembled ◽

Dynamics Simulations

Molecular dynamics simulations were performed to address the permeability of defectless alkanethiol self-assembled monolayers (SAMs) on charged and uncharged Au(111) surfaces in 1-butyl-3-methylimidazolium ([bmim][BF4]) room-temperature ionic liquid (IL).

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Organic Reactions in Ionic Liquids: Ionic Liquid-accelerated Facile Synthesis of 3-alkyl-2,4-thiazolidinediones

Journal of Chemical Research ◽

10.3184/030823405774663273 ◽

2005 ◽

Vol 2005 (8) ◽

pp. 492-494 ◽

Cited By ~ 3

Author(s):

De-Hong Yang ◽

Ben-Yong Yang ◽

Zhen-Chu Chen ◽

Song-Ying Chen ◽

Qin-Guo Zheng

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Organic Reactions ◽

Green Solvent ◽

Facile Synthesis ◽

Rate Enhancement ◽

Significant Rate

The room temperature ionic liquid [bmim]PF6 is a new green solvent for the N-alkylation of 2,4-thiazolidinones. Significant rate enhancement and improved yields have been observed.

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Differential scanning calorimetric study of nonionic surfactant mixtures with a room temperature ionic liquid, bmimBF4

Journal of Colloid and Interface Science ◽

10.1016/j.jcis.2009.05.031 ◽

2009 ◽

Vol 338 (1) ◽

pp. 308-311 ◽

Cited By ~ 5

Author(s):

Tohru Inoue ◽

Yuka Higuchi ◽

Takeshi Misono

Keyword(s):

Ionic Liquid ◽

Nonionic Surfactant ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Differential Scanning Calorimetric ◽

Calorimetric Study ◽

Surfactant Mixtures

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A fluorescence study of the solute–solvent interactions of aminochalcones in a room-temperature ionic liquid

Pure and Applied Chemistry ◽

10.1351/pac-con-12-10-28 ◽

2013 ◽

Vol 85 (7) ◽

pp. 1451-1463 ◽

Cited By ~ 1

Author(s):

Kotni Santhosh ◽

G. Krishnamurthy Grandhi ◽

Snigdha Ghosh ◽

Anunay Samanta

Keyword(s):

Ionic Liquid ◽

Room Temperature ◽

Solvent Polarity ◽

Fluorescence Decay ◽

Room Temperature Ionic Liquid ◽

Excitation Wavelength ◽

Solvation Dynamics ◽

Time Resolved ◽

Solvent Interactions ◽

The One

Unlike most other electron donor–acceptor (EDA) molecules, aminochalcones exhibit unusual solvent polarity-dependent fluorescence behavior. The photophysical behavior of two aminochalcones, namely, 4-aminochalcone (AC) and 4-dimethylaminochalcone (DMAC), has been studied in a viscous room-temperature ionic liquid (IL), 1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6], by steady-state and time-resolved fluorescence techniques. The observation of a single emission band in viscous IL, which is similar to the one observed in less viscous polar conventional solvents, suggests no twisting is necessary for the formation of the charge-transfer state from which the emission of aminochalcones originates. The fluorescence decay profiles, solvation dynamics, and excitation-wavelength-dependent emission behavior of AC are found to be quite different from those of DMAC in the IL. The observed difference is attributed to specific H-bonding interaction between AC and [bmim][PF6].

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Coumarin Synthesis via Knoevenagel Condensation in Moisture Stable Room Temperature Ionic Liquids

Journal of Chemical Research ◽

10.3184/030823403103173868 ◽

2003 ◽

Vol 2003 (5) ◽

pp. 294-295 ◽

Cited By ~ 9

Author(s):

Weiliang Bao ◽

Zhiming Wang ◽

Yuxia Li

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Room Temperature ◽

Knoevenagel Condensation ◽

Reaction Medium ◽

Room Temperature Ionic Liquid ◽

Room Temperature Ionic Liquids ◽

Structure System ◽

Coumarin Synthesis

Several coumarins have been synthesised by Knoevenagel condensation in the piperidine/HOAc/moisture stable room temperature ionic liquid ([Emim]+BF4- referring to structure) system at room temperature; the yield of the reaction is good and the reaction medium can be recycled.

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