Synthesis and Radical Polymerizations of N-Substituted Maleimide Bearing Two Olefinic Groups

2014 ◽  
Vol 1033-1034 ◽  
pp. 619-622
Author(s):  
Hua Jing Gao ◽  
Zhao Hui Jin
Keyword(s):  
Maleic Anhydride ◽  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Optically Active ◽  
Optically Active Polymers ◽  
Allyl Ester ◽  
Radical Polymerizations ◽  
Alcohol Radical

A kind of N-substituted maleimide - having two olefinic bonds with different reactivities, (S)-N-Maleoyl-L-leucine allyl ester ((S)-ALMI), was synthesized from maleic anhydride, L-leucine and allyl alcohol. Radical polymerizations were carried out to obtain optically active polymers using 2,2′-azobisisobutyronitrile. Structures of the monomer and polymers obtained were investigated by NMR measurements. In radical polymerizations, the solvents strongly affect the radical polymerization behaviors of (S)-ALMI.

Optically active polymers, 2. Copolymerization of limonene with maleic anhydride

1994 ◽  
Vol 195 (5) ◽  
pp. 1843-1850 ◽  
Author(s):  
Jolanta Maślińska-Solich ◽  
Teobald Kupka ◽  
Mirosław Kluczka ◽  
Anton Solich
Keyword(s):  
Maleic Anhydride ◽  
Optically Active ◽  
Optically Active Polymers

Studies of Allyl Alcohol Radical Polymerization by PFG-HMQC and HMBC NMR at 750 MHz

2002 ◽  
Vol 35 (7) ◽  
pp. 2602-2607 ◽  
Author(s):  
Sung Joon Oh ◽  
David R. Kinney ◽  
Wei Wang ◽  
Peter L. Rinaldi
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Alcohol Radical

Radical Polymerizations of Optically Active Methacrylamides Having Oxazoline Moieties

2014 ◽  
Vol 955-959 ◽  
pp. 732-735
Author(s):  
Chao Yuan ◽  
Ying Bo Tao ◽  
Xiao Xiao Li ◽  
Xiao Meng Liu
Keyword(s):  
Radical Polymerization ◽  
Specific Rotation ◽  
Optically Active ◽  
Molecular Weights ◽  
Radical Polymerizations

A novel type of chiral N-substituted methacrylamide derivatives bearing an oxazoline pendant (OPMAM) had been synthesized. Radical polymerization were carried out to produced corresponding polymers with high specific rotation in moderate yields. The polymerization characteristics and the chiroptical behavior of the resultant polymers have been examined in detail by using HPLC and CD and UV-vis spectra. The polymers showed relatively high molecular weights(Mn=5000-15000). The abolutely value of the specific rotation of poly(OPMAM)s basically increased with increasing the molecular weights.

Radical Polymerization of a Novel Methacrylamide Derivative

2015 ◽  
Vol 1095 ◽  
pp. 359-362
Author(s):  
Chao Yuan ◽  
Ping Liu ◽  
Long Hua Chen ◽  
Yuan Zhang
Keyword(s):  
Radical Polymerization ◽  
Optical Rotation ◽  
Optically Active ◽  
Optically Active Polymers ◽  
Specific Optical Rotation ◽  
Polymer Yield ◽  
Molecular Weights ◽  
H Nmr

The radical polymerization of a novel methacrylamide derivative, N-[o-(4-ethyl-4, 5-dihydro-1, 3-oxazol-2-yl) phenyl] methacrylamide ((S)-EtOPMAM), was carried out to obtained optically active polymers. The polymer yield and the chiroptical behavior of the resultant polymers have been examined in detail by using IR and 1H NMR spectroscopies in comparison with our previous observation. The polymers showed relatively high molecular weights (Mn=8000-16000) and largest specific rotations ([α]25D =+120.6o). Particularly, the largest specific optical rotation of the polymer is almost the six times of the monomer.

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