Synthesis and Application of 1-(2,5-dimethyl-3-thiazolyl)-2-[2-methyl-5-phenyl-(4-vinyl)-3-thiophene]perfluorocyclopentene

2014 ◽  
Vol 1078 ◽  
pp. 90-93
Author(s):  
Fang Duan ◽  
Gang Liu ◽  
Qing Zhang
Keyword(s):  
Visible Light ◽  
Reversible Cyclization

A new unsymmetrical photochromic diarylethene 1-(2,5-dimethyl-3-thiazolyl)-2-[2-methyl-5-phenyl-(4-vinyl)-3-thiophene] perfluorocyclopentene (1o) was designed and constructed successfully. And its photochromic reactivity, HPLC, kinetics were also investigated systematically. Upon alternating irradiation with UV and visible light in solution, this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions. Diarylethene 1 changed the color from colorless to orange, in which absorption maxima were observed at 596 nm in acetonitrile. What is more, the photoconversion ratio of 1 is 37%.

Synthesis and Characterization of Unsymmetrical Diarylethene Based on Phenylpentane

2014 ◽  
Vol 707 ◽  
pp. 60-63
Author(s):  
Xiao Dong Zhang ◽  
Sha Sha Wei ◽  
Shou Zhi Pu
Keyword(s):  
Visible Light ◽  
Synthesis And Characterization ◽  
Reversible Cyclization

An unsymmetrical photochromic diarylethene, 1-[2-methyl-3-benzothiophene]-2-[2-methyl-5-(4-pentylphenyl)-3-thienyl] perfluorocyclopentene (1a), has been synthesized, and its properties including photochromism and fluorescence have been investigated. The results showed that this compound undergo reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in solution.

Photochromism and Fluorescence of a Novel Unsymmetrical Diarylethene Material Bearing Benzene and Thiophene Ring

2012 ◽  
Vol 164 ◽  
pp. 251-254 ◽  
Author(s):  
Shu Hong Jing ◽  
Shou Zhi Pu ◽  
Hui Li
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Thiophene Ring ◽  
Amorphous Film ◽  
Optical Storage ◽  
Optical Recording ◽  
Pmma Film ◽  
Recording Medium ◽  
Solid States ◽  
Reversible Cyclization

A new photochromic diarylethene compound, 1-[2-methyl-(5-(4- dioxolane) phenyl)-3-thienyl]-2-(2-methyl-3-benzothiophene)perfluorocyclopentene (1o)was synthesized. Its properties, including photochromism and fluorescence were investigated in detail both in solution and PMMA amorphous film. It underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in hexane. The compound showed good phtochromism both in solution and in solid states. Diarylethene 1o changed the color from colorless to purple upon irradiation with 297 nm UV light, in which absorption maxima were observed at 539 nm in hexane and at 547nm in PMMA film, respectively. Using diarylethene 1c/PMMA film as recording medium, optical recording was performed successfully. This new photochromic system also exhibited remarkable optical storage character

Synthesis, Photochromism Properties of a Hybrid Diarylethene Based on Hydroxyl Group

2011 ◽  
Vol 393-395 ◽  
pp. 385-388
Author(s):  
Duo Hua Jiang ◽  
Wei Jun Liu ◽  
Shi Qiang Cui ◽  
Gang Liu
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Amorphous Film ◽  
Methanol Solution ◽  
Fluorescence Properties ◽  
Hydroxyl Group ◽  
Pmma Film ◽  
Open Ring ◽  
Reversible Cyclization

A novel unsymmetrical diarylethene derivative 1-[2-methyl-5-(3-trifluoromethylphenyl)-3-thienyl]-2-[2-methyl-5-(4-hydroxylphenyl)-3-thienyl]hexafluorocyclopentene (1a) was successfully synthesized. The properties of the compound, including photochromic and fluorescence properties of the diarylethene were also investigated systematically. The results showed that this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film, and its absorption maxima were observed at 593 nm in methanol and at 598 nm in PMMA amorphous film, respectively, upon irradiation with 297 nm UV light. In methanol solution, the open-ring isomer of the diarylethene 1 exhibited relatively fluorescence at 569 nm when excited at 360 nm.

Study on Composite Photochromic Properties of New Diarylethenes Bearing Naphthyl Rings

2012 ◽  
Vol 583 ◽  
pp. 134-137
Author(s):  
Pan Pan Ren ◽  
Shou Zhi Pu
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Amorphous Film ◽  
Optoelectronic Properties ◽  
Pmma Film ◽  
Amorphous Films ◽  
Photochromic Properties ◽  
Reversible Cyclization

A novel photochromic diarylethene, 1-[(2-methyl-5-(4-fluorophenyl)-3-thienyl)]-2-(2-methyl-1-naphthyl) perfluorocyclopentene (1o), was synthesized. Its optoelectronic properties, such as photochromism in solution as well as in poly-methylmethacrylate (PMMA) amorphous films, fluorescences switch were investigated in detail. The results showed that this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film, and its absorption maxima were observed at 511 nm in hexane and at 522 nm in PMMA amorphous film, respectively, upon irradiation with 297 nm UV light.

Synthesis and Application of 1-[2-Methyl-5-Phenyl-3-Thiophene]-2-[2-Methyl-5-Phenyl-(4-Vinyl)-3-Thiophene]Perfluorocyclopentene

2014 ◽  
Vol 662 ◽  
pp. 87-90
Author(s):  
Ying Long Fu ◽  
Xue Li ◽  
Gang Liu
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Reversible Cyclization

A new unsymmetrical photochromic diarylethene 1-(2-methyl-5-phenyl-3-thiophene)-2-[2-methyl-5-phenyl-(4-vinyl)-3-thiophene] perfluorocyclopentene (1o) has been synthesized, and its photochromic reactivity, fluorescent were also investigated. The results showed this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in solution,Diarylethene 1 changed the color from colorless to blue upon irradiation with 297 nm UV light, in which absorption maxima were observed at 596 nm in acetonitrile.

Synthesis and Properties of a New Unsymmetrical Diarylethene Bearing Two Thiophene Rings

2012 ◽  
Vol 490-495 ◽  
pp. 3672-3675
Author(s):  
Hui Li ◽  
Yuan Ming Tu ◽  
Gang Liu
Keyword(s):  
Visible Light ◽  
Fluorescence Intensity ◽  
Fluorescence Property ◽  
Pmma Film ◽  
Isomeric Compound ◽  
Fluorescence Switch ◽  
Reversible Cyclization

A new unsymmetrical photochromic diarylethene has been synthesized, namely {1-(2,5-dimethyl-3-thienyl),2-[2-methyl-5-(4-trifluoromethylphenyl)-3-thienyl]}perfluorocyclopentene. Its properties, including photochromic reactivity in solution and fluorescence property both in solution and in PMMA film were investigated. It underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light. The isomeric compound functioned as a fluorescence switch by photoirradiation both in solution and in PMMA film. The fluorescence intensity also showed regular changes along with the change of concentration.

A Novel Unsymmetrical Diarylethene Material Bearing Double Thiophene Ring

2013 ◽  
Vol 763 ◽  
pp. 65-68
Author(s):  
Shu Hong Jing ◽  
Cong Bin Fan ◽  
Shou Zhi Pu
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Thiophene Ring ◽  
Amorphous Film ◽  
Optical Recording ◽  
Pmma Film ◽  
Recording Medium ◽  
Solid States ◽  
Reversible Cyclization

A new photochromic diarylethene compound, 1-[2-methyl-5-(3-thienyl)-3-thieny-2-[2-methyl-5-(3-benzaldehyde)-3-thieny perfluorocyclopentene (1a) was synthesized. Its properties, including photochromism and fluorescence were investigated in detail both in solution and PMMA amorphous film. It underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in hexane. The compound showed good phtochromism both in solution and in solid states. Diarylethene 1a changed the color from colorless to navy upon irradiation with 297 nm UV light, in which absorption maxima were observed at 577 nm in hexane and at 592 nm in PMMA film, respectively. Using diarylethene 1b/PMMA film as recording medium, optical recording was performed successfully.

A New Photochromic Diarylethene for Reversible Molecule Switching Properties Based on Pyrrole and Thiophene

2011 ◽  
Vol 284-286 ◽  
pp. 2239-2242
Author(s):  
Shang Hua He ◽  
Gang Liu ◽  
Ren Jie Wang
Keyword(s):  
Visible Light ◽  
Reaction Kinetics ◽  
Absorption Maximum ◽  
Uv Light ◽  
Amorphous Film ◽  
Pmma Film ◽  
Reversible Cyclization ◽  
Hexane Solution

A new unsymmetrical photochromic diarylethene bearing a pyrrole and a thiophene aryl unit 1-(5-cyan-1,2-dimethylpyrrole)-2-(5-aldehyde-2-butylthiophene) perfluorocyclopentene(1a) has been synthesized. Its properties, including photochromism and kinetics were investigated in detail. It underwent reversible cyclization and cycloreversion reactions upon alternating with UV and visible light both in solution and in PMMA film. The results showed that this compound exhibited reversible photochromism, changing from colorless to blue upon irradiation with UV light, in which absorption maximum were observed at 649 nm and 583 nm in solution and PMMA amorphous film, respectively. This new photochromic system also exhibited remarkable reaction kinetics in hexane solution.

Study on Material Properties with Synthesis and Property of a Novel Unsymmetrical Photochromic Diarylethene

2013 ◽  
Vol 327 ◽  
pp. 94-98
Author(s):  
Hong Yan Xu ◽  
Shou Zhi Pu ◽  
Ren Jie Wang
Keyword(s):  
Visible Light ◽  
Material Properties ◽  
Uv Light ◽  
Amorphous Film ◽  
Optical Recording ◽  
Pmma Film ◽  
Recording Medium ◽  
Photochromic Properties ◽  
Reversible Cyclization

A novel unsymmetrical diarylethene derivative bearing both benzofuran and thiophene moieties, 1-(2-methyl--3-benzofuranyl)-2-[(2-methyl-3-thienyl-5-thienyl)-3-thieny perfluorocyclopentene (1o), was synthesized. At the same time, its photochromic properties were investigated in detail. The results showed that this compound exhibited reversible photochromism, undergoing reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film, and its absorption maxima were observed at 523 nm in hexane and at 539 nm in PMMA amorphous film, respectively, upon irradiation with 297 nm UV light. Finally, using this diarylethene as recording medium, polarization optical recording was carried out successfully.

Synthesis and Property of a New 2,4-Position Hybrid Diarylethene Bearing both Benzene and Isoxazole Moieties

2011 ◽  
Vol 474-476 ◽  
pp. 1569-1572
Author(s):  
Hui Li ◽  
Shou Zhi Pu ◽  
Gang Liu ◽  
Wei Jun Liu
Keyword(s):  
Visible Light ◽  
Uv Light ◽  
Optical Storage ◽  
Reversible Cyclization

A new photochromic diarylethene of bis(4-isoxazolyl)ethene and bis(2-phenyl)ethene was synthesized. Its properties, including photochromism and fluorescence were investigated in detail. It underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light in hexane. The results showed that this compound exhibited reversible photochromism and good fluorescent switching in solution after irradiation with UV light and visible light. Using this dithienylethene 1c as optical storage recording was performed successfully.

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