Preparation of Pd Membrane Supported on Al2O3 Nanofiber Nonwoven Used in Hydrogen Separation

2011 ◽  
Vol 221 ◽  
pp. 662-667
Author(s):  
Jie Shi ◽  
Di Jia ◽  
Bo Wen Cheng ◽  
Wei Min Kang ◽  
Xue Bai

. In this paper, thin palladium (Pd) membranes, which are supported on alumina nanofiber nonwoven produced by electrospinning method, were prepared by electroless plating method. The influence of different pretreatment methods (iron wire activation) and reducing agent (sodium hypophosphite and hydrazine hydrate) on the structure of Pd membrane were studied. The morphology, surface element and crystal structure of the Pd membrane were investigated by SEM, EDS and XRD. The results showed that the compact Pd membrane was formed on the alumina nanofiber nonwoven when the pretreatment method of iron wire activation was adopted and the reducing agent of sodium hypophosphite was used, which will be applied widely in hydrogen separation area.

2007 ◽  
Vol 154 (7) ◽  
pp. E91 ◽  
Author(s):  
Hiroki Uchiyama ◽  
Masato Sone ◽  
Chiemi Ishiyama ◽  
Tatsuro Endo ◽  
Takeshi Hatsuzawa ◽  
...  

2011 ◽  
Vol 179-180 ◽  
pp. 1309-1313 ◽  
Author(s):  
Xiao Liang Zhang ◽  
Xu Feng Xie ◽  
Yan Huang

Pd-based composite membranes are the attractive membrane materials for hydrogen separation due to their high hydrogen permeability and infinite permselectivity. Thin pure Ni and Pd-Ni alloy membranes with high hydrogen permeation were prepared by the electroless plating method. It is difficult to prepare the dense pure Ni membranes with 1-2 μm thickness for hydrogen separation. However, Pd-Ni alloy membranes with several micrometers thickness showed good permeation performance. Hydrogen permeance of the Pd95Ni5 alloy membrane with fcc phase up to 3.1×10-6 mol/m2 s Pa and the ideal permselectivity over 600 were obtained at 773 K.


2005 ◽  
pp. 1013-1018
Author(s):  
Qiang Zeng ◽  
Y. Bayazitoglu ◽  
Jiang Zhu ◽  
Kenneth Wilson ◽  
M. Ashraf Imam ◽  
...  

2016 ◽  
Vol 89 ◽  
pp. 1278-1282 ◽  
Author(s):  
Chang-Hyun Song ◽  
Youngmin Kim ◽  
Byeong-Kwon Ju ◽  
Jong-Woong Kim

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