Fabrication of Mesoporous ZrO2 by Using Rosin-Based Quaternary Ammonium Salt

2011 ◽  
Vol 239-242 ◽  
pp. 3257-3261 ◽  
Author(s):  
Peng Wang ◽  
Zhen Dong Zhao ◽  
Li Zhi He ◽  
Liang Wu Bi ◽  
Yu Xiang Chen
Keyword(s):  
Ammonium Salt ◽  
Significant Influence ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
High Surface ◽  
Textural Properties ◽  
Precipitation Method ◽  
Adsorption And Desorption ◽  
Surface Areas ◽  
Ft Ir

Mesoporous zirconias were prepared by precipitation method using rosin-based quaternary ammonium salt as a directing agent. The samples were characterized by means of XRD, FT-IR and N2-adsorption and desorption measurements. The phase of precursors was amorphous, and well crystallized tetragonal zirconias were obtained after the calcination at 450 °C. The synthesized mesoporous zirconias possessed high surface areas ranging from 183.56 to 203.87 m2g-1and big pore diameters varying from 6.27 to 7.58 nm. The content of the rosin-based quaternary ammonium salt had significant influence on the textural properties of the mesoporous zirconias. Surface areas, pore volumes and pore diameters of the mesoporous zirconias decreased when increasing the surfactant dosage.

Preparation of Novel Gemini Quaternary Ammonium Salt Cationic Surfactant

2012 ◽  
Vol 174-177 ◽  
pp. 1433-1436 ◽  
Author(s):  
Zong Cheng Miao ◽  
Fang Wang ◽  
Deng Deng ◽  
Yong Ming Zhang ◽  
Xiao Ping Huo ◽  
...  
Keyword(s):  
Surface Tension ◽  
Ammonium Chloride ◽  
Cationic Surfactant ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Foam Stability ◽  
High Surface ◽  
Amine Hydrochloride ◽  
Gemini Cationic Surfactant

In order to obtain some novel cationic surfactants with high surface activity, n-octadecyldimethylamine and epichlorohydrin were used to synthesize 2-hydroxy-1, 3-dis (chloride octadecyl dimethyl ammonium) propane, which was a kind of gemini quaternary ammonium salt. N-octadecyldimethylamine and epichlorohydrin were used to prepare active epoxy intermediate glycidyloctadecyldimethyl ammonium chlorided, and then glycidyloctadecyldimethyl ammonium chlorided was reacted with octadecyldimethyl amine hydrochloride to synthesize the gemini cationic surfactant. FTIR and 1H NMR were used to represent structure of the gemini cationic surfactant. The interface characteristics were studied in detail. The critical micellar concentration (CMC) was determined by surface tension test to obtain the values of CMC and surface tension at CMC. The foam ability and foam stability of the gemini cationic surfactant were also discussed through contrast octadecyltrimethyl ammonium chloride and cetyltrimethyl ammonium chloride.

Characterization and Properties of Antheraea pernyi Silk Finished with Reactive Quaternary Ammonium Salt of Chitosan

2011 ◽  
Vol 175-176 ◽  
pp. 288-293 ◽  
Author(s):  
Yan Hua Lu ◽  
De Hong Cheng ◽  
Zhao Dan Yang
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Silk Fiber ◽  
Water Soluble ◽  
Chitosan Derivative ◽  
Sem Images ◽  
Antheraea Pernyi ◽  
Before And After ◽  
Ft Ir

In order to obtain a water soluble and reactive chitosan derivative, quaternary ammonium salt groups and acrylamidomethyl groups were introduced to chitosan by two steps. The chitosan derivative, reactive quaternary ammonium salt of chitosan, was then applied to Antheraea pernyi (A. pernyi) silk by padding and curing method. FT-IR, XRD and SEM were used to characterize the structure of A. pernyi silk before and after treatment. The peak in FT-IR spectra at 1480 cm-1 and 1650 cm-1 revealed the crosslinking reactions of A. pernyi silk fibroin and reactive quaternized chitosan. The XRD results indicated the crystallinity of the treated silk fiber increase a little in comparison with the untreated ones. SEM images clearly showed the reactive quaternary ammonium salt of chitosan attached on the surface of the treated A. pernyi silk fiber, while the surface of the untreated sample was relatively smooth. The thermal stability of the treated silk fiber was enhanced compared to the untreated one by DSC analysis. It was also found that the antibacterial activity of the treated A. pernyi silk fabric against E. coli was more than 99%.

Catalyst- and oxidant-free electrochemical para-selective hydroxylation of N-arylamides in batch and continuous-flow

2020 ◽  
Vol 22 (19) ◽  
pp. 6437-6443
Author(s):  
Cheng-Kou Liu ◽  
Meng-Yi Chen ◽  
Xin-Xin Lin ◽  
Zheng Fang ◽  
Kai Guo
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Continuous Flow ◽  
Quaternary Ammonium Salt ◽  
Selective Hydroxylation

A catalyst-, oxidant-, acidic solvent- and quaternary ammonium salt-free electrochemical para-selective hydroxylation of N-arylamides at rt in batch and continuous-flow was developed.

Synthesis and Performance of Polyoxy-ethylene Ester Quaternary Ammonium Salt

2013 ◽  
Vol 50 (1) ◽  
pp. 9-13 ◽  
Author(s):  
Yong-Qiang Sun ◽  
Wen-Jing Li ◽  
Wan-Xu Wang ◽  
Qiu-Xiao Li ◽  
Wieslaw Hreczuch ◽  
...  
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
And Performance

Instability of Solutions of Quaternary Ammonium Permanganates in Dichloromethane

1997 ◽  
Vol 62 (6) ◽  
pp. 849-854 ◽  
Author(s):  
Vladislav Holba ◽  
Renata Košická
Keyword(s):  
Ammonium Salt ◽  
Rate Constants ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Activation Parameters ◽  
The Stability

The paper deals with instability of solutions of quaternary ammonium permanganates, QMnO4 (Q = tetraethyl-, tetra-1-propyl-, tetra-1-butyl-, tetra-1-pentyl-, tetra-1-octyl-, and cetyltrimethylammonium), in dichloromethane and presents the rate constants and activation parameters of the reduction of permanganate. Attention was paid to the properties of colloidal Mn(IV) intermediate. The stability of the solutions depends markedly on the quaternary ammonium salt used.

Systematic exploration of quaternary ammonium salt adsorption on oxidized coal based on experiments and MD simulations

Fuel ◽  
2021 ◽  
Vol 287 ◽  
pp. 119434
Author(s):  
Jun Chen ◽  
Hongliang Li ◽  
Chunfu Liu ◽  
Lingyun Liu ◽  
Yu Sun ◽  
...  
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Md Simulations ◽  
Oxidized Coal ◽  
Systematic Exploration

scholarly journals Antibacterial performance of polymer quaternary ammonium salt–capped silver nanoparticles on Bacillus subtilis in water

RSC Advances ◽  
2019 ◽  
Vol 9 (44) ◽  
pp. 25667-25676 ◽  
Author(s):  
Jingyu Wang ◽  
Minghao Sui ◽  
Zhanfang Ma ◽  
Hongwei Li ◽  
Bojie Yuan
Keyword(s):  
Silver Nanoparticles ◽  
Bacillus Subtilis ◽  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Antibacterial Performance ◽  
Antibacterial Capacity

Polymer quaternary ammonium salt–capped silver nanoparticles (PQAS–AgNPs) were synthesized, and they exhibited significant antibacterial capacity against Bacillus subtilis.

Synthesis and Applications of Tri-Quaternary Ammonium Salt Gemini Surfactant

2013 ◽  
Vol 34 (1) ◽  
pp. 106-110 ◽  
Author(s):  
Xiongjun Wu ◽  
Lin Zhao ◽  
Xiaojun Wang ◽  
Jinjie Wang ◽  
Yuli Zhang
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salt ◽  
Gemini Surfactant
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