Synthesis and Characterization of Rodlike Ammonium Tetrathiomolybdate and its Thermal Decomposition Mechanism
2011 ◽
Vol 287-290
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pp. 2049-2052
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Keyword(s):
Rodlike ammonium tetrathiomolybdate has been synthesized via ultrasonic assistance using monocrystal ammonium dimolybdate and ammonium sulfide as raw materials. The phase compositions, purity of as-synthesized products were characterized by x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), laser Raman spectroscopy(LRS). The thermal decomposition mechanism of ammonium tetrathiomolybdate was deduced by thermoanalysis. It is shown that brownish-red rhombic ammonium tetrathiomolybdate crystal with high purity could be obtained at 60°C for 1h under relatively mild conditions.
2009 ◽
Vol 113
(39)
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pp. 13014-13017
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2021 ◽
Vol 125
(14)
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pp. 2895-2904
2015 ◽
Vol 121
(1)
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pp. 287-294
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2006 ◽
Vol 16
◽
pp. s402-s405
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2016 ◽
Vol 32
(4)
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pp. 901-906
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Keyword(s):
2018 ◽
Vol 134
◽
pp. 573-579
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